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Tetramethyl-1,4-benzoquinone(DQ)
Product Manager:Nick Wilde
See also:1,4-Benzoquinone, BQ
Recent Literature
The use of a palladium catalyst paired with a bidentate phosphine ligand and duroquinone facilitates an intermolecular oxidative amination process for unactivated olefins and primary aliphatic amines, yielding a variety of secondary allylic amines in high yields and with remarkable regio- and stereoselectivity. This reaction mechanism involves allylic C(sp3)-H activation followed by nucleophilic amination.
M. Li, Y. Jin, Y. Chen, W. Wu, H. Jiang, J. Am. Chem. Soc., 2023, 145, 9448-9453.
https://doi.org/10.1021/jacs.3c02114
Quoted from:
https://www.organic-chemistry.org/chemicals/oxidations/duroquinone.shtm
Aladdin:https://www.aladdinsci.com
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