Lithium diisopropylamide solution - 2.0 M in heptane/THF/ethylbenzene, high purity , CAS No.4111-54-0(Solution)

  • 2.0 M in heptane/THF/ethylbenzene
Item Number
L109346
Grouped product items
SKUSizeAvailabilityPrice Qty
L109346-100ml
100ml
In stock
$54.90
L109346-500ml
500ml
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$244.90

Basic Description

Specifications & Purity2.0 M in heptane/THF/ethylbenzene
Storage TempStore at 2-8°C,Argon charged
Shipped InWet ice
Product Description

Lithium diisopropylamide solution (LDA) is a sterically hindered non-nucleophilic strong base widely used in organic synthesis.

Titanium-ate enolates prepared from ketones by Ti(OiPr)4 and LDA underwent efficient radical trifluoromethylation providing trifluoromethyl ketones in good yield.Used in directed ortho-lithiation of arylsulfonyloxazolidinones to prepare N-substituted saccharin analogs.

Names and Identifiers

Molecular Weight 107.12

Certificates

Certificate of Analysis(COA)

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23 results found

Lot NumberCertificate TypeDateItem
J2424664Certificate of AnalysisOct 15, 2024 L109346
J2424663Certificate of AnalysisOct 15, 2024 L109346
H2419340Certificate of AnalysisAug 06, 2024 L109346
H2419339Certificate of AnalysisAug 06, 2024 L109346
F2427492Certificate of AnalysisMay 21, 2024 L109346
F2427487Certificate of AnalysisMay 21, 2024 L109346
F2427479Certificate of AnalysisMay 21, 2024 L109346
C23151690Certificate of AnalysisDec 15, 2023 L109346
E2408056Certificate of AnalysisDec 15, 2023 L109346
H2308624Certificate of AnalysisJul 31, 2023 L109346
H2308628Certificate of AnalysisJul 31, 2023 L109346
C2404183Certificate of AnalysisJul 31, 2023 L109346
C23151702Certificate of AnalysisFeb 07, 2023 L109346
L2209582Certificate of AnalysisNov 29, 2022 L109346
L2209586Certificate of AnalysisNov 29, 2022 L109346
J2210559Certificate of AnalysisSep 24, 2022 L109346
J2210575Certificate of AnalysisSep 24, 2022 L109346
F2220432Certificate of AnalysisJun 06, 2022 L109346
F2220431Certificate of AnalysisJun 05, 2022 L109346
F2220430Certificate of AnalysisJun 05, 2022 L109346
C2210066Certificate of AnalysisMar 23, 2022 L109346
D2211024Certificate of AnalysisMar 21, 2022 L109346
D2211012Certificate of AnalysisMar 21, 2022 L109346

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Chemical and Physical Properties

SensitivityMoisture sensitive ;heat sensitive;air sensitive

Safety and Hazards(GHS)

Pictogram(s) GHS08,   GHS09,   GHS05,   GHS07,   GHS02
Signal Danger
Hazard Statements

H335:May cause respiratory irritation

H351:Suspected of causing cancer

H373:Causes damage to organs through prolonged or repeated exposure

H314:Causes severe skin burns and eye damage

H225:Highly Flammable liquid and vapor

H336:May cause drowsiness or dizziness

H303:May be harmful if swallowed

H410:Very toxic to aquatic life with long lasting effects

H304:May be fatal if swallowed and enters airways

Precautionary Statements

P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.

P273:Avoid release to the environment.

P280:Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310:IF SWALLOWED: Immediately call a POISON CENTER/doctor/...

P210:Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking.

P310:Immediately call a POISON CENTER or doctor/physician.

P312:Call a POISON CENTER or doctor/... if you feel unwell.

P303+P361+P353:IF ON SKIN (or hair): Take off Immediately all contaminated clothing. Rinse SKIN with water [or shower].

P301+P330+P331:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P363:Wash contaminated clothing before reuse.

Related Documents

References

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