Ultrasounds-mediated 10-seconds synthesis of chalcones as potential farnesyltransferase inhibitors.

Basic Information

ID: ALA4619725

Journal: Bioorg Med Chem Lett

Title: Ultrasounds-mediated 10-seconds synthesis of chalcones as potential farnesyltransferase inhibitors.

Authors: Homerin G, Nica AS, Farce A, Dubois J, Ghinet A.

Abstract: A broad range of chalcones and derivatives were easily and rapidly synthesized, following Claisen-Schmidt condensation of (hetero)aryl ketones and (hetero)aryl aldehydes using a ultrasound probe. A comparison was made with classical magnetic stirring experiments, and an optimization study was realized, showing lithium hydroxide to be the best basic catalyst of the studied condensations. By-products of the reactions (β-hydroxy-ketone, diketones, and cyclohexanols) were also isolated. All compounds were evaluated in vitro for their ability to inhibit human farnesyltransferase, a protein implicated in cancer and rare diseases and on the NCI-60 cancer cell lines panel. Molecules showed inhibitory activity on the target protein and cytostatic effect on different cell lines with particular activity against MCF7, breast cancer cells.

CiteXplore: 32247731

DOI: 10.1016/j.bmcl.2020.127149

Patent ID: