Iridium chloride hydrate - Ir 48.0 - 55.0 %, high purity , CAS No.10025-97-5

  • Ir 48.0 - 55.0 %
Item Number
I111024
Grouped product items
SKUSizeAvailabilityPrice Qty
I111024-250mg
250mg
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$139.90
I111024-1g
1g
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$445.90
I111024-5g
5g
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$1,759.90
View related series
Transition metal catalyst

Basic Description

SynonymsCl4Ir | UNII-PCG7KVC21I | IRIDIUM(IV) CHLORIDE [HSDB] | PCG7KVC21I | MFCD00016155 | Q4498214 | AKOS015914776 | IRIDIUM TETRACHLORIDE | CALMYRPSSNRCFD-UHFFFAOYSA-J | HSDB 6342 | DTXSID10893602 | tetrachloroiridium | CS-0042250 | Iridium(IV)chloride | Iridi
Specifications & PurityIr 48.0 - 55.0 %
Storage TempArgon charged
Shipped InNormal
Product Description

Iridium(IV) chloride is used in chemical analysis as testing for nitric acid in the presence of nitrous acid, microscopy and in plating solutions. It acts as a catalyst precursor for the stereoselective reduction of cyclohexanones.

Names and Identifiers

IUPAC Name tetrachloroiridium
INCHI InChI=1S/4ClH.Ir/h4*1H;/q;;;;+4/p-4
InChi Key CALMYRPSSNRCFD-UHFFFAOYSA-J
Canonical SMILES O.Cl[Ir](Cl)(Cl)Cl
Isomeric SMILES Cl[Ir](Cl)(Cl)Cl
Alternate CAS 207399-11-9
PubChem CID 24815
Molecular Weight 334.03(anhydrous)

Certificates

Certificate of Analysis(COA)

Enter Lot Number to search for COA:

Find and download the COA for your product by matching the lot number on the packaging.

4 results found

Lot NumberCertificate TypeDateItem
F2224493Certificate of AnalysisJun 02, 2022 I111024
F2224494Certificate of AnalysisJun 02, 2022 I111024
K2301114Certificate of AnalysisJun 02, 2022 I111024
B2302397Certificate of AnalysisAug 10, 2021 I111024

Chemical and Physical Properties

SolubilitySoluble in water, alcohol, and dilute hydrochloric acid.
SensitivityHygroscopic
Melt Point(°C)>350°C

Safety and Hazards(GHS)

Pictogram(s) GHS07
Signal Warning
Hazard Statements

H315:Causes skin irritation

H319:Causes serious eye irritation

H335:May cause respiratory irritation

H302:Harmful if swallowed

Precautionary Statements

P261:Avoid breathing dust/fume/gas/mist/vapors/spray.

P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.

P280:Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352:IF ON SKIN: wash with plenty of water.

P321:Specific treatment (see ... on this label).

P405:Store locked up.

P501:Dispose of contents/container to ...

P264:Wash hands [and …] thoroughly after handling.

P271:Use only outdoors or in a well-ventilated area.

P270:Do not eat, drink or smoke when using this product.

P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P403+P233:Store in a well-ventilated place. Keep container tightly closed.

P362+P364:Take off contaminated clothing and wash it before reuse.

P330:Rinse mouth.

P264+P265:Wash hands [and …] thoroughly after handling. Do not touch eyes.

P301+P317:IF SWALLOWED: Get medical help.

P337+P317:If eye irritation persists: Get medical help.

P332+P317:If skin irritation occurs: Get medical help.

P319:Get medical help if you feel unwell.

Related Documents

Citations of This Product

1. Zeyu Guan, Jiankun Li, Shiyi Li, Keyu Wang, Linfeng Lei, Yixing Wang, Linzhou Zhuang, Zhi Xu.  (2024)  The transient covering of iridium species with ultrathin carbon shells via Joule-heating for robust acidic water oxidation.  Materials Chemistry Frontiers,  (3): (824-835).  [PMID:9813312] [10.1039/D3QM00973D]
2. Yiming Jiang, Juncai Leng, Shiqi Zhang, Tingyi Zhou, Mingxuan Liu, Shuoming Liu, Yahui Gao, Jianwei Zhao, Lei Yang, Li Li, Wei Zhao.  (2023)  Modulating Water Splitting Kinetics via Charge Transfer and Interfacial Hydrogen Spillover Effect for Robust Hydrogen Evolution Catalysis in Alkaline Media.  Advanced Science,  10  (24): (2302358).  [PMID:37350571] [10.1002/advs.202302358]
3. Ye Zhang, Xia Kang, Dong-Xue Liu, Ze-Yu Chen.  (2022)  Highly efficient dehydrogenation of hydrazine borane over CoIr/TiO2 catalyst.  INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,  47  (36823).  [PMID:] [10.1016/j.ijhydene.2022.08.252]
4. Tao Liu, Yuxin Chen, Yaming Hao, Jianxiang Wu, Ran Wang, Limin Gu, Xuejing Yang, Qiang Yang, Cheng Lian, Honglai Liu, Ming Gong.  (2022)  Hierarchical anions at the electrode-electrolyte interface for synergized neutral water oxidation.  Chem,  (2700-2714).  [PMID:] [10.1016/j.chempr.2022.06.012]
5. Weibin Chen, Yuxin Xie, Xuehui Gao, Lei Li, Zhan Lin.  (2022)  Simultaneous optimization of CoIr alloy nanoparticles and 2D graphitic-N doped carbon support in CoIr@CN by Ir doping for enhanced oxygen and hydrogen evolution reactions.  Journal of Materials Chemistry A,  10  (29): (15543-15553).  [PMID:] [10.1039/D2TA03496D]
6. You Xu, Mengying Liu, Mingzhen Wang, Tianlun Ren, Kaili Ren, Ziqiang Wang, Xiaonian Li, Liang Wang, Hongjing Wang.  (2022)  Methanol electroreforming coupled to green hydrogen production over bifunctional NiIr-based metal-organic framework nanosheet arrays.  APPLIED CATALYSIS B-ENVIRONMENTAL,  300  (120753).  [PMID:] [10.1016/j.apcatb.2021.120753]
7. Chunlei Peng, Wanpeng Zhao, Zhaoxia Li, Zhaoyu Kuang, Guofeng Cheng, Jeffery T. Miller, Shuhui Sun, Hangrong Chen.  (2021)  Eutectic molten salt assisted synthesis of highly defective and flexible ruthenium oxide for efficient overall water splitting.  CHEMICAL ENGINEERING JOURNAL,  425  (131707).  [PMID:] [10.1016/j.cej.2021.131707]
8. Qi Xue, Hui-Ying Sun, Ya-Nan Li, Ming-Jun Zhong, Fu-Min Li, Xinlong Tian, Pei Chen, Shi-Bin Yin, Yu Chen.  (2021)  Au@Ir core-shell nanowires towards oxygen reduction reaction.  CHEMICAL ENGINEERING JOURNAL,  421  (129760).  [PMID:] [10.1016/j.cej.2021.129760]
9. Xiaoqian Jiang, Xiaoyu Wang, Anqi Lin, Hui Wei.  (2021)  In Situ Exsolution of Noble-Metal Nanoparticles on Perovskites as Enhanced Peroxidase Mimics for Bioanalysis.  ANALYTICAL CHEMISTRY,  93  (14): (5954–5962).  [PMID:33797896] [10.1021/acs.analchem.1c00721]
10. Jingru Wang, Shanhui Zhu, Yunwei Wang, Yingyong Wang, Guoqiang Jin, Xili Tong, Xiangyun Guo.  (2021)  Enhanced activity of Ru-Ir nanoparticles over SiC for hydrogenation of levulinic acid at room-temperature.  MATERIALS RESEARCH BULLETIN,  135  (111128).  [PMID:] [10.1016/j.materresbull.2020.111128]
11. Jinhui Zhu, Min Wei, Qinghao Meng, Zhenyu Chen, Yepeng Fan, Syed Waqar Hasan, Xiaoran Zhang, Dandan Lyu, Zhi Qun Tian, Pei Kang Shen.  (2020)  Ultrathin-shell IrCo hollow nanospheres as highly efficient electrocatalysts towards the oxygen evolution reaction in acidic media.  Nanoscale,  12  (47): (24070-24078).  [PMID:33241831] [10.1039/D0NR06601J]
12. You Xu, Xingjie Chai, Mengying Liu, Tianlun Ren, Shanshan Yu, Ziqiang Wang, Xiaonian Li, Liang Wang, Hongjing Wang.  (2020)  Two-Dimensional NiIr@N-Doped Carbon Nanocomposites Supported on Ni Foam for Electrocatalytic Overall Water Splitting.  CHEMISTRY-A EUROPEAN JOURNAL,  26  (63): (14496-14501).  [PMID:32841440] [10.1002/chem.202003473]
13. Qinxin Luo, Dan Lin, Wenqi Zhan, Wanqun Zhang, Lulu Tang, Jingjing Luo, Zhan Gao, Peng Jiang, Miao Wang, LuYuan Hao, Kaibin Tang.  (2020)  Hexagonal Perovskite Ba0.9Sr0.1Co0.8Fe0.1Ir0.1O3−δ as an Efficient Electrocatalyst towards the Oxygen Evolution Reaction.  ACS Applied Energy Materials,  (7): (7149–7158).  [PMID:] [10.1021/acsaem.0c01192]
14. Feng Guo, Hongtao Zou, Qilu Yao, Bin Huang, Zhang-Hui Lu.  (2020)  Monodispersed bimetallic nanoparticles anchored on TiO2-decorated titanium carbide MXene for efficient hydrogen production from hydrazine in aqueous solution.  RENEWABLE ENERGY,  155  (1293).  [PMID:] [10.1016/j.renene.2020.04.047]
15. Wendan Nie, Yixing Luo, Qifeng Yang, Gang Feng, Qilu Yao, Zhang-Hui Lu.  (2020)  An amine-functionalized mesoporous silica-supported PdIr catalyst: boosting room-temperature hydrogen generation from formic acid.  Inorganic Chemistry Frontiers,  (3): (709-717).  [PMID:] [10.1039/C9QI01375J]
16. Qilu Yao, Meng He, Xiaoling Hong, Xiaoliang Zhang, Zhang-Hui Lu.  (2019)  MoOx-modified bimetallic alloy nanoparticles for highly efficient hydrogen production from hydrous hydrazine.  Inorganic Chemistry Frontiers,  (6): (1546-1552).  [PMID:] [10.1039/C9QI00379G]
17. Junnan Li, Ziwei Pan, Kebin Zhou.  (2018)  Enhanced photocatalytic oxygen evolution activity by formation of Ir@IrOx(OH)y core–shell heterostructure.  NANOTECHNOLOGY,  29  (40): (405705).  [PMID:30015623] [10.1088/1361-6528/aad3f4]
18. Lu Wangting, Zhang Geng, Wei Feng, Li Wenhui, Cheng Kun, Ding Fei, Zhang Jiying, Zheng Wanquan.  (2017)  Shape-controlled synthesis of Pd nanocrystals in an aqueous solution by using amphiphilic triblock copolymers as both the stabilizer and the reductant.  COLLOID AND POLYMER SCIENCE,  295  (4): (703-707).  [PMID:] [10.1007/s00396-017-4041-9]
19. Yuan Gao, Ming Hou, Zhigang Shao, Changkun Zhang, Xiaoping Qin, Baolian Yi.  (2015)  Highly effective oxygen reduction activity and durability of antimony-doped tin oxide modified PtPd/C electrocatalysts.  RSC Advances,  (85): (69479-69486).  [PMID:] [10.1039/C5RA10162J]

References

1. Zeyu Guan, Jiankun Li, Shiyi Li, Keyu Wang, Linfeng Lei, Yixing Wang, Linzhou Zhuang, Zhi Xu.  (2024)  The transient covering of iridium species with ultrathin carbon shells via Joule-heating for robust acidic water oxidation.  Materials Chemistry Frontiers,  (3): (824-835).  [PMID:9813312] [10.1039/D3QM00973D]
2. Yiming Jiang, Juncai Leng, Shiqi Zhang, Tingyi Zhou, Mingxuan Liu, Shuoming Liu, Yahui Gao, Jianwei Zhao, Lei Yang, Li Li, Wei Zhao.  (2023)  Modulating Water Splitting Kinetics via Charge Transfer and Interfacial Hydrogen Spillover Effect for Robust Hydrogen Evolution Catalysis in Alkaline Media.  Advanced Science,  10  (24): (2302358).  [PMID:37350571] [10.1002/advs.202302358]
3. Ye Zhang, Xia Kang, Dong-Xue Liu, Ze-Yu Chen.  (2022)  Highly efficient dehydrogenation of hydrazine borane over CoIr/TiO2 catalyst.  INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,  47  (36823).  [PMID:] [10.1016/j.ijhydene.2022.08.252]
4. Tao Liu, Yuxin Chen, Yaming Hao, Jianxiang Wu, Ran Wang, Limin Gu, Xuejing Yang, Qiang Yang, Cheng Lian, Honglai Liu, Ming Gong.  (2022)  Hierarchical anions at the electrode-electrolyte interface for synergized neutral water oxidation.  Chem,  (2700-2714).  [PMID:] [10.1016/j.chempr.2022.06.012]
5. Weibin Chen, Yuxin Xie, Xuehui Gao, Lei Li, Zhan Lin.  (2022)  Simultaneous optimization of CoIr alloy nanoparticles and 2D graphitic-N doped carbon support in CoIr@CN by Ir doping for enhanced oxygen and hydrogen evolution reactions.  Journal of Materials Chemistry A,  10  (29): (15543-15553).  [PMID:] [10.1039/D2TA03496D]
6. You Xu, Mengying Liu, Mingzhen Wang, Tianlun Ren, Kaili Ren, Ziqiang Wang, Xiaonian Li, Liang Wang, Hongjing Wang.  (2022)  Methanol electroreforming coupled to green hydrogen production over bifunctional NiIr-based metal-organic framework nanosheet arrays.  APPLIED CATALYSIS B-ENVIRONMENTAL,  300  (120753).  [PMID:] [10.1016/j.apcatb.2021.120753]
7. Chunlei Peng, Wanpeng Zhao, Zhaoxia Li, Zhaoyu Kuang, Guofeng Cheng, Jeffery T. Miller, Shuhui Sun, Hangrong Chen.  (2021)  Eutectic molten salt assisted synthesis of highly defective and flexible ruthenium oxide for efficient overall water splitting.  CHEMICAL ENGINEERING JOURNAL,  425  (131707).  [PMID:] [10.1016/j.cej.2021.131707]
8. Qi Xue, Hui-Ying Sun, Ya-Nan Li, Ming-Jun Zhong, Fu-Min Li, Xinlong Tian, Pei Chen, Shi-Bin Yin, Yu Chen.  (2021)  Au@Ir core-shell nanowires towards oxygen reduction reaction.  CHEMICAL ENGINEERING JOURNAL,  421  (129760).  [PMID:] [10.1016/j.cej.2021.129760]
9. Xiaoqian Jiang, Xiaoyu Wang, Anqi Lin, Hui Wei.  (2021)  In Situ Exsolution of Noble-Metal Nanoparticles on Perovskites as Enhanced Peroxidase Mimics for Bioanalysis.  ANALYTICAL CHEMISTRY,  93  (14): (5954–5962).  [PMID:33797896] [10.1021/acs.analchem.1c00721]
10. Jingru Wang, Shanhui Zhu, Yunwei Wang, Yingyong Wang, Guoqiang Jin, Xili Tong, Xiangyun Guo.  (2021)  Enhanced activity of Ru-Ir nanoparticles over SiC for hydrogenation of levulinic acid at room-temperature.  MATERIALS RESEARCH BULLETIN,  135  (111128).  [PMID:] [10.1016/j.materresbull.2020.111128]
11. Jinhui Zhu, Min Wei, Qinghao Meng, Zhenyu Chen, Yepeng Fan, Syed Waqar Hasan, Xiaoran Zhang, Dandan Lyu, Zhi Qun Tian, Pei Kang Shen.  (2020)  Ultrathin-shell IrCo hollow nanospheres as highly efficient electrocatalysts towards the oxygen evolution reaction in acidic media.  Nanoscale,  12  (47): (24070-24078).  [PMID:33241831] [10.1039/D0NR06601J]
12. You Xu, Xingjie Chai, Mengying Liu, Tianlun Ren, Shanshan Yu, Ziqiang Wang, Xiaonian Li, Liang Wang, Hongjing Wang.  (2020)  Two-Dimensional NiIr@N-Doped Carbon Nanocomposites Supported on Ni Foam for Electrocatalytic Overall Water Splitting.  CHEMISTRY-A EUROPEAN JOURNAL,  26  (63): (14496-14501).  [PMID:32841440] [10.1002/chem.202003473]
13. Qinxin Luo, Dan Lin, Wenqi Zhan, Wanqun Zhang, Lulu Tang, Jingjing Luo, Zhan Gao, Peng Jiang, Miao Wang, LuYuan Hao, Kaibin Tang.  (2020)  Hexagonal Perovskite Ba0.9Sr0.1Co0.8Fe0.1Ir0.1O3−δ as an Efficient Electrocatalyst towards the Oxygen Evolution Reaction.  ACS Applied Energy Materials,  (7): (7149–7158).  [PMID:] [10.1021/acsaem.0c01192]
14. Feng Guo, Hongtao Zou, Qilu Yao, Bin Huang, Zhang-Hui Lu.  (2020)  Monodispersed bimetallic nanoparticles anchored on TiO2-decorated titanium carbide MXene for efficient hydrogen production from hydrazine in aqueous solution.  RENEWABLE ENERGY,  155  (1293).  [PMID:] [10.1016/j.renene.2020.04.047]
15. Wendan Nie, Yixing Luo, Qifeng Yang, Gang Feng, Qilu Yao, Zhang-Hui Lu.  (2020)  An amine-functionalized mesoporous silica-supported PdIr catalyst: boosting room-temperature hydrogen generation from formic acid.  Inorganic Chemistry Frontiers,  (3): (709-717).  [PMID:] [10.1039/C9QI01375J]
16. Qilu Yao, Meng He, Xiaoling Hong, Xiaoliang Zhang, Zhang-Hui Lu.  (2019)  MoOx-modified bimetallic alloy nanoparticles for highly efficient hydrogen production from hydrous hydrazine.  Inorganic Chemistry Frontiers,  (6): (1546-1552).  [PMID:] [10.1039/C9QI00379G]
17. Junnan Li, Ziwei Pan, Kebin Zhou.  (2018)  Enhanced photocatalytic oxygen evolution activity by formation of Ir@IrOx(OH)y core–shell heterostructure.  NANOTECHNOLOGY,  29  (40): (405705).  [PMID:30015623] [10.1088/1361-6528/aad3f4]
18. Lu Wangting, Zhang Geng, Wei Feng, Li Wenhui, Cheng Kun, Ding Fei, Zhang Jiying, Zheng Wanquan.  (2017)  Shape-controlled synthesis of Pd nanocrystals in an aqueous solution by using amphiphilic triblock copolymers as both the stabilizer and the reductant.  COLLOID AND POLYMER SCIENCE,  295  (4): (703-707).  [PMID:] [10.1007/s00396-017-4041-9]
19. Yuan Gao, Ming Hou, Zhigang Shao, Changkun Zhang, Xiaoping Qin, Baolian Yi.  (2015)  Highly effective oxygen reduction activity and durability of antimony-doped tin oxide modified PtPd/C electrocatalysts.  RSC Advances,  (85): (69479-69486).  [PMID:] [10.1039/C5RA10162J]

Solution Calculators