Amides and Flavonoids from the Fruit and Leaf Extracts of Melodorum siamensis.

Basic Information

ID: ALA4330156

Journal: J Nat Prod

Title: Amides and Flavonoids from the Fruit and Leaf Extracts of Melodorum siamensis.

Authors: Jaidee W, Andersen RJ, Chavez MAG, Wang YA, Patrick BO, Pyne SG, Muanprasat C, Borwornpinyo S, Laphookhieo S.

Abstract: Four new chalcones (1, 10, 13, and 14), a new flavanone, (9), a new amide (8), and 19 known compounds were acquired from Melodorum siamensis. The structures were established by NMR and MS data analyses. Compounds 1 (er 1.4:1) and 2 (er 1.1:1) were scalemic and were resolved to yield (-)-1 and (+)-1 and (-)-2 and (+)-2, respectively. The absolute configurations of these compounds were determined from experimental and calculated ECD data. The structures and configurations of (-)-2 and (+)-8 were identified by single-crystal X-ray diffraction analysis. Compound 11 showed nuclear factor-κB inhibitory effects (IC50 = 9 μM) in a pancreatic β cell line (MIN-6 cells).

CiteXplore: 30694059

DOI: 10.1021/acs.jnatprod.8b00696

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