Click Here for 5% Off Your First Aladdin Purchase!
Call +1 (833) 552-7181 or Contact us Earn $25 in coupons on your first order with Aladdin!
Toggle Nav
My Cart
Search
Advanced Search
Menu
Sign In
྾
main product photo

Lithium borohydride - ≥90%, high purity , CAS No.16949-15-8

  • ≥90%
Item Number
L432213
Grouped product items
SKUSizeAvailabilityPrice Qty
L432213-10g
10g
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$64.90
L432213-50g
50g
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$259.90
Add to Wish List Compare
Bulk Order  SDS  DATASHEET

Basic Description

SynonymsLITHIUM BOROHYDRIDE|16949-15-8|Borate(1-), tetrahydro-, lithium|lithium;boron(1-)|8L87X4S4KP|EINECS 241-021-7|UN1413|boryllithium|UNII-8L87X4S4KP|MFCD00011088|Lithium tetrahydroborate(1-) (1:1)|lithium(1+) boranuide|LITHIUM BOROHYDRIDE [MI]|DTXSID40895058
Specifications & Purity≥90%
Product Description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here . Lithium borohydride, a white solid, may be prepared from the exchange reaction of LiCl and sodium borohydride in isopropylamine. The orthorhombic crystal structure converts to tetragonal at 108 o C and eventually melting at 278 o C. Infrared and Raman spectral studies at 80 o C have been reported in a study.


Application

Versatile reducing agent for aldehydes, ketones, acid chlorides, lactones, epoxides, and esters. Applied in the lithiation of 2H-WS 2 giving high yields of exfoliated WS 2 , and opening the way to new intercalation compounds and nanocomposites. Lithium borohydride is used as hydrogen storage system. It regenerates hydrogen at 320-380 o C at 10atm (H 2 pressure).

Names and Identifiers

IUPAC Name lithium;boron(1-)
INCHI InChI=1S/B.Li/q-1;+1
InChi Key NZTNZPDOBQDOSO-UHFFFAOYSA-N
Canonical SMILES [Li+].[B-]
Isomeric SMILES [Li+].[B-]
WGK Germany 2
RTECS ED2725000
PubChem CID 20722760
UN Number 1413
Packing Group I
Molecular Weight 21.78

Certificates

Certificate of Analysis(COA)

Enter Lot Number to search for COA:

Chemical and Physical Properties

Flash Point(°C)-18℃
Melt Point(°C)275°C

Safety and Hazards(GHS)

Pictogram(s) GHS06,   GHS05,   GHS02
Signal Danger
Hazard Statements

H301:Toxic if swallowed

H260:In contact with water releases flammable gases which may ignite spontaneously

H314:Causes severe skin burns and eye damage

Precautionary Statements

P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.

P280:Wear protective gloves/protective clothing/eye protection/face protection.

P231+P232:Handle under inert gas/... Protect from moisture.

P370+P378:In case of fire: Use ... to extinguish.

P310:Immediately call a POISON CENTER or doctor/physician.

P405:Store locked up.

P501:Dispose of contents/container to ...

P264:Wash hands [and …] thoroughly after handling.

P303+P361+P353:IF ON SKIN (or hair): Take off Immediately all contaminated clothing. Rinse SKIN with water [or shower].

P271:Use only outdoors or in a well-ventilated area.

P331:Do NOT induce vomiting.

P270:Do not eat, drink or smoke when using this product.

P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P362+P364:Take off contaminated clothing and wash it before reuse.

P330:Rinse mouth.

P402+P404:Store in a dry place. Store in a closed container.

WGK Germany 2
RTECS ED2725000
Class 4.3

Related Documents

 SDS

 Specification Sheet

References

1. L M Likhosherstov,O S Novikova,V A Derevitskaia,N K Kochetkov.  (1984-01-01)  [New method of cleaving the N-linked carbohydrate chains of glycoproteins using alkaline lithium borohydride]..  Doklady Akademii nauk SSSR,  274  ((1)): (222-225).  [PMID:6705674]
2. N P Arbatskiĭ,L M Likhosherstov,M V Serebriakova,O S Brusov,V N Shibaev,V A Derevitskaia,N K Kochetkov.  (2000-05-12)  [The degradation of glycoproteins with lithium borohydride. Isolation and analysis of O-glycopeptides with reduced C-terminal amino acid residue]..  Bioorganicheskaia khimiia,  26  ((1)): (51-60).  [PMID:10806552]
3. David A Evans,George Borg,Karl A Scheidt.  (2002-10-09)  Remarkably stable tetrahedral intermediates: carbinols from nucleophilic additions to N-acylpyrroles..  Angewandte Chemie (International ed. in English),  41  ((17)): (3188-3191).  [PMID:12207385]
4. G Erfurt,M R Krbetschek.  (2002-10-18)  A radioluminescence study of spectral and dose characteristics of common luminophors..  Radiation protection dosimetry,  100  ((1-4)): (403-406).  [PMID:12382908]
5. Mark R Biscoe,Ronald Breslow.  (2003-10-16)  Hydrophobically directed selective reduction of ketones..  Journal of the American Chemical Society,  125  ((42)): (12718-12719).  [PMID:14558814]
6. Prabhat Arya,Patricia Durieux,Zai-Xin Chen,Reni Joseph,Donald M Leek.  (2004-01-13)  Stereoselective diversity-oriented solution and solid-phase synthesis of tetrahydroquinoline-based polycyclic derivatives..  Journal of combinatorial chemistry,  6  ((1)): (54-64).  [PMID:14714985]
7. Sumalee Supothina,Masahiko Isaka,Kanyawim Kirtikara,Morakot Tanticharoen,Yodhathai Thebtaranonth.  (2005-02-17)  Enniatin production by the entomopathogenic fungus Verticillium hemipterigenum BCC 1449..  The Journal of antibiotics,  57  ((11)): (732-738).  [PMID:15712668]
8. Barbara Milani,Corrado Crottib,Erica Farnetti.  (2008-11-26)  Hydrogen transfer reduction of polyketones catalyzed by iridium complexes: a novel route towards more biocompatible materials..  Dalton transactions (Cambridge, England : 2003),    ((34)): (4659-4663).  [PMID:19024366]
9. Hui Wu,Wei Zhou,Ke Wang,Terrence J Udovic,John J Rush,Taner Yildirim,Leonid A Bendersky,Adam F Gross,Sky L Van Atta,John J Vajo,Frederick E Pinkerton,Martin S Meyer.  (2009-05-08)  Size effects on the hydrogen storage properties of nanoscaffolded Li3BN2H8..  Nanotechnology,  20  ((20)): (204002-204002).  [PMID:19420650]
10. Matthew S Wellons,Polly A Berseth,Ragaiy Zidan.  (2009-05-08)  Novel catalytic effects of fullerene for LiBH4 hydrogen uptake and release..  Nanotechnology,  20  ((20)): (204022-204022).  [PMID:19420670]
11. S M Opalka,X Tang,B L Laube,T H Vanderspurt.  (2009-05-08)  Experimental and theoretical screening of nanoscale oxide reactivity with LiBH4..  Nanotechnology,  20  ((20)): (204024-204024).  [PMID:19420672]
12. Pascal Martelli,Arndt Remhof,Andreas Borgschulte,Philippe Mauron,Dirk Wallacher,Ewout Kemner,Margarita Russina,Flavio Pendolino,Andreas Züttel.  (2010-09-03)  BH4− self-diffusion in liquid LiBH4..  The journal of physical chemistry. A,  114  ((37)): (10117-10121).  [PMID:20806929]
13. Meganne Christian,Kondo-Francois Aguey-Zinsou.  (2010-10-05)  Destabilisation of complex hydrides through size effects..  Nanoscale,  2  ((12)): (2587-2590).  [PMID:20886168]
14. Roger Domènech-Ferrer,Frank Ziegs,Sabrina Klod,Inge Lindemann,Ralf Voigtländer,Lothar Dunsch,Oliver Gutfleisch.  (2011-03-18)  In situ Raman cell for high pressure and temperature studies of metal and complex hydrides..  Analytical chemistry,  83  ((8)): (3199-3204).  [PMID:21410226]
15. Mita Dasog,Wenbo Hou,Robert W J Scott.  (2011-06-28)  Controlled growth and catalytic activity of gold monolayer protected clusters in presence of borohydride salts..  Chemical communications (Cambridge, England),  47  ((30)): (8569-8571).  [PMID:21706115]
16. Xinyi Chen,Shaofeng Li,Yanhui Guo,Xuebin Yu.  (2011-08-19)  Promoted dehydrogenation in ammine lithium borohydride supported by carbon nanotubes..  Dalton transactions (Cambridge, England : 2003),  40  ((38)): (9679-9689).  [PMID:21850349]
17. Piter S Miedema,Peter Ngene,Ad M J van der Eerden,Tsu-Chien Weng,Dennis Nordlund,Dimosthenis Sokaras,Roberto Alonso-Mori,Amélie Juhin,Petra E de Jongh,Frank M F de Groot.  (2012-03-20)  In situ X-ray Raman spectroscopy of LiBH4..  Physical chemistry chemical physics : PCCP,  14  ((16)): (5581-5587).  [PMID:22428166]
18. Alyssa M Keil,Douglas M Frederick,Erina Y Jacinto,Erica L Kennedy,Randy J Zauhar,Nathan M West,Ruy Tchao,Peter J Harvison.  (2015-07-21)  Cytotoxicity of thiazolidinedione-, oxazolidinedione- and pyrrolidinedione-ring containing compounds in HepG2 cells..  Toxicology in vitro : an international journal published in association with BIBRA,  29  ((7)): (1887-1896).  [PMID:26193171]

Solution Calculators

Privacy Policy Website Terms of Use Return policy Terms and Conditions of Sale Cookie Policy Sales Policy
Products are chemical reagents for research use only and are not intended for human use. We do not sell to patients.
Copyright © 2023-present Aladdin Scientific Corp . All rights reserved.