| SKU | Size | Availability | Price | Qty |
|---|---|---|---|---|
| L466070-100ml | 100ml | Available within 8-12 weeks(?) Production requires sourcing of materials. We appreciate your patience and understanding. | $382.90 |
| Synonyms | 53042-33-4|CID 23680082|DTXSID70635560|PUBCHEM_23680082|LITHIUM DIMETHYLAMINOBOROHYDRIDE 1M SO& |
|---|---|
| Specifications & Purity | 1M in THF |
| Storage Temp | Store at 2-8°C |
| Shipped In | Wet ice |
| Product Description | Description Lithium dimethylaminoborohydride is a reagent exhibiting dual properties like a metal hydride and nitrogen nucleophile. It is generally considered as an alternative to lithium aluminum hydride (LAH) for the reduction of carbonyl compounds, amides, and lactams.Lithium Aminoborohydride (LAB) ReagentsReactant for:B-H oxidative addition reactionsReduction and amination reactionsReduction of N-alkyl lactamsSynthesis of tertiary amine-boranesCapable of reducing a variety of fuctional groups.LABs can transfer the amine moiety, as in the case of the reaction with halopyridines and primary alkyl methanesulfonates. |
| INCHI | InChI=1S/C2H6BN.Li/c1-4(2)3;/h1-2H3;/q-1;+1 |
|---|---|
| InChi Key | JUNGCHBOXMGZCV-UHFFFAOYSA-N |
| Canonical SMILES | [Li+].[B-]N(C)C |
| Isomeric SMILES | [Li+].[B-]N(C)C |
| WGK Germany | 3 |
| PubChem CID | 23680082 |
| Molecular Weight | 61.9 |
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| Flash Point(°F) | 1.4 °F |
|---|---|
| Flash Point(°C) | -17 °C |
| Pictogram(s) | GHS05, GHS02 |
|---|---|
| Signal | Danger |
| Hazard Statements | H260:In contact with water releases flammable gases which may ignite spontaneously H314:Causes severe skin burns and eye damage H228:Flammable solid |
| Precautionary Statements | P280:Wear protective gloves/protective clothing/eye protection/face protection. P223:Do not allow contact with water. P231+P232:Handle under inert gas/... Protect from moisture. P370+P378:In case of fire: Use ... to extinguish. P210:Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking. P321:Specific treatment (see ... on this label). P405:Store locked up. P501:Dispose of contents/container to ... P240:Ground/bond container and receiving equipment. P264:Wash hands [and …] thoroughly after handling. P260:Do not breathe dust/fume/gas/mist/vapors/spray. P241:Use explosion-proof [electrical/ventilating/lighting/.../] equipment. P301+P330+P331:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing. P363:Wash contaminated clothing before reuse. P402+P404:Store in a dry place. Store in a closed container. P302+P335+P334:Brush off loose particles from skin. Immerse in cool water [or wrap in wet bandages]. P305+P354+P338:IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. P302+P361+P354:IF ON SKIN: Take off Immediately all contaminated clothing. Immediately rinse with water for several minutes. P316:Get emergency medical help immediately. |
| WGK Germany | 3 |
| RIDADR | UN3399A4.3(3)/PGI |
| 1. S Thomas,T Huynh,V Enriquez-Rios,B Singaram. (2001-11-27) Aminoborohydrides. 14. Lithium aminoborohydrides in the selective reduction or amination of alkyl methanesulfonate esters.. Organic letters, 3 ((24)): (3915-3918). [PMID:11720568] |
| 2. Shannon Thomas,Sara Roberts,Lubov Pasumansky,Soya Gamsey,Bakthan Singaram. (2003-10-11) Aminoborohydrides 15. The first mild and efficient method for generating 2-(dialkylamino)-pyridines from 2-fluoropyridine.. Organic letters, 5 ((21)): (3867-3870). [PMID:14535730] |
