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Iodotrimethylsilane - 97%,contains Copper scrap as stabilizer, high purity , CAS No.16029-98-4

12 Citations
  • ≥97%
  • stabilized with copper scrap
Item Number
I100104
Grouped product items
SKUSizeAvailabilityPrice Qty
I100104-5g
5g
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$24.90
I100104-25g
25g
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$90.90
I100104-100g
100g
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$275.90
I100104-250g
250g
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$519.90
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Organosilane Protection/Deprotection Reagents

Basic Description

SynonymsA810132 | Iodotrimethylsilane, purum, >=98.0% (AT) | DTXSID4065997 | F15417 | UNII-7A65KRZ6NV | iodo trimethylsilane | SCHEMBL216 | FT-0656496 | tms-iodide | Iodotrimethylsilane | iodo-trimethylsilane | Iodo-trimethyl-silane | iodotrimethyl-silane | BCP18
Specifications & Purity≥97%, stabilized with copper scrap
Storage TempProtected from light,Store at -20°C,Argon charged
Shipped InIce chest + Ice pads
Product Description

Iodotrimethylsilane is an efficient reagent for ether, ester, carbamate, ketal, and lactone cleavage.Reagent was recently reported to convert allyl- and benzylphosphotriesters to the corresponding iodides. For the introduction of the TMS group, e.g., TMS enol ethers.
An efficient reagent for ether, ester, carbamate, ketal, and lactone cleavage；Efficient reagent for cleaving ethers, esters, carbamates, ketals, and lactones. For the introduction of the TMS group, e.g., TMS enol ethers.Key reagent for the selective deprotection of an N-Cbz group in the presence of a trimethyltin moiety. Reagent was recently reported to convert allyl- and benzylphosphotriesters to the corresponding iodides.

Iodotrimethylsilane is used for the introduction of trimethylsilyl group in organic synthesis. It is also useful for gas chromatography analysis by converting alcohol into a silyl ether derivative, thereby making it more volatile than the original molecule.

Names and Identifiers

IUPAC Name iodo(trimethyl)silane
INCHI InChI=1S/C3H9ISi/c1-5(2,3)4/h1-3H3
InChi Key CSRZQMIRAZTJOY-UHFFFAOYSA-N
Canonical SMILES C[Si](C)(C)I
Isomeric SMILES C[Si](C)(C)I
WGK Germany 3
PubChem CID 85247
UN Number 2924
Molecular Weight 200.09
Beilstein 1731136
Reaxy-Rn 1731136

Certificates

Certificate of Analysis(COA)

Enter Lot Number to search for COA:

Find and download the COA for your product by matching the lot number on the packaging.

36 results found

Lot NumberCertificate TypeDateItem
J2422448Certificate of AnalysisSep 25, 2024 I100104
J2422447Certificate of AnalysisSep 25, 2024 I100104
J2422446Certificate of AnalysisSep 25, 2024 I100104
J2422445Certificate of AnalysisSep 25, 2024 I100104
J2422443Certificate of AnalysisSep 25, 2024 I100104
J2409856Certificate of AnalysisJul 13, 2024 I100104
C2409127Certificate of AnalysisJun 18, 2024 I100104
C2409129Certificate of AnalysisJun 18, 2024 I100104
A2402046Certificate of AnalysisApr 07, 2024 I100104
A2402340Certificate of AnalysisApr 07, 2024 I100104
A2402045Certificate of AnalysisApr 07, 2024 I100104
K2327101Certificate of AnalysisMar 20, 2024 I100104
G2319458Certificate of AnalysisNov 10, 2023 I100104
G2319795Certificate of AnalysisNov 10, 2023 I100104
D2303480Certificate of AnalysisJul 18, 2023 I100104
D2303481Certificate of AnalysisJul 18, 2023 I100104
G2319376Certificate of AnalysisJul 11, 2023 I100104
G2319377Certificate of AnalysisJul 11, 2023 I100104
G2319781Certificate of AnalysisJul 11, 2023 I100104
H2114167Certificate of AnalysisApr 12, 2023 I100104
H2114165Certificate of AnalysisSep 13, 2022 I100104
G2230178Certificate of AnalysisJun 16, 2022 I100104
G2230181Certificate of AnalysisJun 16, 2022 I100104
G2230180Certificate of AnalysisJun 16, 2022 I100104
G2230179Certificate of AnalysisJun 16, 2022 I100104
G2230177Certificate of AnalysisJun 16, 2022 I100104
H2114168Certificate of AnalysisApr 26, 2022 I100104
C2215285Certificate of AnalysisApr 24, 2022 I100104
C2209229Certificate of AnalysisMar 15, 2022 I100104
K2123500Certificate of AnalysisMar 10, 2022 I100104
K2123501Certificate of AnalysisMar 10, 2022 I100104
K2123559Certificate of AnalysisMar 10, 2022 I100104
H2114164Certificate of AnalysisDec 03, 2021 I100104
C2203070Certificate of AnalysisNov 09, 2021 I100104
B2208082Certificate of AnalysisNov 09, 2021 I100104
F2221237Certificate of AnalysisJun 16, 2021 I100104

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Chemical and Physical Properties

SolubilityMiscible with water.
SensitivityMoisture & Light Sensitive
Refractive Index 1.47-1.48
Flash Point(°F)28°F
Flash Point(°C)-2℃
Boil Point(°C)106°C

Safety and Hazards(GHS)

Pictogram(s) GHS05,   GHS02
Signal Danger
Hazard Statements

H314:Causes severe skin burns and eye damage

H225:Highly Flammable liquid and vapor

Precautionary Statements

P280:Wear protective gloves/protective clothing/eye protection/face protection.

P370+P378:In case of fire: Use ... to extinguish.

P210:Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking.

P321:Specific treatment (see ... on this label).

P405:Store locked up.

P501:Dispose of contents/container to ...

P233:Keep container tightly closed.

P240:Ground/bond container and receiving equipment.

P264:Wash hands [and …] thoroughly after handling.

P403+P235:Store in a well-ventilated place. Keep cool.

P260:Do not breathe dust/fume/gas/mist/vapors/spray.

P303+P361+P353:IF ON SKIN (or hair): Take off Immediately all contaminated clothing. Rinse SKIN with water [or shower].

P241:Use explosion-proof [electrical/ventilating/lighting/.../] equipment.

P301+P330+P331:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P363:Wash contaminated clothing before reuse.

P242:Use only non-sparking tools.

P243:Take precautionary measures against static discharge.

P305+P354+P338:IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing.

P302+P361+P354:IF ON SKIN: Take off Immediately all contaminated clothing. Immediately rinse with water for several minutes.

P316:Get emergency medical help immediately.

WGK Germany 3
Reaxy-Rn 1731136

Related Documents

 SDS

 Specification Sheet

Alternative Products

  1. Diiodosilane - 98%，contains copper as stabilizer, used for , CAS No. 13760-02-6, by Aladdin Scientific
    Diiodosilane
    • ≥98%
    • stabilized with copper

    Starting at $95.90

Citations of This Product

How to Cite Aladdin Scientific Products?
1. Lei Chen, Weiyu Luo, Yima He, Lizhen Huang, Jinjie Xu, Kaixin Li, Yonggang Min.  (2023)  High-Performance Polyimide Films Derived from Biomass-Based Furfural: Fabrication and Properties.  Coatings,  13  (10): (1726).  [PMID:28191891] [10.3390/coatings13101726]
2. Xiaowei Yu, Kaikai Liu, Bolun Wang, Hongyue Zhang, Yuanyuan Qi, Jihong Yu.  (2022)  Time-Dependent Polychrome Stereoscopic Luminescence Triggered by Resonance Energy Transfer between Carbon Dots-in-Zeolite Composites and Fluorescence Quantum Dots.  ADVANCED MATERIALS,  35  (6): (2208735).  [PMID:36446033] [10.1002/adma.202208735]
3. Jingxuan Chen, Donglin Jia, Rongshan Zhuang, Yong Hua, Xiaoliang Zhang.  (2022)  Highly Orientated Perovskite Quantum Dot Solids for Efficient Solar Cells.  ADVANCED MATERIALS,  34  (37): (2204259).  [PMID:35905705] [10.1002/adma.202204259]
4. Ying Li, Jiahui Wang, Qing Yang, Guozhen Shen.  (2022)  Flexible Artificial Optoelectronic Synapse based on Lead-Free Metal Halide Nanocrystals for Neuromorphic Computing and Color Recognition.  Advanced Science,  9  (22): (2202123).  [PMID:35661449] [10.1002/advs.202202123]
5. Qing Tian, Guozhen Ding, Yuting Cai, Zicheng Li, Xueyuan Tang, Rong-Jun Xie, Peng Gao.  (2021)  Enhanced Performance of Perovskite Solar Cells Loaded with Iodine-Rich CsPbI3 Quantum Dots.  ACS Applied Energy Materials,  4  (8): (7535–7543).  [PMID:] [10.1021/acsaem.1c00517]
6. Zhenxing Fang, Kuang Wu, Le Wang, Da Xu, Weiwei Wang, Yuhang Lin, Xiaohui Liu, Chun Sun.  (2021)  Highly efficient and blue-excitable Mn-doped PEA2Pb(Br/I)4 perovskite for solid lighting.  JOURNAL OF LUMINESCENCE,  237  (118155).  [PMID:] [10.1016/j.jlumin.2021.118155]
7. Menglong Liu, Naizhong Jiang, Hai Huang, Jidong Lin, Feng Huang, Yongping Zheng, Daqin Chen.  (2021)  Ni2+-doped CsPbI3 perovskite nanocrystals with near-unity photoluminescence quantum yield and superior structure stability for red light-emitting devices.  CHEMICAL ENGINEERING JOURNAL,  413  (127547).  [PMID:] [10.1016/j.cej.2020.127547]
8. Jun-Nan Yang, Yang Song, Ji-Song Yao, Kun-Hua Wang, Jing-Jing Wang, Bai-Sheng Zhu, Ming-Ming Yao, Sami Ur Rahman, Yi-Feng Lan, Feng-Jia Fan, Hong-Bin Yao.  (2020)  Potassium Bromide Surface Passivation on CsPbI3-xBrx Nanocrystals for Efficient and Stable Pure Red Perovskite Light-Emitting Diodes.  Journal of the American Chemical Society,  142  (6): (2956–2967).  [PMID:31902206] [10.1021/jacs.9b11719]
9. Xiaoli Zhu, Jibo Dou, Qiang Huang, Xiaoyong Zhang, Yen Wei.  (2019)  Introducing the Kabachnik–Fields multicomponent reaction for functionalization of multiwalled carbon nanotubes and their performance for removal of methylene blue.  Journal of the Taiwan Institute of Chemical Engineers,  100  (85).  [PMID:] [10.1016/j.jtice.2019.04.008]
10. Ji-Song Yao, Jing Ge, Kun-Hua Wang, Guozhen Zhang, Bai-Sheng Zhu, Chen Chen, Qun Zhang, Yi Luo, Shu-Hong Yu, Hong-Bin Yao.  (2019)  Few-Nanometer-Sized α-CsPbI3 Quantum Dots Enabled by Strontium Substitution and Iodide Passivation for Efficient Red-Light Emitting Diodes.  Journal of the American Chemical Society,  141  (5): (2069–2079).  [PMID:30616341] [10.1021/jacs.8b11447]
11. Ruming Jiang, Meiying Liu, Hongye Huang, Long Huang, Qiang Huang, Yuanqing Wen, Qian-yong Cao, Jianwen Tian, Xiaoyong Zhang, Yen Wei.  (2018)  A novel self-catalyzed photoATRP strategy for preparation of fluorescent hydroxyapatite nanoparticles and their biological imaging.  APPLIED SURFACE SCIENCE,  434  (1129).  [PMID:] [10.1016/j.apsusc.2017.11.039]
12. Shifeng Yan, Yuanyuan Sun, An Chen, Lei Liu, Kunxi Zhang, Guifei Li, Yourong Duan, Jingbo Yin.  (2017)  Templated fabrication of pH-responsive poly(L-glutamic acid) based nanogels via surface-grafting and macromolecular crosslinking.  RSC Advances,  7  (24): (14888-14901).  [PMID:] [10.1039/C7RA00631D]

References

1. M Numazawa,M Nagaoka,Y Kunitama.  (1986-09-01)  Regiospecific deoxygenation of the dihydroxyacetone moiety at C-17 of corticoid steroids with iodotrimethylsilane..  Chemical & pharmaceutical bulletin,  34  ((9)): (3722-3726).  [PMID:3815593]
2. M Sako,T Kihara,K Okada,Y Ohtani,H Kawamoto.  (2001-05-12)  Reductive cleavage of heteroaryl c-halogen bonds by iodotrimethylsilane. Facile and regioselective dechlorination of antibiotic pyrrolnitrin..  The Journal of organic chemistry,  66  ((10)): (3610-3612).  [PMID:11348155]
3. Manuel Montejo,Sarah L Hinchley,A Ben Altabef,Heather E Robertson,Francisco Partal Ureña,David W H Rankin,Juan J López González.  (2006-02-17)  An experimental and theoretical study of the molecular structure and vibrational spectra of iodotrimethylsilane (SiIMe3)..  Physical chemistry chemical physics : PCCP,  8  ((4)): (477-485).  [PMID:16482290]
4. Qing Zhu,Matthew S Tremblay.  (2006-10-20)  Allyl and benzyl iodides by the anomalous action of iodotrimethylsilane..  Bioorganic & medicinal chemistry letters,  16  ((24)): (6170-6172).  [PMID:17049854]
5. Bin Huang,Xiaoman Li,Wenwen Sun,Dong Ren,Xiao Li,Xiaonan Li,Ying Liu,Qiang Li,Xuejun Pan.  (2014-07-01)  Occurrence, removal, and fate of progestogens, androgens, estrogens, and phenols in six sewage treatment plants around Dianchi Lake in China..  Environmental science and pollution research international,  21  ((22)): (12898-12908).  [PMID:24974791]
6. Erick J Rendón-Ramirez,Alejandro Ortiz-Stern,Corazon Martinez-Mejia,Mario C Salinas-Carmona,Adrian Rendon,Viviana L Mata-Tijerina,Adrian G Rosas-Taraco.  (2015-04-30)  TGF-β Blood Levels Distinguish Between Influenza A (H1N1)pdm09 Virus Sepsis and Sepsis due to Other Forms of Community-Acquired Pneumonia..  Viral immunology,  28  ((5)): (248-254).  [PMID:25923384]
7. Michael C De Siena,Sidney E Creutz,Annie Regan,Paul Malinowski,Qianni Jiang,Kyle T Kluherz,Guomin Zhu,Zhong Lin,James J De Yoreo,Xiaodong Xu,Jiun-Haw Chu,Daniel R Gamelin.  (2020-02-08)  Two-Dimensional van der Waals Nanoplatelets with Robust Ferromagnetism..  Nano letters,  20  ((3)): (2100-2106).  [PMID:32031382]
8. Z Tocik,R A Earl,J Beránek.  (1980-10-24)  The use of iodotrimethylsilane in nucleosidation procedure..  Nucleic acids research,  8  ((20)): (4755-4761).  [PMID:7443524]
9. Yu-Fon Chen,Chien-Hsiang Chang,Ching-Yu Lin,Li-Fang Lin,Ming-Lung Yeh,Jeng-Shiung Jan.  (2018-02-27)  Disulfide-cross-linked PEG-block-polypeptide nanoparticles with high drug loading content as glutathione-triggered anticancer drug nanocarriers..  Colloids and surfaces. B, Biointerfaces,  165  (172-181).  [PMID:29482128]
10. Lei Chen, Weiyu Luo, Yima He, Lizhen Huang, Jinjie Xu, Kaixin Li, Yonggang Min.  (2023)  High-Performance Polyimide Films Derived from Biomass-Based Furfural: Fabrication and Properties.  Coatings,  13  (10): (1726).  [PMID:28191891] [10.3390/coatings13101726]
11. Xiaowei Yu, Kaikai Liu, Bolun Wang, Hongyue Zhang, Yuanyuan Qi, Jihong Yu.  (2022)  Time-Dependent Polychrome Stereoscopic Luminescence Triggered by Resonance Energy Transfer between Carbon Dots-in-Zeolite Composites and Fluorescence Quantum Dots.  ADVANCED MATERIALS,  35  (6): (2208735).  [PMID:36446033] [10.1002/adma.202208735]
12. Jingxuan Chen, Donglin Jia, Rongshan Zhuang, Yong Hua, Xiaoliang Zhang.  (2022)  Highly Orientated Perovskite Quantum Dot Solids for Efficient Solar Cells.  ADVANCED MATERIALS,  34  (37): (2204259).  [PMID:35905705] [10.1002/adma.202204259]
13. Ying Li, Jiahui Wang, Qing Yang, Guozhen Shen.  (2022)  Flexible Artificial Optoelectronic Synapse based on Lead-Free Metal Halide Nanocrystals for Neuromorphic Computing and Color Recognition.  Advanced Science,  9  (22): (2202123).  [PMID:35661449] [10.1002/advs.202202123]
14. Qing Tian, Guozhen Ding, Yuting Cai, Zicheng Li, Xueyuan Tang, Rong-Jun Xie, Peng Gao.  (2021)  Enhanced Performance of Perovskite Solar Cells Loaded with Iodine-Rich CsPbI3 Quantum Dots.  ACS Applied Energy Materials,  4  (8): (7535–7543).  [PMID:] [10.1021/acsaem.1c00517]
15. Zhenxing Fang, Kuang Wu, Le Wang, Da Xu, Weiwei Wang, Yuhang Lin, Xiaohui Liu, Chun Sun.  (2021)  Highly efficient and blue-excitable Mn-doped PEA2Pb(Br/I)4 perovskite for solid lighting.  JOURNAL OF LUMINESCENCE,  237  (118155).  [PMID:] [10.1016/j.jlumin.2021.118155]
16. Menglong Liu, Naizhong Jiang, Hai Huang, Jidong Lin, Feng Huang, Yongping Zheng, Daqin Chen.  (2021)  Ni2+-doped CsPbI3 perovskite nanocrystals with near-unity photoluminescence quantum yield and superior structure stability for red light-emitting devices.  CHEMICAL ENGINEERING JOURNAL,  413  (127547).  [PMID:] [10.1016/j.cej.2020.127547]
17. Jun-Nan Yang, Yang Song, Ji-Song Yao, Kun-Hua Wang, Jing-Jing Wang, Bai-Sheng Zhu, Ming-Ming Yao, Sami Ur Rahman, Yi-Feng Lan, Feng-Jia Fan, Hong-Bin Yao.  (2020)  Potassium Bromide Surface Passivation on CsPbI3-xBrx Nanocrystals for Efficient and Stable Pure Red Perovskite Light-Emitting Diodes.  Journal of the American Chemical Society,  142  (6): (2956–2967).  [PMID:31902206] [10.1021/jacs.9b11719]
18. Xiaoli Zhu, Jibo Dou, Qiang Huang, Xiaoyong Zhang, Yen Wei.  (2019)  Introducing the Kabachnik–Fields multicomponent reaction for functionalization of multiwalled carbon nanotubes and their performance for removal of methylene blue.  Journal of the Taiwan Institute of Chemical Engineers,  100  (85).  [PMID:] [10.1016/j.jtice.2019.04.008]
19. Ji-Song Yao, Jing Ge, Kun-Hua Wang, Guozhen Zhang, Bai-Sheng Zhu, Chen Chen, Qun Zhang, Yi Luo, Shu-Hong Yu, Hong-Bin Yao.  (2019)  Few-Nanometer-Sized α-CsPbI3 Quantum Dots Enabled by Strontium Substitution and Iodide Passivation for Efficient Red-Light Emitting Diodes.  Journal of the American Chemical Society,  141  (5): (2069–2079).  [PMID:30616341] [10.1021/jacs.8b11447]
20. Ruming Jiang, Meiying Liu, Hongye Huang, Long Huang, Qiang Huang, Yuanqing Wen, Qian-yong Cao, Jianwen Tian, Xiaoyong Zhang, Yen Wei.  (2018)  A novel self-catalyzed photoATRP strategy for preparation of fluorescent hydroxyapatite nanoparticles and their biological imaging.  APPLIED SURFACE SCIENCE,  434  (1129).  [PMID:] [10.1016/j.apsusc.2017.11.039]
21. Shifeng Yan, Yuanyuan Sun, An Chen, Lei Liu, Kunxi Zhang, Guifei Li, Yourong Duan, Jingbo Yin.  (2017)  Templated fabrication of pH-responsive poly(L-glutamic acid) based nanogels via surface-grafting and macromolecular crosslinking.  RSC Advances,  7  (24): (14888-14901).  [PMID:] [10.1039/C7RA00631D]

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