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Dichloro(dimethylamino)phosphine - 98%, high purity , CAS No.683-85-2

  • ≥98%
Item Number
D154283
Grouped product items
SKUSizeAvailabilityPrice Qty
D154283-1g
1g
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$36.90
D154283-5g
5g
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$129.90
D154283-25g
25g
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$452.90

Basic Description

SynonymsDimethylphosphoramidous dichloride, 97% | Dimethylphosphoramidous dichloride | N,N-Dimethylphosphoramidous dichloride | (CH3)2NPCl2 | N-dichlorophosphanyl-N-methylmethanamine | FT-0632796 | (Dimethylamino)phosphonous Dichloride | DTXSID90218455 | 1,1-Dich
Specifications & Purity98%
Storage TempStore at 2-8°C,Argon charged
Shipped InWet ice
Product Description

Dimethylphosphoramidous dichloride (dimethylaminodichlorophosphine) is a phosphorus chloride derivative. It exists in two stable isomers, a gauche-conformer with C1 symmetry and anti-conformer with Cs symmetry. Its synthesis has been reported. Molecular conformation has been investigated through correlation between the 35Cl NQR frequencies and charge on the chlorine atoms. Its vibrational spectra has been studied. Its reaction with SO2 has been investigated. It participates in the synthesis of [(dimethylamino)phosphoryl] bis(difluoromethylene)phosphonate.


application:

Dimethylphosphoramidous dichloride (N,N-dimethylamidodichlorophosphite) may be used in the synthesis of the following:
N,N-dimethylamidotetrachlorophosphorane
O-propylchloroformimino-N,N-dimethylamidochlorophosphate
1,3-bisarylsulphonyl-1,3,2,4-diazadiphosphetidines

Names and Identifiers

IUPAC Name N-dichlorophosphanyl-N-methylmethanamine
INCHI InChI=1S/C2H6Cl2NP/c1-5(2)6(3)4/h1-2H3
InChi Key XPWWDZRSNFSLRQ-UHFFFAOYSA-N
Canonical SMILES CN(C)P(Cl)Cl
Isomeric SMILES CN(C)P(Cl)Cl
WGK Germany 3
PubChem CID 136483
Molecular Weight 145.95

Certificates

Certificate of Analysis(COA)

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6 results found

Lot NumberCertificate TypeDateItem
G2405315Certificate of AnalysisMar 07, 2024 D154283
G2405396Certificate of AnalysisMar 07, 2024 D154283
G2405397Certificate of AnalysisMar 07, 2024 D154283
G2405403Certificate of AnalysisMar 07, 2024 D154283
G2405404Certificate of AnalysisMar 07, 2024 D154283
G2405405Certificate of AnalysisMar 07, 2024 D154283

Chemical and Physical Properties

SolubilityReacts with water.
SensitivityMoisture Sensitive,Heat Sensitive
Refractive Index1.5
Flash Point(°F)-9.4 °F
Flash Point(°C)-23°C(lit.)
Boil Point(°C)150°C(lit.)

Safety and Hazards(GHS)

Pictogram(s) GHS05,   GHS02
Signal Danger
Hazard Statements

H314:Causes severe skin burns and eye damage

H225:Highly Flammable liquid and vapor

Precautionary Statements

P280:Wear protective gloves/protective clothing/eye protection/face protection.

P370+P378:In case of fire: Use ... to extinguish.

P210:Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking.

P321:Specific treatment (see ... on this label).

P405:Store locked up.

P501:Dispose of contents/container to ...

P233:Keep container tightly closed.

P240:Ground/bond container and receiving equipment.

P264:Wash hands [and …] thoroughly after handling.

P403+P235:Store in a well-ventilated place. Keep cool.

P260:Do not breathe dust/fume/gas/mist/vapors/spray.

P303+P361+P353:IF ON SKIN (or hair): Take off Immediately all contaminated clothing. Rinse SKIN with water [or shower].

P241:Use explosion-proof [electrical/ventilating/lighting/.../] equipment.

P301+P330+P331:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P363:Wash contaminated clothing before reuse.

P242:Use only non-sparking tools.

P243:Take precautionary measures against static discharge.

P305+P354+P338:IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing.

P302+P361+P354:IF ON SKIN: Take off Immediately all contaminated clothing. Immediately rinse with water for several minutes.

P316:Get emergency medical help immediately.

WGK Germany 3

Related Documents

References

1. G K Surya Prakash,Mikhail Zibinsky,Thomas G Upton,Boris A Kashemirov,Charles E McKenna,Keriann Oertell,Myron F Goodman,Vinod K Batra,Lars C Pedersen,William A Beard,David D Shock,Samuel H Wilson,George A Olah.  (2010-08-21)  Synthesis and biological evaluation of fluorinated deoxynucleotide analogs based on bis-(difluoromethylene)triphosphoric acid..  Proceedings of the National Academy of Sciences of the United States of America,  107  ((36)): (15693-15698).  [PMID:20724659]

Solution Calculators