Dibenzyl azodicarboxylate - technical grade, 90%, high purity , CAS No.2449-05-0

Item Number

D432367

Grouped product items
SKU	Size	Availability	Price	Qty
D432367-5g	5g	Available within 8-12 weeks(?) Production requires sourcing of materials. We appreciate your patience and understanding.	$183.90
D432367-25g	25g	Available within 8-12 weeks(?) Production requires sourcing of materials. We appreciate your patience and understanding.	$548.90

Basic Description

Synonyms	Dibenzyl azodicarboxylate\|2449-05-0\|dibenzyl diazene-1,2-dicarboxylate\|952229-16-2\|DTXSID3044887\|MFCD00016737\|benzyl N-phenylmethoxycarbonyliminocarbamate\|CHEMBL3182293\|IRJKSAIGIYODAN-ISLYRVAYSA-N\|IRJKSAIGIYODAN-UHFFFAOYSA-N\|AKOS024348901\|Dibenzyl (E)-1,2
Specifications & Purity	technical grade, 90%
Storage Temp	Store at 2-8°C
Shipped In	Wet ice
Grade	technical grade
Product Description	Dibenzyl azodicarboxylate undergoes[4+2] cycloaddition reaction with glycal to yield 2-aminoglycosides. Application Dibenzyl azodicarboxylate was used as electrophilic reagent in the synthesis of C -glycosyl α-amino acids via proline-catalyzed α-amination of C -glycosylalkyl aldehydes. It was used in enantioselective synthesis of optically active pyrazolidine derivatives.

Names and Identifiers

IUPAC Name	benzyl N-phenylmethoxycarbonyliminocarbamate
INCHI	InChI=1S/C16H14N2O4/c19-15(21-11-13-7-3-1-4-8-13)17-18-16(20)22-12-14-9-5-2-6-10-14/h1-10H,11-12H2
InChi Key	IRJKSAIGIYODAN-UHFFFAOYSA-N
Canonical SMILES	C1=CC=C(C=C1)COC(=O)N=NC(=O)OCC2=CC=CC=C2
Isomeric SMILES	C1=CC=C(C=C1)COC(=O)N=NC(=O)OCC2=CC=CC=C2
WGK Germany	3
PubChem CID	75557
Molecular Weight	298.29
Beilstein	2298734

Safety and Hazards(GHS)

Pictogram(s)	GHS07
Signal	Warning
Hazard Statements	H315:Causes skin irritation H319:Causes serious eye irritation H335:May cause respiratory irritation
Precautionary Statements	P261:Avoid breathing dust/fume/gas/mist/vapors/spray. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of water. P321:Specific treatment (see ... on this label). P405:Store locked up. P501:Dispose of contents/container to ... P264:Wash hands [and …] thoroughly after handling. P271:Use only outdoors or in a well-ventilated area. P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing. P403+P233:Store in a well-ventilated place. Keep container tightly closed. P362+P364:Take off contaminated clothing and wash it before reuse. P264+P265:Wash hands [and …] thoroughly after handling. Do not touch eyes. P337+P317:If eye irritation persists: Get medical help. P332+P317:If skin irritation occurs: Get medical help. P319:Get medical help if you feel unwell.
WGK Germany	3

References

1. Shengming Ma, Ning Jiao, Zilong Zheng, Zhichao Ma, Zhan Lu, Longwu Ye, Youqian Deng, Guofei Chen,. (2004-06-18) Cu- and Pd-catalyzed asymmetric one-pot tandem addition-cyclization reaction of 2-(2',3'-alkadienyl)-beta-keto esters, organic halides, and dibenzyl azodicarboxylate: an effective protocol for the enantioselective synthesis of pyrazolidine derivatives.. Organic letters, 6 ((13)): ( 2193-2196 ). [PMID:15200318]

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Basic Description