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Lithium difluoro(oxalato)borate - ≥99%, high purity , CAS No.409071-16-5
Discover Lithium difluoro(oxalato)borate by Aladdin Scientific in ≥99% for only $9.90. Available - in Ligands at Aladdin Scientific. Tags: Organoboron.
Basic Description Synonyms lithium;2,2-difluoro-1,3-dioxa-2-boranuidacyclopentane-4,5-dione | SB66427 | EN300-7655610 | A914353 | Lithium Difluoro(oxalato)borate (LiODFB) | 2,2-Difluoro-4,5-dioxo-1,3,2-dioxaborolane Lithium Salt | AKOS030228434 | CS-0157932 | SY015317 | Lithium dif Specifications & Purity ≥99% Storage Temp Room temperature,Argon charged Shipped In Normal Product Description product description：
Lithium difluoro(oxalato)borate (LIODFB) is a class of electrolytic materials that can be used in the fabrication of lithium-ion batteries. Lithium-ion batteries consist of anode, cathode, and electrolyte with a charge-discharge cycle. These materials enable the formation of greener and sustainable batteries for electrical energy storage.
application：
LiODFB is used as a thermally stable novel salt and an electrolytic additive for lithium-ion batteries. It facilitates the formation of stable solid electrolyte interphase (SEI) on the negative electrode during the fabrication of the cell. It substantially enhances the cyclic performance, capacity and power retention of the electrochemical system.
Lithium difluorooxalatoborate (LIODFB) is a salt for high-performance Li-ion batteries with improved cycle life; power capability; low temperature and high rate performance of the battery. It has the advantages of both lithium bis(oxalato)borate (LiBOB) and LiBF4. LIODFB also stabilizes the solid electrolyte interface (SEI) on the surface of a graphite anode and is also used as an additive to improve the cycling efficiency and capacity retention of cells
Names and Identifiers IUPAC Name lithium;2,2-difluoro-1,3-dioxa-2-boranuidacyclopentane-4,5-dione INCHI InChI=1S/C2BF2O4.Li/c4-3(5)8-1(6)2(7)9-3;/q-1;+1 InChi Key MEDDCIKGDMDORY-UHFFFAOYSA-N Canonical SMILES [Li+].[B-]1(OC(=O)C(=O)O1)(F)F Isomeric SMILES [Li+].[B-]1(OC(=O)C(=O)O1)(F)F PubChem CID 91810277 Molecular Weight 143.77
Chemical and Physical Properties Sensitivity Hygroscopic Melt Point(°C) 265-271 °C
Safety and Hazards(GHS) Pictogram(s) GHS07 Signal Warning Hazard Statements H315: Causes skin irritation
H319: Causes serious eye irritation
H335: May cause respiratory irritation
Precautionary Statements P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352: IF ON SKIN: wash with plenty of water.
P321: Specific treatment (see ... on this label).
P405: Store locked up.
P501: Dispose of contents/container to ...
P264: Wash hands [and …] thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P403+P233: Store in a well-ventilated place. Keep container tightly closed.
P362+P364: Take off contaminated clothing and wash it before reuse.
P264+P265: Wash hands [and …] thoroughly after handling. Do not touch eyes.
P337+P317: If eye irritation persists: Get medical help.
P332+P317: If skin irritation occurs: Get medical help.
P319: Get medical help if you feel unwell.
Citations of This Product 1. Zhen Shi, Jirong Wang, Kairui Guo, Hongli Wang, Hui Nie, Zhigang Xue. (2023) Deep eutectic solvent-assisted phase separation for polyurea-based polymer electrolytes. CHEMICAL ENGINEERING JOURNAL, 468 (143687). [PMID: [10.1016/j.cej.2023.143687 ] 2. Geng Tang, Shao-Peng Shen, Hong-Ji Li, Liang Zhang, Jin-Chi Zheng, Yuan Luo, Jun-Pei Yue, Yongzheng Shi, Zhe Chen. (2023) Flame-Retardant Gel Electrolyte toward High-Safety Lithium Metal Batteries with High-Mass-Loading Cathodes. Journal of Physical Chemistry C, 127 (20): (9463–9470). [PMID: [10.1021/acs.jpcc.3c00744 ] 3. Wanbao Wu, Qing Li, Miaomiao Cao, Deping Li, Jingyu Lu, Mingyu Li, Jiaheng Zhang. (2022) Non-Flammable Dual-Salt Deep Eutectic Electrolyte for High-Voltage Lithium Metal Battery. Crystals, 12 (9): (1290). [PMID: [10.3390/cryst12091290 ]
References 1. Zhen Shi, Jirong Wang, Kairui Guo, Hongli Wang, Hui Nie, Zhigang Xue. (2023) Deep eutectic solvent-assisted phase separation for polyurea-based polymer electrolytes. CHEMICAL ENGINEERING JOURNAL, 468 (143687). [PMID: [10.1016/j.cej.2023.143687 ] 2. Geng Tang, Shao-Peng Shen, Hong-Ji Li, Liang Zhang, Jin-Chi Zheng, Yuan Luo, Jun-Pei Yue, Yongzheng Shi, Zhe Chen. (2023) Flame-Retardant Gel Electrolyte toward High-Safety Lithium Metal Batteries with High-Mass-Loading Cathodes. Journal of Physical Chemistry C, 127 (20): (9463–9470). [PMID: [10.1021/acs.jpcc.3c00744 ] 3. Wanbao Wu, Qing Li, Miaomiao Cao, Deping Li, Jingyu Lu, Mingyu Li, Jiaheng Zhang. (2022) Non-Flammable Dual-Salt Deep Eutectic Electrolyte for High-Voltage Lithium Metal Battery. Crystals, 12 (9): (1290). [PMID: [10.3390/cryst12091290 ]
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