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ID: ALA1147944

Journal: Bioorg Med Chem

Title: Analysis of the inhibition of mammalian carboxylesterases by novel fluorobenzoins and fluorobenzils.

Authors: Hicks LD, Hyatt JL, Moak T, Edwards CC, Tsurkan L, Wierdl M, Ferreira AM, Wadkins RM, Potter PM.

Abstract: We have synthesized and assessed the ability of symmetrical fluorobenzoins and fluorobenzils to inhibit mammalian carboxylesterases (CE). The majority of the latter were excellent inhibitors of CEs however unexpectedly, the fluorobenzoins were very good enzyme inhibitors. Positive correlations were seen with the charge on the hydroxyl carbon atom, the carbonyl oxygen, and the Hammett constants for the derived K(i) values with the fluorobenzoins.

CiteXplore: 17399985

DOI: 10.1016/j.bmc.2007.03.012