Your company account is blocked and you cannot place orders. If you have questions, please contact your company administrator.

Tetramethyl-1,4-benzoquinone(DQ)

Product Manager:Nick Wilde

See also:1,4-Benzoquinone, BQ


Recent Literature


The use of a palladium catalyst paired with a bidentate phosphine ligand and duroquinone facilitates an intermolecular oxidative amination process for unactivated olefins and primary aliphatic amines, yielding a variety of secondary allylic amines in high yields and with remarkable regio- and stereoselectivity. This reaction mechanism involves allylic C(sp3)-H activation followed by nucleophilic amination.
M. Li, Y. Jin, Y. Chen, W. Wu, H. Jiang, J. Am. Chem. Soc., 2023, 145, 9448-9453.

https://doi.org/10.1021/jacs.3c02114


Quoted from:

https://www.organic-chemistry.org/chemicals/oxidations/duroquinone.shtm

 

Aladdin:https://www.aladdinsci.com

Was this helpful? No Be the first to vote!