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Lithium diisopropylamide - 97%, high purity , CAS No.4111-54-0

3 Citations

2M in THF/n-hexanes

CAS#: 4111-54-0(Solution)
Formula: C₆H₁₄LiN
Molecular Weight: 107.12

Item Number

L432709

Grouped product items
SKU	Size	Availability	Price	Qty
L432709-100ml	100ml	Available within 8-12 weeks(?) Production requires sourcing of materials. We appreciate your patience and understanding.	$54.90
L432709-500ml	500ml	Available within 8-12 weeks(?) Production requires sourcing of materials. We appreciate your patience and understanding.	$244.90

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Organic lithium

Basic Description

Synonyms	Lithium diisopropylamide \| 4111-54-0 \| Diisopropylaminolithium \| UNII-OL028KIW1I \| OL028KIW1I \| lithiodiisopropylamine \| 2-Propanamine, N-(1-methylethyl)-, lithium salt \| lithium;di(propan-2-yl)azanide \| lithiumdiisopropylamide \| EINECS 223-893-0 \| Lithium di-isopropyl amide
Specifications & Purity	2M in THF/n-hexanes
Storage Temp	Store at 2-8°C,Argon charged
Shipped In	Wet ice
Product Description	Lithium diisopropylamide (LDA) is a hindered non-nucleophilic strong base that abstracts hydrogen from active carbon. It can be prepared from diisopropylamine and butyllithium in the presence of tetrahydrofuran. Application Lithium diisopropylamide can be used for the generation of carbanion or enolate anions from carbonyl group-containing compounds. It can also be used as a base in: The direct alkylation and acylation of ketones. The aldol condensation reaction. α-Selenation reaction. The synthesis of α, β- unsaturated carbonyl compounds from carbonyl compounds. The alkylation of acids, esters, amides, and nitriles. The initiation of anionic polymerization.

Names and Identifiers

Molecular Weight	107.12

Certificates

Certificate of Analysis(COA)

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Chemical and Physical Properties

Sensitivity	Moisture & heat & air sensitive

Safety and Hazards(GHS)

Pictogram(s)	GHS08, GHS09, GHS05, GHS07, GHS02
Signal	Danger
Hazard Statements	H335:May cause respiratory irritation H351:Suspected of causing cancer H373:Causes damage to organs through prolonged or repeated exposure H314:Causes severe skin burns and eye damage H225:Highly Flammable liquid and vapor H336:May cause drowsiness or dizziness H303:May be harmful if swallowed H410:Very toxic to aquatic life with long lasting effects H304:May be fatal if swallowed and enters airways
Precautionary Statements	P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing. P273:Avoid release to the environment. P280:Wear protective gloves/protective clothing/eye protection/face protection. P301+P310:IF SWALLOWED: Immediately call a POISON CENTER/doctor/... P210:Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking. P310:Immediately call a POISON CENTER or doctor/physician. P312:Call a POISON CENTER or doctor/... if you feel unwell. P303+P361+P353:IF ON SKIN (or hair): Take off Immediately all contaminated clothing. Rinse SKIN with water [or shower]. P301+P330+P331:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing. P363:Wash contaminated clothing before reuse.

Citations of This Product

1. Jiejian Chen, Qiyao Yang, Minchen Liu, Mengting Lin, Tiantian Wang, Zhentao Zhang, Xincheng Zhong, Ningning Guo, Yiying Lu, Jing Xu, Changsheng Wang, Min Han, Qichun Wei. (2023) Remarkable Boron Delivery Of iRGD-Modified Polymeric Nanoparticles For Boron Neutron Capture Therapy. International Journal of Nanomedicine, [PMID:31632025]
2. Wei Zhang, Xiang-Fu Du, Ben Liu, Cairong Li, Jing Long, Mei-Xia Zhao, Zhenyu Yao, Xing-Jie Liang, Yuxiao Lai. (2022) Engineering Supramolecular Nanomedicine for Targeted Near Infrared-triggered Mitochondrial Dysfunction to Potentiate Cisplatin for Efficient Chemophototherapy. ACS Nano, 16 (1): (1421–1435). [PMID:34962119]
3. Rui Li, Haoran Xu, Yuhang Zhang, Lijing Chang, Yang Ma, Yanjun Hou, Shoulei Miao, Cheng Wang. (2021) Electrochromic properties of pyrene conductive polymers modified by chemical polymerization. RSC Advances, 11 (62): (39291-39305). [PMID:35492490]

References

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