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Lithium diisopropylamide - 97%, high purity , CAS No.4111-54-0

  • ≥97%
Item Number
L432709
Grouped product items
SKUSizeAvailabilityPrice Qty
L432709-25g
25g
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$585.90
L432709-100g
100g
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$1,849.90
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Basic Description

SynonymsLithium diisopropylamide|4111-54-0|Diisopropylaminolithium|UNII-OL028KIW1I|OL028KIW1I|lithiodiisopropylamine|2-Propanamine, N-(1-methylethyl)-, lithium salt|lithium;di(propan-2-yl)azanide|lithiumdiisopropylamide|EINECS 223-893-0|Lithium di-isopropyl amide
Specifications & Purity97%
Product Description

Lithium diisopropylamide (LDA) is a hindered non-nucleophilic strong base that abstracts hydrogen from active carbon. It can be prepared from diisopropylamine and butyllithium in the presence of tetrahydrofuran.


Application

Lithium diisopropylamide can be used for the generation of carbanion or enolate anions from carbonyl group-containing compounds. It can also be used as a base in: The direct alkylation and acylation of ketones. The aldol condensation reaction. α-Selenation reaction. The synthesis of α, β- unsaturated carbonyl compounds from carbonyl compounds. The alkylation of acids, esters, amides, and nitriles. The initiation of anionic polymerization.

Names and Identifiers

IUPAC Name lithium;di(propan-2-yl)azanide
INCHI InChI=1S/C6H14N.Li/c1-5(2)7-6(3)4;/h5-6H,1-4H3;/q-1;+1
InChi Key ZCSHNCUQKCANBX-UHFFFAOYSA-N
Canonical SMILES [Li+].CC(C)[N-]C(C)C
Isomeric SMILES [Li+].CC(C)[N-]C(C)C
WGK Germany 3
PubChem CID 2724682
Molecular Weight 107.12
Beilstein 3655042
Reaxy-Rn 906717

Certificates

Certificate of Analysis(COA)

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Chemical and Physical Properties

Flash Point(°F)35.6 °F
Flash Point(°C)-18 °C
Boil Point(°C)60-136°C

Safety and Hazards(GHS)

Pictogram(s) GHS05,   GHS02
Signal Danger
Hazard Statements

H314:Causes severe skin burns and eye damage

H228:Flammable solid

H250:Catches fire spontaneously if exposed to air

Precautionary Statements

P280:Wear protective gloves/protective clothing/eye protection/face protection.

P370+P378:In case of fire: Use ... to extinguish.

P210:Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking.

P321:Specific treatment (see ... on this label).

P405:Store locked up.

P501:Dispose of contents/container to ...

P233:Keep container tightly closed.

P240:Ground/bond container and receiving equipment.

P264:Wash hands [and …] thoroughly after handling.

P260:Do not breathe dust/fume/gas/mist/vapors/spray.

P222:Do not allow contact with air.

P231:Handle under inert gas.

P241:Use explosion-proof [electrical/ventilating/lighting/.../] equipment.

P301+P330+P331:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P363:Wash contaminated clothing before reuse.

P302+P335+P334:Brush off loose particles from skin. Immerse in cool water [or wrap in wet bandages].

P305+P354+P338:IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing.

P302+P361+P354:IF ON SKIN: Take off Immediately all contaminated clothing. Immediately rinse with water for several minutes.

P316:Get emergency medical help immediately.

WGK Germany 3
Reaxy-Rn 906717
Merck Index 3196

Related Documents

 SDS

 Specification Sheet

References

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