Lithium borohydride - 95%, high purity , CAS No.16949-15-8

3 Citations
  • ≥95%
Item Number
L107011
Grouped product items
SKUSizeAvailabilityPrice Qty
L107011-10g
10g
In stock
$79.90
L107011-50g
50g
In stock
$299.90
L107011-250g
250g
In stock
$1,199.90
View related series
Reducing Agents Reductant

Basic Description

Specifications & Purity≥95%
Storage TempArgon charged
Shipped InNormal
Product Description

Lithium borohydride is a general reducing agent commonly used to reduce aldehydes, ketones esters, lactones, and epoxides. It catalyzes hydroboration of alkenes. It is also used in the preparation of other borohydrides such as aluminum borohydride.

Names and Identifiers

IUPAC Name lithium;boron(1-)
INCHI InChI=1S/B.Li/q-1;+1
InChi Key NZTNZPDOBQDOSO-UHFFFAOYSA-N
Canonical SMILES [Li+].[B-]
Isomeric SMILES [Li+].[B-]
WGK Germany 2
RTECS ED2725000
PubChem CID 20722760
UN Number 1413
Packing Group I
Molecular Weight 21.78

Certificates

Certificate of Analysis(COA)

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23 results found

Lot NumberCertificate TypeDateItem
H2405563Certificate of AnalysisJul 20, 2024 L107011
H2405562Certificate of AnalysisJul 20, 2024 L107011
H2405561Certificate of AnalysisJul 20, 2024 L107011
E2408443Certificate of AnalysisApr 25, 2024 L107011
E2408441Certificate of AnalysisApr 25, 2024 L107011
B24231038Certificate of AnalysisFeb 01, 2024 L107011
B24231039Certificate of AnalysisFeb 01, 2024 L107011
B24231040Certificate of AnalysisFeb 01, 2024 L107011
D2417023Certificate of AnalysisFeb 01, 2024 L107011
J2327655Certificate of AnalysisOct 16, 2023 L107011
J2327623Certificate of AnalysisOct 16, 2023 L107011
J2327622Certificate of AnalysisOct 16, 2023 L107011
E2318540Certificate of AnalysisMay 06, 2023 L107011
E2318528Certificate of AnalysisMay 06, 2023 L107011
B2311066Certificate of AnalysisDec 06, 2022 L107011
B2311115Certificate of AnalysisDec 06, 2022 L107011
I2202370Certificate of AnalysisAug 16, 2022 L107011
I2202440Certificate of AnalysisAug 16, 2022 L107011
I2202441Certificate of AnalysisAug 16, 2022 L107011
E2227188Certificate of AnalysisMay 22, 2022 L107011
E2227187Certificate of AnalysisMay 22, 2022 L107011
E2227183Certificate of AnalysisMay 22, 2022 L107011
C2204008Certificate of AnalysisMar 07, 2022 L107011

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Chemical and Physical Properties

SolubilitySoluble in ether, THF, and aliphatic aminesSoluble in ether, tetrahydrofuran, aliphatic amines and ethanol.
SensitivityMoisture Sensitive
Flash Point(°C)-18℃
Melt Point(°C)275°C

Safety and Hazards(GHS)

Pictogram(s) GHS06,   GHS05,   GHS02
Signal Danger
Hazard Statements

H301:Toxic if swallowed

H260:In contact with water releases flammable gases which may ignite spontaneously

H314:Causes severe skin burns and eye damage

Precautionary Statements

P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.

P280:Wear protective gloves/protective clothing/eye protection/face protection.

P231+P232:Handle under inert gas/... Protect from moisture.

P370+P378:In case of fire: Use ... to extinguish.

P310:Immediately call a POISON CENTER or doctor/physician.

P405:Store locked up.

P501:Dispose of contents/container to ...

P264:Wash hands [and …] thoroughly after handling.

P303+P361+P353:IF ON SKIN (or hair): Take off Immediately all contaminated clothing. Rinse SKIN with water [or shower].

P271:Use only outdoors or in a well-ventilated area.

P331:Do NOT induce vomiting.

P270:Do not eat, drink or smoke when using this product.

P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P362+P364:Take off contaminated clothing and wash it before reuse.

P330:Rinse mouth.

P402+P404:Store in a dry place. Store in a closed container.

WGK Germany 2
RTECS ED2725000
Class 4.3

Related Documents

Citations of This Product

1. Zhi-Kang Qin, Li-Qing He, Xiao-Li Ding, Ting-Zhi Si, Ping Cui, Hai-Wen Li, Yong-Tao Li.  (2023)  Liquid Channels Built-In Solid Magnesium Hydrides for Boosting Hydrogen Sorption.  Inorganics,  11  (5): (216).  [PMID:]
2. Jiahui Li, Yangfeng Wang, Mengru Hu, Zhangze Ye, Xiaohua Zheng, Peng Li, Chu Liang.  (2023)  Self-templated synthesis of boron-doped porous carbon by chemical interaction of 2LiBH4·CO2 with CO2.  CHEMICAL ENGINEERING JOURNAL,  454  (140205).  [PMID:]
3. Kang Chen, Mili Liu, Liuzhang Ouyang, Hui Wang, Jiangwen Liu, Min Zhu.  (2022)  Efficient hydrogen release from LiBH4 alcoholysis in methanol/ethylene glycol based solutions over a wide temperature range.  JOURNAL OF ALLOYS AND COMPOUNDS,  905  (164030).  [PMID:]

References

1. L M Likhosherstov,O S Novikova,V A Derevitskaia,N K Kochetkov.  (1984-01-01)  [New method of cleaving the N-linked carbohydrate chains of glycoproteins using alkaline lithium borohydride]..  Doklady Akademii nauk SSSR,  274  ((1)): (222-225).  [PMID:6705674]
2. N P Arbatskiĭ,L M Likhosherstov,M V Serebriakova,O S Brusov,V N Shibaev,V A Derevitskaia,N K Kochetkov.  (2000-05-12)  [The degradation of glycoproteins with lithium borohydride. Isolation and analysis of O-glycopeptides with reduced C-terminal amino acid residue]..  Bioorganicheskaia khimiia,  26  ((1)): (51-60).  [PMID:10806552]
3. David A Evans,George Borg,Karl A Scheidt.  (2002-10-09)  Remarkably stable tetrahedral intermediates: carbinols from nucleophilic additions to N-acylpyrroles..  Angewandte Chemie (International ed. in English),  41  ((17)): (3188-3191).  [PMID:12207385]
4. G Erfurt,M R Krbetschek.  (2002-10-18)  A radioluminescence study of spectral and dose characteristics of common luminophors..  Radiation protection dosimetry,  100  ((1-4)): (403-406).  [PMID:12382908]
5. Mark R Biscoe,Ronald Breslow.  (2003-10-16)  Hydrophobically directed selective reduction of ketones..  Journal of the American Chemical Society,  125  ((42)): (12718-12719).  [PMID:14558814]
6. Prabhat Arya,Patricia Durieux,Zai-Xin Chen,Reni Joseph,Donald M Leek.  (2004-01-13)  Stereoselective diversity-oriented solution and solid-phase synthesis of tetrahydroquinoline-based polycyclic derivatives..  Journal of combinatorial chemistry,  ((1)): (54-64).  [PMID:14714985]
7. Sumalee Supothina,Masahiko Isaka,Kanyawim Kirtikara,Morakot Tanticharoen,Yodhathai Thebtaranonth.  (2005-02-17)  Enniatin production by the entomopathogenic fungus Verticillium hemipterigenum BCC 1449..  The Journal of antibiotics,  57  ((11)): (732-738).  [PMID:15712668]
8. Barbara Milani,Corrado Crottib,Erica Farnetti.  (2008-11-26)  Hydrogen transfer reduction of polyketones catalyzed by iridium complexes: a novel route towards more biocompatible materials..  Dalton transactions (Cambridge, England : 2003),    ((34)): (4659-4663).  [PMID:19024366]
9. Hui Wu,Wei Zhou,Ke Wang,Terrence J Udovic,John J Rush,Taner Yildirim,Leonid A Bendersky,Adam F Gross,Sky L Van Atta,John J Vajo,Frederick E Pinkerton,Martin S Meyer.  (2009-05-08)  Size effects on the hydrogen storage properties of nanoscaffolded Li3BN2H8..  Nanotechnology,  20  ((20)): (204002-204002).  [PMID:19420650]
10. Matthew S Wellons,Polly A Berseth,Ragaiy Zidan.  (2009-05-08)  Novel catalytic effects of fullerene for LiBH4 hydrogen uptake and release..  Nanotechnology,  20  ((20)): (204022-204022).  [PMID:19420670]
11. S M Opalka,X Tang,B L Laube,T H Vanderspurt.  (2009-05-08)  Experimental and theoretical screening of nanoscale oxide reactivity with LiBH4..  Nanotechnology,  20  ((20)): (204024-204024).  [PMID:19420672]
12. Pascal Martelli,Arndt Remhof,Andreas Borgschulte,Philippe Mauron,Dirk Wallacher,Ewout Kemner,Margarita Russina,Flavio Pendolino,Andreas Züttel.  (2010-09-03)  BH4− self-diffusion in liquid LiBH4..  The journal of physical chemistry. A,  114  ((37)): (10117-10121).  [PMID:20806929]
13. Meganne Christian,Kondo-Francois Aguey-Zinsou.  (2010-10-05)  Destabilisation of complex hydrides through size effects..  Nanoscale,  ((12)): (2587-2590).  [PMID:20886168]
14. Roger Domènech-Ferrer,Frank Ziegs,Sabrina Klod,Inge Lindemann,Ralf Voigtländer,Lothar Dunsch,Oliver Gutfleisch.  (2011-03-18)  In situ Raman cell for high pressure and temperature studies of metal and complex hydrides..  Analytical chemistry,  83  ((8)): (3199-3204).  [PMID:21410226]
15. Mita Dasog,Wenbo Hou,Robert W J Scott.  (2011-06-28)  Controlled growth and catalytic activity of gold monolayer protected clusters in presence of borohydride salts..  Chemical communications (Cambridge, England),  47  ((30)): (8569-8571).  [PMID:21706115]
16. Xinyi Chen,Shaofeng Li,Yanhui Guo,Xuebin Yu.  (2011-08-19)  Promoted dehydrogenation in ammine lithium borohydride supported by carbon nanotubes..  Dalton transactions (Cambridge, England : 2003),  40  ((38)): (9679-9689).  [PMID:21850349]
17. Piter S Miedema,Peter Ngene,Ad M J van der Eerden,Tsu-Chien Weng,Dennis Nordlund,Dimosthenis Sokaras,Roberto Alonso-Mori,Amélie Juhin,Petra E de Jongh,Frank M F de Groot.  (2012-03-20)  In situ X-ray Raman spectroscopy of LiBH4..  Physical chemistry chemical physics : PCCP,  14  ((16)): (5581-5587).  [PMID:22428166]
18. Alyssa M Keil,Douglas M Frederick,Erina Y Jacinto,Erica L Kennedy,Randy J Zauhar,Nathan M West,Ruy Tchao,Peter J Harvison.  (2015-07-21)  Cytotoxicity of thiazolidinedione-, oxazolidinedione- and pyrrolidinedione-ring containing compounds in HepG2 cells..  Toxicology in vitro : an international journal published in association with BIBRA,  29  ((7)): (1887-1896).  [PMID:26193171]
19. Kostiantyn V Kravchyk,Laura Piveteau,Riccarda Caputo,Meng He,Nicholas P Stadie,Maryna I Bodnarchuk,Rainer T Lechner,Maksym V Kovalenko.  (2018-08-09)  Colloidal Bismuth Nanocrystals as a Model Anode Material for Rechargeable Mg-Ion Batteries: Atomistic and Mesoscale Insights..  ACS nano,  12  ((8)): (8297-8307).  [PMID:30086624]
20. Zhi-Kang Qin, Li-Qing He, Xiao-Li Ding, Ting-Zhi Si, Ping Cui, Hai-Wen Li, Yong-Tao Li.  (2023)  Liquid Channels Built-In Solid Magnesium Hydrides for Boosting Hydrogen Sorption.  Inorganics,  11  (5): (216).  [PMID:]
21. Jiahui Li, Yangfeng Wang, Mengru Hu, Zhangze Ye, Xiaohua Zheng, Peng Li, Chu Liang.  (2023)  Self-templated synthesis of boron-doped porous carbon by chemical interaction of 2LiBH4·CO2 with CO2.  CHEMICAL ENGINEERING JOURNAL,  454  (140205).  [PMID:]
22. Kang Chen, Mili Liu, Liuzhang Ouyang, Hui Wang, Jiangwen Liu, Min Zhu.  (2022)  Efficient hydrogen release from LiBH4 alcoholysis in methanol/ethylene glycol based solutions over a wide temperature range.  JOURNAL OF ALLOYS AND COMPOUNDS,  905  (164030).  [PMID:]

Solution Calculators