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Hexabromobenzene - 99%, high purity , CAS No.87-82-1

  • ≥99%
Item Number
H114690
Grouped product items
SKUSizeAvailabilityPrice Qty
H114690-25g
25g
In stock
$29.90
H114690-100g
100g
In stock
$106.90
H114690-500g
500g
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$136.90
View related series
Aryl halide Non heterocyclic block

Basic Description

SynonymsHEXABROMOBENZENE|87-82-1|Benzene, hexabromo-|Perbromobenzene|1,2,3,4,5,6-Hexabromobenzene|T01859XWIR|DTXSID1024128|NSC-113975|Benzene, 1,2,3,4,5,6-hexabromo-|HXBBZ|CCRIS 5917|HSDB 2912|EINECS 201-773-9|NSC 113975|UNII-T01859XWIR|AI3-60220|PLASAFETY HBB|He
Specifications & Purity≥99%
Shipped InNormal
Product Description

Hexabromobenzene is used as fire retardant in plastics, paper and electric manufactured goods. It undergoes protodebromination when treated with sodium methoxide in methanol and ethyl methyl ketone to give a mixture of tetrabromobenzenes.

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.The porphyrinogenic potential of hexabromobenzene (HBB) with hexachlorobenzene was studied in the liver of primiparous rats.

Associated Targets

AR Tclin Androgen receptor 0 Activities

Activity TypeActivity Value -log(M)Mechanism of ActionActivity ReferencePublications (PubMed IDs)

THRB Tclin Thyroid hormone receptor beta 0 Activities

Activity TypeActivity Value -log(M)Mechanism of ActionActivity ReferencePublications (PubMed IDs)

Names and Identifiers

Pubchem Sid488180198
Pubchem Sid Urlhttps://pubchem.ncbi.nlm.nih.gov/substance/488180198
IUPAC Name 1,2,3,4,5,6-hexabromobenzene
INCHI InChI=1S/C6Br6/c7-1-2(8)4(10)6(12)5(11)3(1)9
InChi Key CAYGQBVSOZLICD-UHFFFAOYSA-N
Canonical SMILES C1(=C(C(=C(C(=C1Br)Br)Br)Br)Br)Br
Isomeric SMILES C1(=C(C(=C(C(=C1Br)Br)Br)Br)Br)Br
WGK Germany 3
PubChem CID 6905
UN Number 3077
Packing Group III
Molecular Weight 551.49
Beilstein 1912586

Certificates

Certificate of Analysis(COA)

Enter Lot Number to search for COA:

To view the certificate results,please click on a Lot number.For Lot numbers from past orders,please use our order status section

11 results found

Lot NumberCertificate TypeDateItem
J2215175Certificate of AnalysisJul 15, 2024 H114690
J2215319Certificate of AnalysisJul 15, 2024 H114690
J2215331Certificate of AnalysisJul 15, 2024 H114690
G2418090Certificate of AnalysisApr 30, 2024 H114690
G2418091Certificate of AnalysisApr 30, 2024 H114690
G2418401Certificate of AnalysisApr 30, 2024 H114690
H2125218Certificate of AnalysisMay 15, 2023 H114690
E2128101Certificate of AnalysisMar 09, 2023 H114690
G2320149Certificate of AnalysisJul 30, 2022 H114690
F2214222Certificate of AnalysisMar 21, 2022 H114690
D2022057Certificate of AnalysisFeb 22, 2022 H114690

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Chemical and Physical Properties

SolubilitySolubility in hot Toluene almost transparency.
Melt Point(°C)>300°C

Safety and Hazards(GHS)

Pictogram(s) GHS07
Signal Warning
Hazard Statements

H315:Causes skin irritation

H319:Causes serious eye irritation

H335:May cause respiratory irritation

H413:May cause long lasting harmful effects to aquatic life

H302:Harmful if swallowed

H312:Harmful in contact with skin

H332:Harmful if inhaled

H302+H312+H332:Harmful if swallowed, in contact with skin or if inhaled

Precautionary Statements

P261:Avoid breathing dust/fume/gas/mist/vapors/spray.

P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.

P273:Avoid release to the environment.

P280:Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352:IF ON SKIN: wash with plenty of water.

P321:Specific treatment (see ... on this label).

P405:Store locked up.

P501:Dispose of contents/container to ...

P264:Wash hands [and …] thoroughly after handling.

P271:Use only outdoors or in a well-ventilated area.

P270:Do not eat, drink or smoke when using this product.

P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P403+P233:Store in a well-ventilated place. Keep container tightly closed.

P362+P364:Take off contaminated clothing and wash it before reuse.

P330:Rinse mouth.

P264+P265:Wash hands [and …] thoroughly after handling. Do not touch eyes.

P301+P317:IF SWALLOWED: Get medical help.

P317:Get emergency medical help.

P337+P317:If eye irritation persists: Get medical help.

P332+P317:If skin irritation occurs: Get medical help.

P319:Get medical help if you feel unwell.

WGK Germany 3
Class 9

Related Documents

References

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2. C E Mendoza,J B Shields,G W Laver.  (1979-02-01)  Comparison of the porphyrinogenic activity of hexabromobenzene and hexachlorobenzene in primiparous Wistar rats..  Bulletin of environmental contamination and toxicology,  21  ((3)): (358-364).  [PMID:376006]
3. Y Yamaguchi,M Kawano,R Tatsukawa.  (1988-11-01)  Tissue distribution and excretion of hexabromobenzene and its debrominated metabolites in the rat..  Archives of environmental contamination and toxicology,  17  ((6)): (807-812).  [PMID:3228297]
4. I Watanabe,T Kashimoto,R Tatsukawa.  (1986-05-01)  Hexabromobenzene and its debrominated compounds in river and estuary sediments in Japan..  Bulletin of environmental contamination and toxicology,  36  ((5)): (778-784).  [PMID:3708183]
5. G Koss,H Döring,C Stremme,S Seubert,A Seubert,B Arndt,J Seidel,W Koransky,H Ippen.  (1986-04-01)  Elimination of porphyrins and their precursors in rats pretreated with hexabromobenzene..  Food and chemical toxicology : an international journal published for the British Industrial Biological Research Association,  24  ((4)): (325-328).  [PMID:3732979]
6. A Belfroid,J Meiling,H J Drenth,J Hermens,W Seinen,K van Gestel.  (1995-08-01)  Dietary uptake of superlipophilic compounds by earthworms (Eisenia andrei)..  Ecotoxicology and environmental safety,  31  ((3)): (185-191).  [PMID:7498054]
7. A Belfroid,J Meiling,H J Drenth,J Hermens,W Seinen,K van Gestel.  (1995-08-01)  Dietary uptake of superlipophilic compounds by earthworms (Eisenia andrei)..  Ecotoxicology and environmental safety,  31  ((3)): (185-191).  [PMID:7498054]
8. J A Szymańska.  (1998-02-10)  Hepatotoxicity of brominated benzenes: relationship between chemical structure and hepatotoxic effects in acute intoxication of mice..  Archives of toxicology,  72  ((2)): (97-103).  [PMID:9456081]
9. Silke Rupp,Jörg W Metzger.  (2005-08-09)  Brominated-chlorinated diphenyl ethers formed by thermolysis of polybrominated diphenyl ethers at low temperatures..  Chemosphere,  60  ((11)): (1644-1651).  [PMID:16083771]
10. Barbara Frydrych,Jadwiga A Szymańska,Monika Sala,Elzbieta Bruchajzer.  (2005-10-06)  The effect of selected aromatic bromine derivatives on the activity of glutathione peroxidase and transferase..  International journal of occupational medicine and environmental health,  18  ((2)): (127-132).  [PMID:16201203]
11. Kristýna Pluhácková,Petr Jurecka,Pavel Hobza.  (2007-02-03)  Stabilisation energy of C(6)H(6)...C(6)X(6) (X = F, Cl, Br, I, CN) complexes: complete basis set limit calculations at MP2 and CCSD(T) levels..  Physical chemistry chemical physics : PCCP,  ((6)): (755-760).  [PMID:17268688]
12. Bruno Gouteux,Mehran Alaee,Scott A Mabury,Grazina Pacepavicius,Derek C G Muir.  (2009-01-30)  Polymeric brominated flame retardants: are they a relevant source of emerging brominated aromatic compounds in the environment?.  Environmental science & technology,  42  ((24)): (9039-9044).  [PMID:19174868]
13. Lewis T Gauthier,Dave Potter,Craig E Hebert,Robert J Letcher.  (2009-02-26)  Temporal trends and spatial distribution of non-polybrominated diphenyl ether flame retardants in the eggs of colonial populations of Great Lakes herring gulls..  Environmental science & technology,  43  ((2)): (312-317).  [PMID:19238957]
14. Jiang-Ping Wu,Yun-Tao Guan,Ying Zhang,Xiao-Jun Luo,Hui Zhi,She-Jun Chen,Bi-Xian Mai.  (2010-10-19)  Several current-use, non-PBDE brominated flame retardants are highly bioaccumulative: evidence from field determined bioaccumulation factors..  Environment international,  37  ((1)): (210-215).  [PMID:20952068]
15. Hans Peter H Arp,Thomas Møskeland,Patrik L Andersson,Jenny Rattfelt Nyholm.  (2010-12-09)  Presence and partitioning properties of the flame retardants pentabromotoluene, pentabromoethylbenzene and hexabromobenzene near suspected source zones in Norway..  Journal of environmental monitoring : JEM,  13  ((3)): (505-513).  [PMID:21140013]
16. Axel Möller,Zhiyong Xie,Renate Sturm,Ralf Ebinghaus.  (2011-03-23)  Polybrominated diphenyl ethers (PBDEs) and alternative brominated flame retardants in air and seawater of the European Arctic..  Environmental pollution (Barking, Essex : 1987),  159  ((6)): (1577-1583).  [PMID:21421283]
17. Yumi Katayama,Mitsuru Aoyagi,Takuya Matsumoto,Hiroyuki Harada,Alina M Simion,Naoyoshi Egashira,Yoshiharu Mitoma,Cristian Simion.  (2016-10-16)  Hydrodehalogenation of hexachloro- and hexabromobenzene by metallic calcium in ethanol, in the presence of Rh/C catalyst..  Environmental science and pollution research international,  24  ((1)): (591-597).  [PMID:27743324]
18. G H Elder,A G Roberts,A J Urquhart.  (1987-01-01)  Alterations of uroporphyrinogen decarboxylase by chlorinated organics..  Annals of the New York Academy of Sciences,  514  (141-147).  [PMID:3442378]
19. R B Franklin,R K Breger,J J Lech.  (1983-08-01)  Comparative effects of hexachloro- and hexabromobenzene on hepatic monooxygenase activity of male and female rats..  Journal of toxicology and environmental health,  12  ((2-3)): (223-234).  [PMID:6655732]
20. K D Courtney,J E Andrews.  (1984-02-01)  Teratogenic evaluation and fetal deposition of hexabromobenzene (HBB) and hexafluorobenzene (HFB) in CD-1 mice..  Journal of environmental science and health. Part. B, Pesticides, food contaminants, and agricultural wastes,  19  ((1)): (83-94).  [PMID:6715792]
21. G Koss,H Döring,B Würminghausen,W Koransky.  (1982-11-01)  Metabolic fate of hexabromobenzene in rats..  Toxicology letters,  14  ((1-2)): (69-77).  [PMID:7157418]
22. A G Smith,J E Francis.  (1980-05-01)  Relative abilities on a molar basis of hexafluoro-, hexachloro- and hexabromobenzenes to decrease liver uroporphyrinogen decarboxylase activity and cause porphyria in female rats..  Research communications in chemical pathology and pharmacology,  28  ((2)): (377-384).  [PMID:7394329]
23. A Sapota,A Kilanowicz,J A Szymańska.  (1997-01-01)  The distribution and excretion of hexabromobenzene after a single administration in rat..  International journal of occupational medicine and environmental health,  10  ((4)): (365-374).  [PMID:9575663]
24. Qiwu Zhang,Hiroki Matsumoto,Fumio Saito,Michel Baron.  (2002-09-12)  Debromination of hexabromobenzene by its co-grinding with CaO..  Chemosphere,  48  ((8)): (787-793).  [PMID:12222772]
25. Elzbieta Bruchajzer,Barbara Frydrych,Jadwiga A Szymańska.  (2005-02-03)  Effect of repeated administration of hexabromobenzene and 1,2,4,5-tetrabromobenzene on the levels of selected cytochromes in rat liver..  International journal of occupational medicine and environmental health,  17  ((3)): (347-353).  [PMID:15683155]
26. Amina Salamova,Ronald A Hites.  (2011-09-29)  Discontinued and alternative brominated flame retardants in the atmosphere and precipitation from the great lakes basin..  Environmental science & technology,  45  ((20)): (8698-8706).  [PMID:21942402]
27. Susan L Klosterhaus,Heather M Stapleton,Mark J La Guardia,Denise J Greig.  (2012-07-07)  Brominated and chlorinated flame retardants in San Francisco Bay sediments and wildlife..  Environment international,  47  (56-65).  [PMID:22766500]
28. Joanna Wencel-Delord,Corinna Nimphius,Honggen Wang,Frank Glorius.  (2012-10-23)  Rhodium(III) and hexabromobenzene-a catalyst system for the cross-dehydrogenative coupling of simple arenes and heterocycles with arenes bearing directing groups..  Angewandte Chemie (International ed. in English),  51  ((52)): (13001-13005).  [PMID:23086666]

Solution Calculators