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Lithium borohydride - 2.0M in THF, high purity , CAS No.16949-15-8

  • 2.0M in THF
Item Number
L107012
Grouped product items
SKUSizeAvailabilityPrice Qty
L107012-25ml
25ml
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$34.90
L107012-100ml
100ml
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$107.90
L107012-500ml
500ml
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$483.90
View related series
Reducing agent Reductant

Basic Description

SynonymsLITHIUM BOROHYDRIDE|16949-15-8|Borate(1-), tetrahydro-, lithium|lithium;boron(1-)|8L87X4S4KP|EINECS 241-021-7|UN1413|boryllithium|UNII-8L87X4S4KP|MFCD00011088|Lithium tetrahydroborate(1-) (1:1)|lithium(1+) boranuide|LITHIUM BOROHYDRIDE [MI]|DTXSID40895058
Specifications & Purity2.0M in THF
Storage TempArgon charged
Shipped InNormal
Product Description

Lithium borohydride solution (2M in THF) has been used for the reduction of 5-benzylidene-2,4-thiazolidinediones and 5-benzylidene-4-oxo-2-thiazolidinethiones to form 5-benzyl-2,4-thiazolidinediones and 5-benzyl-4-oxo-2-thiazolidinethiones, respectively. Reactant for: · Preparation of gallium, indium, rhenium and zinc tris(mercaptoimidazolyl)hydroborato complexes · Mechano-chemical metathesis reactions · Noncatalytic hydrolysis for hydrogen generation · Growth of large gold monolayer protected-clusters · Anion substitution reactions · Dehydrogenation reactions

Names and Identifiers

IUPAC Name lithium;boron(1-)
INCHI InChI=1S/B.Li/q-1;+1
InChi Key NZTNZPDOBQDOSO-UHFFFAOYSA-N
Canonical SMILES [Li+].[B-]
Isomeric SMILES [Li+].[B-]
WGK Germany 2
RTECS ED2725000
PubChem CID 20722760
UN Number 1413
Packing Group I
Molecular Weight 21.78

Certificates

Certificate of Analysis(COA)

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45 results found

Lot NumberCertificate TypeDateItem
H2405259Certificate of AnalysisJul 20, 2024 L107012
H2412538Certificate of AnalysisJul 20, 2024 L107012
H2405258Certificate of AnalysisJul 18, 2024 L107012
H2405260Certificate of AnalysisJul 18, 2024 L107012
D2425385Certificate of AnalysisMar 29, 2024 L107012
D2425383Certificate of AnalysisMar 29, 2024 L107012
D2425381Certificate of AnalysisMar 29, 2024 L107012
B2422173Certificate of AnalysisJan 31, 2024 L107012
B2422191Certificate of AnalysisJan 31, 2024 L107012
B2422192Certificate of AnalysisJan 31, 2024 L107012
B2422224Certificate of AnalysisJan 31, 2024 L107012
A2402433Certificate of AnalysisDec 20, 2023 L107012
A2402434Certificate of AnalysisDec 20, 2023 L107012
K2330119Certificate of AnalysisNov 20, 2023 L107012
K2330117Certificate of AnalysisNov 20, 2023 L107012
J2323721Certificate of AnalysisOct 16, 2023 L107012
J2323720Certificate of AnalysisOct 16, 2023 L107012
J2323735Certificate of AnalysisOct 16, 2023 L107012
H2309400Certificate of AnalysisJul 31, 2023 L107012
H2309399Certificate of AnalysisJul 31, 2023 L107012
H2309397Certificate of AnalysisJul 31, 2023 L107012
H2309398Certificate of AnalysisJul 31, 2023 L107012
E2330953Certificate of AnalysisMay 15, 2023 L107012
E2330960Certificate of AnalysisMay 15, 2023 L107012
E2330962Certificate of AnalysisMay 15, 2023 L107012
E2330963Certificate of AnalysisMay 15, 2023 L107012
C23181150Certificate of AnalysisMar 13, 2023 L107012
C23181138Certificate of AnalysisMar 13, 2023 L107012
C23181136Certificate of AnalysisMar 13, 2023 L107012
A2329356Certificate of AnalysisJan 06, 2023 L107012
A2329500Certificate of AnalysisJan 06, 2023 L107012
A2329498Certificate of AnalysisJan 06, 2023 L107012
A2329322Certificate of AnalysisJan 06, 2023 L107012
J2228675Certificate of AnalysisOct 11, 2022 L107012
J2228691Certificate of AnalysisOct 11, 2022 L107012
J2228692Certificate of AnalysisOct 11, 2022 L107012
J2228701Certificate of AnalysisOct 11, 2022 L107012
G2216357Certificate of AnalysisJun 30, 2022 L107012
G2216356Certificate of AnalysisJun 30, 2022 L107012
G2216355Certificate of AnalysisJun 30, 2022 L107012
G2216354Certificate of AnalysisJun 30, 2022 L107012
F2201043Certificate of AnalysisMar 22, 2022 L107012
F2201042Certificate of AnalysisMar 22, 2022 L107012
F2201036Certificate of AnalysisMar 22, 2022 L107012
F2201034Certificate of AnalysisMar 22, 2022 L107012

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Chemical and Physical Properties

SensitivityMoisture Sensitive
Flash Point(°C)-18℃
Melt Point(°C)275°C

Safety and Hazards(GHS)

Pictogram(s) GHS06,   GHS05,   GHS02
Signal Danger
Hazard Statements

H301:Toxic if swallowed

H260:In contact with water releases flammable gases which may ignite spontaneously

H314:Causes severe skin burns and eye damage

Precautionary Statements

P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.

P280:Wear protective gloves/protective clothing/eye protection/face protection.

P231+P232:Handle under inert gas/... Protect from moisture.

P370+P378:In case of fire: Use ... to extinguish.

P310:Immediately call a POISON CENTER or doctor/physician.

P405:Store locked up.

P501:Dispose of contents/container to ...

P264:Wash hands [and …] thoroughly after handling.

P303+P361+P353:IF ON SKIN (or hair): Take off Immediately all contaminated clothing. Rinse SKIN with water [or shower].

P271:Use only outdoors or in a well-ventilated area.

P331:Do NOT induce vomiting.

P270:Do not eat, drink or smoke when using this product.

P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P362+P364:Take off contaminated clothing and wash it before reuse.

P330:Rinse mouth.

P402+P404:Store in a dry place. Store in a closed container.

WGK Germany 2
RTECS ED2725000
Class 4.3

Related Documents

References

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2. N P Arbatskiĭ,L M Likhosherstov,M V Serebriakova,O S Brusov,V N Shibaev,V A Derevitskaia,N K Kochetkov.  (2000-05-12)  [The degradation of glycoproteins with lithium borohydride. Isolation and analysis of O-glycopeptides with reduced C-terminal amino acid residue]..  Bioorganicheskaia khimiia,  26  ((1)): (51-60).  [PMID:10806552]
3. David A Evans,George Borg,Karl A Scheidt.  (2002-10-09)  Remarkably stable tetrahedral intermediates: carbinols from nucleophilic additions to N-acylpyrroles..  Angewandte Chemie (International ed. in English),  41  ((17)): (3188-3191).  [PMID:12207385]
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5. Mark R Biscoe,Ronald Breslow.  (2003-10-16)  Hydrophobically directed selective reduction of ketones..  Journal of the American Chemical Society,  125  ((42)): (12718-12719).  [PMID:14558814]
6. Prabhat Arya,Patricia Durieux,Zai-Xin Chen,Reni Joseph,Donald M Leek.  (2004-01-13)  Stereoselective diversity-oriented solution and solid-phase synthesis of tetrahydroquinoline-based polycyclic derivatives..  Journal of combinatorial chemistry,  ((1)): (54-64).  [PMID:14714985]
7. Sumalee Supothina,Masahiko Isaka,Kanyawim Kirtikara,Morakot Tanticharoen,Yodhathai Thebtaranonth.  (2005-02-17)  Enniatin production by the entomopathogenic fungus Verticillium hemipterigenum BCC 1449..  The Journal of antibiotics,  57  ((11)): (732-738).  [PMID:15712668]
8. Barbara Milani,Corrado Crottib,Erica Farnetti.  (2008-11-26)  Hydrogen transfer reduction of polyketones catalyzed by iridium complexes: a novel route towards more biocompatible materials..  Dalton transactions (Cambridge, England : 2003),    ((34)): (4659-4663).  [PMID:19024366]
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10. Matthew S Wellons,Polly A Berseth,Ragaiy Zidan.  (2009-05-08)  Novel catalytic effects of fullerene for LiBH4 hydrogen uptake and release..  Nanotechnology,  20  ((20)): (204022-204022).  [PMID:19420670]
11. S M Opalka,X Tang,B L Laube,T H Vanderspurt.  (2009-05-08)  Experimental and theoretical screening of nanoscale oxide reactivity with LiBH4..  Nanotechnology,  20  ((20)): (204024-204024).  [PMID:19420672]
12. Pascal Martelli,Arndt Remhof,Andreas Borgschulte,Philippe Mauron,Dirk Wallacher,Ewout Kemner,Margarita Russina,Flavio Pendolino,Andreas Züttel.  (2010-09-03)  BH4− self-diffusion in liquid LiBH4..  The journal of physical chemistry. A,  114  ((37)): (10117-10121).  [PMID:20806929]
13. Meganne Christian,Kondo-Francois Aguey-Zinsou.  (2010-10-05)  Destabilisation of complex hydrides through size effects..  Nanoscale,  ((12)): (2587-2590).  [PMID:20886168]
14. Roger Domènech-Ferrer,Frank Ziegs,Sabrina Klod,Inge Lindemann,Ralf Voigtländer,Lothar Dunsch,Oliver Gutfleisch.  (2011-03-18)  In situ Raman cell for high pressure and temperature studies of metal and complex hydrides..  Analytical chemistry,  83  ((8)): (3199-3204).  [PMID:21410226]
15. Xinyi Chen,Shaofeng Li,Yanhui Guo,Xuebin Yu.  (2011-08-19)  Promoted dehydrogenation in ammine lithium borohydride supported by carbon nanotubes..  Dalton transactions (Cambridge, England : 2003),  40  ((38)): (9679-9689).  [PMID:21850349]
16. Piter S Miedema,Peter Ngene,Ad M J van der Eerden,Tsu-Chien Weng,Dennis Nordlund,Dimosthenis Sokaras,Roberto Alonso-Mori,Amélie Juhin,Petra E de Jongh,Frank M F de Groot.  (2012-03-20)  In situ X-ray Raman spectroscopy of LiBH4..  Physical chemistry chemical physics : PCCP,  14  ((16)): (5581-5587).  [PMID:22428166]
17. David J Timson,Steffen Lindert.  (2013-06-05)  Comparison of dynamics of wildtype and V94M human UDP-galactose 4-epimerase-A computational perspective on severe epimerase-deficiency galactosemia..  Gene,  526  ((2)): (318-324).  [PMID:23732289]
18. Alyssa M Keil,Douglas M Frederick,Erina Y Jacinto,Erica L Kennedy,Randy J Zauhar,Nathan M West,Ruy Tchao,Peter J Harvison.  (2015-07-21)  Cytotoxicity of thiazolidinedione-, oxazolidinedione- and pyrrolidinedione-ring containing compounds in HepG2 cells..  Toxicology in vitro : an international journal published in association with BIBRA,  29  ((7)): (1887-1896).  [PMID:26193171]

Solution Calculators