Basic Description

Synonyms	10025-82-8\|Indium chloride (InCl3)\|trichloroindigane\|InCl3\|DTXSID8033566\|MFCD00011058\|NCGC00090704-01\|NCGC00090704-03\|DTXCID6013566\|Indium(III) Chloride, Anhydrous\|CAS-10025-82-8\|Indium (133-In) chloride\|Indium chloride (133InCl3)\|HSDB 6973\|Indiclor (TN)\|
Specifications & Purity	~39% indium basis, 2-3 mol/mol water
Product Description	Application Reagent/catalyst for various organic transformations, e.g. allylation of aldehydes, ketones, and quinones; Diels-Alder reaction; the aldol reaction; Michael additions; the reductive Friedel-Crafts;

Names and Identifiers

IUPAC Name	trichloroindigane
INCHI	InChI=1S/3ClH.In/h3*1H;/q;;;+3/p-3
InChi Key	PSCMQHVBLHHWTO-UHFFFAOYSA-K
Canonical SMILES	Cl[In](Cl)Cl
Isomeric SMILES	Cl[In](Cl)Cl
RTECS	NL1400000
PubChem CID	24812
Molecular Weight	221.18

Certificates

Certificate of Analysis(COA)

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Chemical and Physical Properties

Boil Point(°C)	800℃
Melt Point(°C)	586℃

Safety and Hazards(GHS)

Pictogram(s)	GHS05, GHS07
Signal	Danger
Hazard Statements	H314:Causes severe skin burns and eye damage H302:Harmful if swallowed
Precautionary Statements	P280:Wear protective gloves/protective clothing/eye protection/face protection. P321:Specific treatment (see ... on this label). P405:Store locked up. P501:Dispose of contents/container to ... P264:Wash hands [and …] thoroughly after handling. P260:Do not breathe dust/fume/gas/mist/vapors/spray. P270:Do not eat, drink or smoke when using this product. P301+P330+P331:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing. P363:Wash contaminated clothing before reuse. P330:Rinse mouth. P301+P317:IF SWALLOWED: Get medical help. P305+P354+P338:IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. P302+P361+P354:IF ON SKIN: Take off Immediately all contaminated clothing. Immediately rinse with water for several minutes. P316:Get emergency medical help immediately.
RTECS	NL1400000

References

1. Gregory K Friestad,Koushik Banerjee. (2009-02-10) Synthesis of gamma-amino esters via Mn-mediated radical addition to chiral gamma-hydrazonoesters.. Organic letters, 11 ((5)): (1095-1098). [PMID:19199819]
2. Bonil Koo,Reken N Patel,Brian A Korgel. (2009-02-17) Synthesis of CuInSe(2) nanocrystals with trigonal pyramidal shape.. Journal of the American Chemical Society, 131 ((9)): (3134-3135). [PMID:19216573]
3. Enrique Font-Sanchis,Angela Sastre-Santos,Fernando Fernández-Lázaro. (2009-03-26) Fluoride-triggered indium-mediated synthesis of (hetero)biaryls.. Dalton transactions (Cambridge, England : 2003), ((14)): (2470-2473). [PMID:19319390]
4. Biswanath Das,Kongara Damodar,Nisith Bhunia. (2009-07-04) A simple and efficient access to alpha-amino phosphonates from N-benzyloxycarbonylamino sulfones using indium(III) chloride.. The Journal of organic chemistry, 74 ((15)): (5607-5609). [PMID:19572593]
5. On-Yi Lee,Ka-Lun Law,Dan Yang. (2009-07-14) Secondary amine formation from reductive amination of carbonyl compounds promoted by Lewis acid using the InCl3/Et3SiH system.. Organic letters, 11 ((15)): (3302-3305). [PMID:19591453]
6. Patrick J Kirby,Cassandra J Shines,Genie J Taylor,Ronald W Bousquet,Herman C Price,Jeffrey I Everitt,Daniel L Morgan. (2009-12-10) Pleural effects of indium phosphide in B6C3F1 mice: nonfibrous particulate induced pleural fibrosis.. Experimental lung research, 35 ((10)): (858-882). [PMID:19995279]
7. Philip C Andrews,William J Gee,Peter C Junk,Harald Krautscheid. (2010-01-22) Highly efficient indium(III)-mediated cyclisation of 5-hydroxy-1,3-diketones to 2,3-dihydro-4H-pyran-4-ones; mechanistic insights from in situ Fourier transform infrared spectroscopy.. Organic & biomolecular chemistry, 8 ((3)): (698-705). [PMID:20090989]
8. Kensuke Kiyokawa,Makoto Yasuda,Akio Baba. (2010-03-12) Cyclopropylmethylation of benzylic and allylic chlorides with cyclopropylmethylstannane catalyzed by gallium or indium halide.. Organic letters, 12 ((7)): (1520-1523). [PMID:20218636]
9. Swarupananda Maiti,Vellaisamy Sridharan,J Carlos Menéndez. (2010-07-03) Synthesis of a library of 5,6-unsubstituted 1,4-dihydropyridines based on a one-pot 4CR/elimination process and their application to the generation of structurally diverse fused nitrogen heterocycles.. Journal of combinatorial chemistry, 12 ((5)): (713-722). [PMID:20593849]
10. Agostino Pietrangelo, Spencer C Knight, Aalo K Gupta, Letitia J Yao, Marc A Hillmyer, William B Tolman,. (2010-08-03) Mechanistic study of the stereoselective polymerization of D,L-lactide using indium(III) halides.. Journal of the American Chemical Society, 132 ((33)): ( 11649-11657 ). [PMID:20672812]
11. Neelakandan Vidhya Lakshmi,Prakasam Thirumurugan,K M Noorulla,Paramasivan T Perumal. (2010-08-03) InCl3 mediated one-pot multicomponent synthesis, anti-microbial, antioxidant and anticancer evaluation of 3-pyranyl indole derivatives.. Bioorganic & medicinal chemistry letters, 20 ((17)): (5054-5061). [PMID:20675130]
12. David S Giera,Christoph Schneider. (2010-10-01) InCl3-catalyzed allylic Friedel-Crafts reactions toward the stereocontrolled synthesis of 1,2,3,4-tetrahydroquinolines.. Organic letters, 12 ((21)): (4884-4887). [PMID:20879793]
13. Masateru Ono,Ayako Takigawa,Tomoko Mineno,Hitoshi Yoshimitsu,Toshihiro Nohara,Tsuyoshi Ikeda,Emiko Fukuda-Teramachi,Naoki Noda,Kazumoto Miyahara. (2010-10-14) Acylated glycosides of hydroxy fatty acid methyl esters generated from the crude resin glycoside (pharbitin) of seeds of Pharbitis nil by treatment with indium(III) chloride in methanol.. Journal of natural products, 73 ((11)): (1846-1852). [PMID:20939542]
14. B V Subba Reddy,M Ramana Reddy,Ch Madan,K Pranay Kumar,M Srinivasa Rao. (2010-11-12) Indium(III) chloride catalyzed three-component coupling reaction: a novel synthesis of 2-substituted aryl(indolyl)kojic acid derivatives as potent antifungal and antibacterial agents.. Bioorganic & medicinal chemistry letters, 20 ((24)): (7507-7511). [PMID:21067928]
15. Ryo Takagi,Yuji Suzuki,Yoshiko Seki,Masateru Ikehata,Chieko Kajihara,Hidesuke Shimizu,Hiroyuki Yanagisawa. (2011-02-18) Indium chloride-induced micronuclei in in vivo and in vitro experimental systems.. Journal of occupational health, 53 ((2)): (102-109). [PMID:21325779]
16. Yan-li Xu,Ying-ming Pan,Qiang Wu,Heng-shan Wang,Pei-zhen Liu. (2011-09-16) Regioselective synthesis of 1,3,5-substituted benzenes via the InCl(3)/2-iodophenol-catalyzed cyclotrimerization of alkynes.. The Journal of organic chemistry, 76 ((20)): (8472-8476). [PMID:21916477]
17. Amarnadh Nalla,Inge Buch,Birger Hesse. (2011-12-24) Easy and efficient (111)indium labeling of long-term stored DTPA conjugated protein.. Current radiopharmaceuticals, 4 ((1)): (1-4). [PMID:22191609]
18. Tanmoy Chanda,Rajiv Kumar Verma,Maya Shankar Singh. (2012-02-09) InCl3-driven regioselective synthesis of functionalized/annulated quinolines: scope and limitations.. Chemistry, an Asian journal, 7 ((4)): (778-787). [PMID:22311639]
19. Naveen Mulakayala,Bhaskar Kandagatla,Ismail,Rajesh Kumar Rapolu,Pallavi Rao,Chaitanya Mulakayala,Chitta Suresh Kumar,Javed Iqbal,Srinivas Oruganti. (2012-07-04) InCl3-catalysed synthesis of 2-aryl quinazolin-4(3H)-ones and 5-aryl pyrazolo[4,3-d]pyrimidin-7(6H)-ones and their evaluation as potential anticancer agents.. Bioorganic & medicinal chemistry letters, 22 ((15)): (5063-5066). [PMID:22749421]
20. Chepuri V Suneel Kumar,Vedavati G Puranik,Chepuri V Ramana. (2012-07-06) InCl3-mediated addition of indole to isatogens: an expeditious synthesis of 13-deoxy-isatisine\u2005A.. Chemistry (Weinheim an der Bergstrasse, Germany), 18 ((31)): (9601-9611). [PMID:22763920]
21. Christine Rangger,Anna Helbok,Elisabeth von Guggenberg,Jane Sosabowski,Thorsten Radolf,Ruth Prassl,Fritz Andreae,Gudrun C Thurner,Roland Haubner,Clemens Decristoforo. (2012-12-12) Influence of PEGylation and RGD loading on the targeting properties of radiolabeled liposomal nanoparticles.. International journal of nanomedicine, 7 (5889-5900). [PMID:23226020]
22. Sebastian Bernhardt,Zhi-Liang Shen,Paul Knochel. (2012-12-21) Preparation of functionalized organoindium reagents by means of magnesium insertion into organic halides in the presence of InCl3 at room temperature.. Chemistry (Weinheim an der Bergstrasse, Germany), 19 ((3)): (828-833). [PMID:23255158]
23. Ruey-Hseng Lin,Ming-Ling Yang,Yi-Ching Li,Hui-Min Chang,Yu-Hsiang Kuan. (2013-09-12) Indium chloride-induced micronuclei via reactive oxygen species in Chinese hamster lung fibroblast V79 cells.. Environmental toxicology, 28 ((10)): (595-600). [PMID:24022999]
24. S Kobayashi,T Busujima,S Nagayama. (2000-11-10) A novel classification of Lewis acids on the basis of activity and selectivity.. Chemistry (Weinheim an der Bergstrasse, Germany), 6 ((19)): (3491-3494). [PMID:11072812]
25. Yunhua Chen,Jieping Wan,Chunyan Wang,Cuirong Sun. (2008-10-31) Diastereoselective synthesis of cyclopentanediols by InCl 3/Al mediated intramolecular pinacol coupling reaction in aqueous media.. Molecules (Basel, Switzerland), 13 ((10)): (2652-2658). [PMID:18971861]
26. Bo-Yu Li,Zhong-Jun Li,Xiang-Bao Meng. (2010-06-30) InCl(3)-catalyzed asymmetric aza-Friedel-Crafts reaction of indoles with imines generated from O-pivaloylated beta-D-galactosylamine.. Carbohydrate research, 345 ((12)): (1708-1712). [PMID:20584527]

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Indium(III) chloride hydrate - ~39% indium basis, 2-3 mol/mol water, high purity , CAS No.10025-82-8

Basic Description

Names and Identifiers

Certificates

Certificate of Analysis(COA)

Chemical and Physical Properties

Safety and Hazards(GHS)

Related Documents

References

Solution Calculators

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Dilution Calculator

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SKU	Size	Availability	Price	Qty
I431124-10g	10g	Available within 8-12 weeks(?) Production requires sourcing of materials. We appreciate your patience and understanding.	$223.90
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