Girard’s reagent T - 98%, high purity , CAS No.123-46-6

  • ≥98%
Item Number
G108418
Grouped product items
SKUSizeAvailabilityPrice Qty
G108418-25g
25g
In stock
$21.90
G108418-100g
100g
In stock
$78.90
G108418-500g
500g
In stock
$151.90
View related series
Ammonium salt Onium salts

Basic Description

SynonymsQ27285753 | 2-Hydrazineyl-N,N,N-trimethyl-2-oxoethan-1-aminium chloride | l-(-)-malicaciddiethylester | girard-t | (Hydrazinocarbonylmethyl)trimethylammonium chloride | Carbazoylmethyltrimethylammonium chloride | Ethanaminium, 2-hydrazino-N,N,N-trimethyl-
Specifications & Purity≥98%
Storage TempArgon charged
Shipped InNormal
Product Description

For the separation of estrone and the other 17 - steroidal ketone compounds.

Names and Identifiers

IUPAC Name (2-hydrazinyl-2-oxoethyl)-trimethylazanium;chloride
INCHI InChI=1S/C5H13N3O.ClH/c1-8(2,3)4-5(9)7-6;/h4,6H2,1-3H3;1H
InChi Key YSULOORXQBDPCU-UHFFFAOYSA-N
Canonical SMILES C[N+](C)(C)CC(=O)NN.[Cl-]
Isomeric SMILES C[N+](C)(C)CC(=O)NN.[Cl-]
WGK Germany 3
RTECS CP3150000
PubChem CID 67156
Molecular Weight 167.64
Beilstein 3727163
Reaxy-Rn 3727163

Certificates

Certificate of Analysis(COA)

Enter Lot Number to search for COA:

Find and download the COA for your product by matching the lot number on the packaging.

10 results found

Lot NumberCertificate TypeDateItem
C2405050Certificate of AnalysisJul 30, 2022 G108418
J2215236Certificate of AnalysisJul 30, 2022 G108418
J2215241Certificate of AnalysisJul 30, 2022 G108418
J2215243Certificate of AnalysisJul 30, 2022 G108418
J2215292Certificate of AnalysisJul 30, 2022 G108418
D2117024Certificate of AnalysisMay 17, 2022 G108418
D2117025Certificate of AnalysisMay 17, 2022 G108418
D2117026Certificate of AnalysisMay 17, 2022 G108418
D2117027Certificate of AnalysisMay 17, 2022 G108418
D2415399Certificate of AnalysisApr 25, 2021 G108418

Chemical and Physical Properties

SolubilitySolubility in Water almost transparency
SensitivityMoisture & air sensitive.
Melt Point(°C)192°C

Safety and Hazards(GHS)

Pictogram(s) GHS07
Signal Warning
Hazard Statements

H315:Causes skin irritation

H319:Causes serious eye irritation

H335:May cause respiratory irritation

Precautionary Statements

P261:Avoid breathing dust/fume/gas/mist/vapors/spray.

P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.

P280:Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352:IF ON SKIN: wash with plenty of water.

P321:Specific treatment (see ... on this label).

P405:Store locked up.

P501:Dispose of contents/container to ...

P264:Wash hands [and …] thoroughly after handling.

P271:Use only outdoors or in a well-ventilated area.

P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P403+P233:Store in a well-ventilated place. Keep container tightly closed.

P362+P364:Take off contaminated clothing and wash it before reuse.

P264+P265:Wash hands [and …] thoroughly after handling. Do not touch eyes.

P337+P317:If eye irritation persists: Get medical help.

P332+P317:If skin irritation occurs: Get medical help.

P319:Get medical help if you feel unwell.

WGK Germany 3
RTECS CP3150000
Reaxy-Rn 3727163
Merck Index 4429

Related Documents

Citations of This Product

1. Hai-Xia Xu, Hui Chen, Zhong-Ping Yin, Qing-Feng Zhang.  (2024)  Piceid dicarboxylic acid esters as potent α-glucosidase inhibitors and antiglycation agents: Synthesis, spectroscopic and molecular docking studies.  JOURNAL OF MOLECULAR STRUCTURE,  1296  (3): (136938).  [PMID:25527291] [10.1016/j.molstruc.2023.136938]
2. Lu Liu, Hongyang Ma, Madani Khan, Benjamin S. Hsiao.  (2023)  Highly Efficient Cationic/Anionic Cellulose Membranes for Removal of Cr(VI) and Pb(II) Ions.  Membranes,  13  (7): (651).  [PMID:37505017] [10.3390/membranes13070651]
3. Qiuyu Lin, Luyun Xue, Jiannan Sun, Yuanchao Wang, Heyong Cheng.  (2022)  Suzuki C–C Coupling in Paper Spray Ionization: Microsynthesis of Biaryls and High-Sensitivity MS Detection of Aryl Bromides.  JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY,  33  (10): (1921–1935).  [PMID:36074999] [10.1021/jasms.2c00192]
4. Lang Chen, Chenyan Yu, Yuan Xiong, Kai Chen, Pei Liu, Adriana C. Panayi, Xiufeng Xiao, Qian Feng, Bobin Mi, Guohui Liu.  (2023)  Multifunctional hydrogel enhances bone regeneration through sustained release of Stromal Cell-Derived Factor-1α and exosomes.  Bioactive Materials,  25  (460).  [PMID:37056272] [10.1016/j.bioactmat.2022.07.030]
5. Yuan Xiong, Lang Chen, Pei Liu, Tao Yu, Chuanchuan Lin, Chenchen Yan, Yiqiang Hu, Wu Zhou, Yun Sun, Adriana C. Panayi, Faqi Cao, Hang Xue, Liangcong Hu, Ze Lin, Xudong Xie, Xiufeng Xiao, Qian Feng, Bobin Mi, Guohui Liu.  (2021)  All-in-One: Multifunctional Hydrogel Accelerates Oxidative Diabetic Wound Healing through Timed-Release of Exosome and Fibroblast Growth Factor.  Small,  18  (1): (2104229).  [PMID:34791802] [10.1002/smll.202104229]
6. Xiu Chen, Quan Shi, Xibin Zhou, Xuezheng Liu.  (2019)  Molecular characterization of aldehydes and ketones in particle phase of mainstream and sidestream cigarette smoke.  Royal Society Open Science,  (2):   [PMID:30891292] [10.1098/rsos.181832]

References

1. D Serban,J M Pages,A E Bussard,I P Witz.  (1981-11-01)  The participation of trimethylammonium in the mouse erythrocyte epitope recognized by monoclonal autoantibodies..  Immunology letters,  ((5)): (315-319).  [PMID:6173316]
2. S Görög,M Gazdag,P Kemenes-Bakos.  (1996-06-01)  Analysis of steroids Part 50. Derivatization of ketosteroids for their separation and determination by capillary electrophoresis..  Journal of pharmaceutical and biomedical analysis,  14  ((8-10)): (1115-1124).  [PMID:8818023]
3. David W Johnson,Rosemarie Gerace,Enzo Ranieri,Minh-Uyen Trinh,Ralph Fingerhut.  (2006-11-30)  Analysis of succinylacetone, as a Girard T derivative, in urine and dried bloodspots by flow injection electrospray ionization tandem mass spectrometry..  Rapid communications in mass spectrometry : RCM,  21  ((1)): (59-63).  [PMID:17133337]
4. David W Johnson.  (2007-08-07)  A modified Girard derivatizing reagent for universal profiling and trace analysis of aldehydes and ketones by electrospray ionization tandem mass spectrometry..  Rapid communications in mass spectrometry : RCM,  21  ((18)): (2926-2932).  [PMID:17676710]
5. Kyoung-Soon Jang,Yun-Gon Kim,Geun-Cheol Gil,Sang-Ho Park,Byung-Gee Kim.  (2009-01-13)  Mass spectrometric quantification of neutral and sialylated N-glycans from a recombinant therapeutic glycoprotein produced in the two Chinese hamster ovary cell lines..  Analytical biochemistry,  386  ((2)): (228-236).  [PMID:19135424]
6. Bert Vissers,Joseph Everaert,Justyna Sekula,Anna Malak,Hugo Bohets,Grzegorz Bazylak,Luc J Nagels.  (2009-01-22)  Unique potentiometric detection systems for HPLC determination of some steroids in human urine..  Journal of separation science,  32  ((2)): (167-179).  [PMID:19156641]
7. Usama El-Ayaan,I M Kenawy,Y G Abu El-Reash.  (2007-02-24)  Synthesis, thermal and spectral studies of first-row transition metal complexes with Girard P reagent-based ligand..  Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy,  68  ((2)): (211-219).  [PMID:17317280]
8. Abraham K Badu-Tawiah,Dahlia I Campbell,R Graham Cooks.  (2012-03-20)  Reactions of microsolvated organic compounds at ambient surfaces: droplet velocity, charge state, and solvent effects..  Journal of the American Society for Mass Spectrometry,  23  ((6)): (1077-1084).  [PMID:22427191]
9. Santosh L Gande,Krishna Saxena,Sridhar Sreeramulu,Verena Linhard,Denis Kudlinzki,Stephanie Heinzlmeir,Andreas J Reichert,Arne Skerra,Bernhard Kuster,Harald Schwalbe.  (2016-09-30)  Expression and Purification of EPHA2 Tyrosine Kinase Domain for Crystallographic and NMR Studies..  Chembiochem : a European journal of chemical biology,  17  ((23)): (2257-2263).  [PMID:27685543]
10. Hai-Xia Xu, Hui Chen, Zhong-Ping Yin, Qing-Feng Zhang.  (2024)  Piceid dicarboxylic acid esters as potent α-glucosidase inhibitors and antiglycation agents: Synthesis, spectroscopic and molecular docking studies.  JOURNAL OF MOLECULAR STRUCTURE,  1296  (3): (136938).  [PMID:25527291] [10.1016/j.molstruc.2023.136938]
11. Lu Liu, Hongyang Ma, Madani Khan, Benjamin S. Hsiao.  (2023)  Highly Efficient Cationic/Anionic Cellulose Membranes for Removal of Cr(VI) and Pb(II) Ions.  Membranes,  13  (7): (651).  [PMID:37505017] [10.3390/membranes13070651]
12. Qiuyu Lin, Luyun Xue, Jiannan Sun, Yuanchao Wang, Heyong Cheng.  (2022)  Suzuki C–C Coupling in Paper Spray Ionization: Microsynthesis of Biaryls and High-Sensitivity MS Detection of Aryl Bromides.  JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY,  33  (10): (1921–1935).  [PMID:36074999] [10.1021/jasms.2c00192]
13. Lang Chen, Chenyan Yu, Yuan Xiong, Kai Chen, Pei Liu, Adriana C. Panayi, Xiufeng Xiao, Qian Feng, Bobin Mi, Guohui Liu.  (2023)  Multifunctional hydrogel enhances bone regeneration through sustained release of Stromal Cell-Derived Factor-1α and exosomes.  Bioactive Materials,  25  (460).  [PMID:37056272] [10.1016/j.bioactmat.2022.07.030]
14. Yuan Xiong, Lang Chen, Pei Liu, Tao Yu, Chuanchuan Lin, Chenchen Yan, Yiqiang Hu, Wu Zhou, Yun Sun, Adriana C. Panayi, Faqi Cao, Hang Xue, Liangcong Hu, Ze Lin, Xudong Xie, Xiufeng Xiao, Qian Feng, Bobin Mi, Guohui Liu.  (2021)  All-in-One: Multifunctional Hydrogel Accelerates Oxidative Diabetic Wound Healing through Timed-Release of Exosome and Fibroblast Growth Factor.  Small,  18  (1): (2104229).  [PMID:34791802] [10.1002/smll.202104229]
15. Xiu Chen, Quan Shi, Xibin Zhou, Xuezheng Liu.  (2019)  Molecular characterization of aldehydes and ketones in particle phase of mainstream and sidestream cigarette smoke.  Royal Society Open Science,  (2):   [PMID:30891292] [10.1098/rsos.181832]

Solution Calculators