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ID: ALA4229347

Journal: Bioorg Med Chem Lett

Title: Design, synthesis, and biological evaluation of novel ubiquitin-activating enzyme inhibitors.

Authors: Itoh Y, Suzuki M.

Abstract: Ubiquitin-activating enzyme (E1), which catalyzes the activation of ubiquitin in the initial step of the ubiquitination cascade, is a potential therapeutic target in multiple myeloma and breast cancer treatment. However, only a few E1 inhibitors have been reported to date. Moreover, there has been little medicinal chemistry research on the three-dimensional structure of E1. Therefore, in the present study, we attempted to identify novel E1 inhibitors using structure-based drug design. Following the rational design, synthesis, and in vitro biological evaluation of several such compounds, we identified a reversible E1 inhibitor (4b). Compound 4b increased p53 levels in MCF-7 breast cancer cells and inhibited their growth. These findings suggest that reversible E1 inhibitors are potential anticancer agents.

CiteXplore: 29548576

DOI: 10.1016/j.bmcl.2018.03.004