Lithium Tetrafluoroborate - 99.9% metals basis, high purity , CAS No.14283-07-9

  • ≥99.9% metals basis
Item Number
L107398
Grouped product items
SKUSizeAvailabilityPrice Qty
L107398-5g
5g
In stock
$58.90
L107398-25g
25g
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$205.90
L107398-100g
100g
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$583.90

Basic Description

SynonymsLithium tetrafluoroborate | 14283-07-9 | Lithium fluoroborate | lithium borofluoride | lithium;tetrafluoroborate | Lithium tetrafluoroborate (LiBF4 ) | Lithium tetrafluoroborate, anhydrous | Borate(1-), tetrafluoro-, lithium | MFCD00011087 | LiBF4 | AF751CNK2N | UFXJWFBILHTTET
Specifications & Purity≥99.9% metals basis
Storage TempArgon charged
Shipped InNormal

Names and Identifiers

IUPAC Name lithium;tetrafluoroborate
INCHI InChI=1S/BF4.Li/c2-1(3,4)5;/q-1;+1
InChi Key UFXJWFBILHTTET-UHFFFAOYSA-N
Canonical SMILES [Li+].[B-](F)(F)(F)F
Isomeric SMILES [Li+].[B-](F)(F)(F)F
WGK Germany 3
PubChem CID 4298216
UN Number 3260
Packing Group II
Molecular Weight 93.75

Certificates

Certificate of Analysis(COA)

Enter Lot Number to search for COA:

Find and download the COA for your product by matching the lot number on the packaging.

9 results found

Lot NumberCertificate TypeDateItem
L2311128Certificate of AnalysisDec 18, 2023 L107398
L2311129Certificate of AnalysisDec 18, 2023 L107398
D1817078Certificate of AnalysisFeb 22, 2022 L107398
B2215595Certificate of AnalysisFeb 17, 2022 L107398
B2215597Certificate of AnalysisFeb 17, 2022 L107398
F2228320Certificate of AnalysisFeb 17, 2022 L107398
F2228321Certificate of AnalysisFeb 17, 2022 L107398
F2228323Certificate of AnalysisFeb 17, 2022 L107398
I2128214Certificate of AnalysisOct 11, 2021 L107398

Chemical and Physical Properties

Melt Point(°C)293-300 ℃ (dec.) (lit.)

Safety and Hazards(GHS)

Pictogram(s) GHS08,   GHS05,   GHS07
Signal Danger
Hazard Statements

H315:Causes skin irritation

H319:Causes serious eye irritation

H314:Causes severe skin burns and eye damage

H302:Harmful if swallowed

H318:Causes serious eye damage

H312:Harmful in contact with skin

H332:Harmful if inhaled

Precautionary Statements

P261:Avoid breathing dust/fume/gas/mist/vapors/spray.

P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.

P280:Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352:IF ON SKIN: wash with plenty of water.

P321:Specific treatment (see ... on this label).

P405:Store locked up.

P501:Dispose of contents/container to ...

P264:Wash hands [and …] thoroughly after handling.

P260:Do not breathe dust/fume/gas/mist/vapors/spray.

P271:Use only outdoors or in a well-ventilated area.

P270:Do not eat, drink or smoke when using this product.

P301+P330+P331:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P363:Wash contaminated clothing before reuse.

P362+P364:Take off contaminated clothing and wash it before reuse.

P330:Rinse mouth.

P264+P265:Wash hands [and …] thoroughly after handling. Do not touch eyes.

P301+P317:IF SWALLOWED: Get medical help.

P305+P354+P338:IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing.

P317:Get emergency medical help.

P337+P317:If eye irritation persists: Get medical help.

P332+P317:If skin irritation occurs: Get medical help.

P302+P361+P354:IF ON SKIN: Take off Immediately all contaminated clothing. Immediately rinse with water for several minutes.

P316:Get emergency medical help immediately.

WGK Germany 3
Class 8
Merck Index 5543

Related Documents

Citations of This Product

1. Qifeng Yang, Yiming Mo.  (2023)  Direct Electrochemical Oxidation of Benzylic C–H Bond by La2O3@C/CP Composite Electrode with Water as the Green Oxygen Source.  INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,  62  (46): (19427–19436).  [PMID:2969919] [10.1021/acs.iecr.3c02229]
2. Tianxu Wang, Lei Wang, Yuanze Chen, Lijie Zhu, Mingqing Yang, Shiyu Zhang, Chunhui Niu, Yong Lv.  (2023)  Polyaniline Films Fabricated by Pre-Nucleation Electrodeposition Method with High Electrochemical Activity: Parameter Optimization and Analysis.  MACROMOLECULAR CHEMISTRY AND PHYSICS,    (15): (2300333).  [PMID:19531583] [10.1002/macp.202300333]
3. Leipeng Zhang, Tingting Hao, Shanshan Song, Bo Wang, Dongqi Liu, Zichen Ren, Wenchao Liu, Yike Zhang, Gaoping Xu, Xiangqiao Yan, Yuan Lu, Yao Li.  (2023)  Enhancing infrared electrochromic properties of the poly(styrene sulfonate) doped polyaniline composite film by morphology regulation.  CHEMICAL ENGINEERING JOURNAL,  475  (1): (145927).  [PMID:10202154] [10.1016/j.cej.2023.145927]
4. Leng Yumin, Qu Panpan, Wang Anyi, Jiang Kai, Dong Yuchen, Han Pei, Cheng Jinbing, Zhang Liwei.  (2023)  Fabrication of glass-based analytical devices by immobilizing nanomaterials on glass substrate with a fluorescent glue for the highly sensitive determination of mercury ions.  MICROCHIMICA ACTA,  190  (8): (1-8).  [PMID:37505293] [10.1007/s00604-023-05875-z]
5. Geng Tang, Shao-Peng Shen, Hong-Ji Li, Liang Zhang, Jin-Chi Zheng, Yuan Luo, Jun-Pei Yue, Yongzheng Shi, Zhe Chen.  (2023)  Flame-Retardant Gel Electrolyte toward High-Safety Lithium Metal Batteries with High-Mass-Loading Cathodes.  Journal of Physical Chemistry C,  127  (20): (9463–9470).  [PMID:] [10.1021/acs.jpcc.3c00744]
6. Xiaojing Lv, Xuchen Zhu, Ling Zhang, Mi Ouyang, Minao Xia, Chunyan Liu, Cheng Zhang.  (2023)  Highly transparent to red/green/blue photo-crosslinkable polymer for patterned electrochromic device.  Journal of Materials Chemistry C,  11  (16): (5490-5497).  [PMID:] [10.1039/D3TC00325F]
7. Zichen Ren, Gaoping Xu, Bo Wang, Shanshan Song, Tingting Hao, Dongqi Liu, Yike Zhang, Jiupeng Zhao, Leipeng Zhang, Yao Li.  (2023)  Polyaniline-Based Infrared Dynamic Patterned Encoder with Multiple Thermal Radiation Characteristics.  ACS Applied Materials & Interfaces,  15  (11): (14740–14747).  [PMID:36884015] [10.1021/acsami.2c19993]
8. Zexing Xie, Meiying Xie, Tingting Tang, Fan Yang, Liyan Xue, Zhengming Jiang.  (2023)  β-Diketone-Driven Deep Eutectic Solvent for Ultra-Efficient Natural Stable Lithium-7 Isotope Separation.  Separations,  10  (2): (111).  [PMID:] [10.3390/separations10020111]
9. Xinzhen Lu, Yifeng Cheng, Menghao Li, Yucheng Zou, Cheng Zhen, Duojie Wu, Xianbin Wei, Xiangyan Li, Xuming Yang, Meng Gu.  (2023)  A Stable Polymer-based Solid-State Lithium Metal Battery and its Interfacial Characteristics Revealed by Cryogenic Transmission Electron Microscopy.  ADVANCED FUNCTIONAL MATERIALS,  33  (12): (2212847).  [PMID:] [10.1002/adfm.202212847]
10. Jingcheng Zhang, Linhan Huang, Taoxiong Fang, Zhipeng Xiang, Sijia He, Pekka Peljo, Shiyu Gan, Xinjian Huang, Haiqiang Deng.  (2022)  Quantized Collision/Fusion Events of Anionic Ionosomes at a Polarized Soft Micro-Interface.  Chemistry-An Asian Journal,  17  (24): (e202200731).  [PMID:36208291] [10.1002/asia.202200731]
11. Yunju Wang, Shunchao Ma, Hongyu Wang.  (2022)  Difluoro(oxalato)borate's Role in the Intercalation Behavior of Mixed Anions from Sulfolane.  ChemSusChem,  16  (4): (e202201218).  [PMID:36039804] [10.1002/cssc.202201218]
12. Sijing Liu, Yuewang Yang, Shusheng Chen, Jiongzhi Zheng, Dong Gyu Lee, Dan Li, Jinglei Yang, Baoling Huang.  (2022)  High p- and n-type thermopowers in stretchable self-healing ionogels.  Nano Energy,  100  (107542).  [PMID:] [10.1016/j.nanoen.2022.107542]
13. Chen Zilong, Zeng Hao, Chu Dongdong, Zhang Fangfang, Cheng Meng, Yang Zhihua, Pan Shilie.  (2022)  LiB5O5F2(OH)4: A new deep-ultraviolet birefringent crystal with [B5O5F2(OH)4] anionic group.  Science China-Materials,  65  (9): (2585-2590).  [PMID:] [10.1007/s40843-021-1998-4]
14. Shujing Wen, Chao Luo, Qingrong Wang, Zhenyao Wei, Yanxiang Zeng, Yidong Jiang, Guangzhao Zhang, Hongli Xu, Jun Wang, Chaoyang Wang, Jian Chang, Yonghong Deng.  (2022)  Integrated design of ultrathin crosslinked network polymer electrolytes for flexible and stable all-solid-state lithium batteries.  Energy Storage Materials,  47  (453).  [PMID:] [10.1016/j.ensm.2022.02.035]
15. Tingting Feng, Guozhu Yang, Shu Zhang, Ziqiang Xu, Haiping Zhou, Mengqiang Wu.  (2022)  Low-temperature and high-voltage lithium-ion battery enabled by localized high-concentration carboxylate electrolytes.  CHEMICAL ENGINEERING JOURNAL,  433  (134138).  [PMID:] [10.1016/j.cej.2021.134138]
16. Zhiwei Chen, Jiangwei Zhang, Chao Zhang, Ruixue Cui, Meijie Tan, Song Guo, Hongjuan Wang, Jiqing Jiao, Tongbu Lu.  (2022)  Regulating the coordination metal center in immobilized molecular complexes as single-atomic electrocatalysts for highly active, selective and durable electrochemical CO2 reduction.  JOURNAL OF POWER SOURCES,  519  (230788).  [PMID:] [10.1016/j.jpowsour.2021.230788]
17. Zhong Fang, Yang Yang, Tianle Zheng, Nan Wang, Congxiao Wang, Xiaoli Dong, Yonggang Wang, Yongyao Xia.  (2021)  An all-climate CFx/Li battery with mechanism-guided electrolyte.  Energy Storage Materials,  42  (477).  [PMID:] [10.1016/j.ensm.2021.08.002]
18. Zhaoquan Zheng, Bingyu Wang, Jing Chen, Yan Wang, Ziyue Miao, Cenyao Shang, Qiang Zhang.  (2021)  Facile synthesis of Antibacterial, Biocompatible, quaternized Poly(ionic liquid)s with pendant saccharides.  EUROPEAN POLYMER JOURNAL,  158  (110702).  [PMID:] [10.1016/j.eurpolymj.2021.110702]
19. Weixia Lv, Caijian Zhu, Jun Chen, Caixia Ou, Qian Zhang, Shengwen Zhong.  (2021)  High performance of low-temperature electrolyte for lithium-ion batteries using mixed additives.  CHEMICAL ENGINEERING JOURNAL,  418  (129400).  [PMID:] [10.1016/j.cej.2021.129400]
20. Shujuan Han, Miriding Mutailipu, Abudukadi Tudi, Zhihua Yang, Shilie Pan.  (2020)  PbB5O7F3: A High-Performing Short-Wavelength Nonlinear Optical Material.  CHEMISTRY OF MATERIALS,  32  (5): (2172–2179).  [PMID:] [10.1021/acs.chemmater.0c00150]
21. Yunhui Shi, Yutian Wang, Yifan Gu, Liting Zheng, Shaoshuai Ma, Xinhua Xu.  (2020)  Self-healable and stretchable ionogels serve as electrolytes and substrates for integrated all-in-one micro-supercapacitors.  CHEMICAL ENGINEERING JOURNAL,  392  (123645).  [PMID:] [10.1016/j.cej.2019.123645]
22. Yunju Wang, Jiayu Li, Yuhao Huang, Hongyu Wang.  (2019)  Anion Storage Behavior of Graphite Electrodes in LiBF4/Sulfone/Ethyl Methyl Carbonate Solutions.  LANGMUIR,  35  (46): (14804–14811).  [PMID:31660747] [10.1021/acs.langmuir.9b02758]
23. Zenghong Song, Meirong Cai, Yongmin Liang, Mingjin Fan, Feng Zhou, Weimin Liu.  (2013)  In situ preparation of anti-corrosion ionic liquids as the lubricant additives in multiply-alkylated cyclopentanes.  RSC Advances,  (44): (21715-21721).  [PMID:] [10.1039/C3RA42092B]
24. Lijuan Shi, Liqiang Zheng.  (2012)  Aggregation Behavior of Surface Active Imidazolium Ionic Liquids in Ethylammonium Nitrate: Effect of Alkyl Chain Length, Cations, and Counterions.  JOURNAL OF PHYSICAL CHEMISTRY B,  116  (7): (2162–2172).  [PMID:22268528] [10.1021/jp211338k]

References

1. Qifeng Yang, Yiming Mo.  (2023)  Direct Electrochemical Oxidation of Benzylic C–H Bond by La2O3@C/CP Composite Electrode with Water as the Green Oxygen Source.  INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,  62  (46): (19427–19436).  [PMID:2969919] [10.1021/acs.iecr.3c02229]
2. Tianxu Wang, Lei Wang, Yuanze Chen, Lijie Zhu, Mingqing Yang, Shiyu Zhang, Chunhui Niu, Yong Lv.  (2023)  Polyaniline Films Fabricated by Pre-Nucleation Electrodeposition Method with High Electrochemical Activity: Parameter Optimization and Analysis.  MACROMOLECULAR CHEMISTRY AND PHYSICS,    (15): (2300333).  [PMID:19531583] [10.1002/macp.202300333]
3. Leipeng Zhang, Tingting Hao, Shanshan Song, Bo Wang, Dongqi Liu, Zichen Ren, Wenchao Liu, Yike Zhang, Gaoping Xu, Xiangqiao Yan, Yuan Lu, Yao Li.  (2023)  Enhancing infrared electrochromic properties of the poly(styrene sulfonate) doped polyaniline composite film by morphology regulation.  CHEMICAL ENGINEERING JOURNAL,  475  (1): (145927).  [PMID:10202154] [10.1016/j.cej.2023.145927]
4. Leng Yumin, Qu Panpan, Wang Anyi, Jiang Kai, Dong Yuchen, Han Pei, Cheng Jinbing, Zhang Liwei.  (2023)  Fabrication of glass-based analytical devices by immobilizing nanomaterials on glass substrate with a fluorescent glue for the highly sensitive determination of mercury ions.  MICROCHIMICA ACTA,  190  (8): (1-8).  [PMID:37505293] [10.1007/s00604-023-05875-z]
5. Geng Tang, Shao-Peng Shen, Hong-Ji Li, Liang Zhang, Jin-Chi Zheng, Yuan Luo, Jun-Pei Yue, Yongzheng Shi, Zhe Chen.  (2023)  Flame-Retardant Gel Electrolyte toward High-Safety Lithium Metal Batteries with High-Mass-Loading Cathodes.  Journal of Physical Chemistry C,  127  (20): (9463–9470).  [PMID:] [10.1021/acs.jpcc.3c00744]
6. Xiaojing Lv, Xuchen Zhu, Ling Zhang, Mi Ouyang, Minao Xia, Chunyan Liu, Cheng Zhang.  (2023)  Highly transparent to red/green/blue photo-crosslinkable polymer for patterned electrochromic device.  Journal of Materials Chemistry C,  11  (16): (5490-5497).  [PMID:] [10.1039/D3TC00325F]
7. Zichen Ren, Gaoping Xu, Bo Wang, Shanshan Song, Tingting Hao, Dongqi Liu, Yike Zhang, Jiupeng Zhao, Leipeng Zhang, Yao Li.  (2023)  Polyaniline-Based Infrared Dynamic Patterned Encoder with Multiple Thermal Radiation Characteristics.  ACS Applied Materials & Interfaces,  15  (11): (14740–14747).  [PMID:36884015] [10.1021/acsami.2c19993]
8. Zexing Xie, Meiying Xie, Tingting Tang, Fan Yang, Liyan Xue, Zhengming Jiang.  (2023)  β-Diketone-Driven Deep Eutectic Solvent for Ultra-Efficient Natural Stable Lithium-7 Isotope Separation.  Separations,  10  (2): (111).  [PMID:] [10.3390/separations10020111]
9. Xinzhen Lu, Yifeng Cheng, Menghao Li, Yucheng Zou, Cheng Zhen, Duojie Wu, Xianbin Wei, Xiangyan Li, Xuming Yang, Meng Gu.  (2023)  A Stable Polymer-based Solid-State Lithium Metal Battery and its Interfacial Characteristics Revealed by Cryogenic Transmission Electron Microscopy.  ADVANCED FUNCTIONAL MATERIALS,  33  (12): (2212847).  [PMID:] [10.1002/adfm.202212847]
10. Jingcheng Zhang, Linhan Huang, Taoxiong Fang, Zhipeng Xiang, Sijia He, Pekka Peljo, Shiyu Gan, Xinjian Huang, Haiqiang Deng.  (2022)  Quantized Collision/Fusion Events of Anionic Ionosomes at a Polarized Soft Micro-Interface.  Chemistry-An Asian Journal,  17  (24): (e202200731).  [PMID:36208291] [10.1002/asia.202200731]
11. Yunju Wang, Shunchao Ma, Hongyu Wang.  (2022)  Difluoro(oxalato)borate's Role in the Intercalation Behavior of Mixed Anions from Sulfolane.  ChemSusChem,  16  (4): (e202201218).  [PMID:36039804] [10.1002/cssc.202201218]
12. Sijing Liu, Yuewang Yang, Shusheng Chen, Jiongzhi Zheng, Dong Gyu Lee, Dan Li, Jinglei Yang, Baoling Huang.  (2022)  High p- and n-type thermopowers in stretchable self-healing ionogels.  Nano Energy,  100  (107542).  [PMID:] [10.1016/j.nanoen.2022.107542]
13. Chen Zilong, Zeng Hao, Chu Dongdong, Zhang Fangfang, Cheng Meng, Yang Zhihua, Pan Shilie.  (2022)  LiB5O5F2(OH)4: A new deep-ultraviolet birefringent crystal with [B5O5F2(OH)4] anionic group.  Science China-Materials,  65  (9): (2585-2590).  [PMID:] [10.1007/s40843-021-1998-4]
14. Shujing Wen, Chao Luo, Qingrong Wang, Zhenyao Wei, Yanxiang Zeng, Yidong Jiang, Guangzhao Zhang, Hongli Xu, Jun Wang, Chaoyang Wang, Jian Chang, Yonghong Deng.  (2022)  Integrated design of ultrathin crosslinked network polymer electrolytes for flexible and stable all-solid-state lithium batteries.  Energy Storage Materials,  47  (453).  [PMID:] [10.1016/j.ensm.2022.02.035]
15. Tingting Feng, Guozhu Yang, Shu Zhang, Ziqiang Xu, Haiping Zhou, Mengqiang Wu.  (2022)  Low-temperature and high-voltage lithium-ion battery enabled by localized high-concentration carboxylate electrolytes.  CHEMICAL ENGINEERING JOURNAL,  433  (134138).  [PMID:] [10.1016/j.cej.2021.134138]
16. Zhiwei Chen, Jiangwei Zhang, Chao Zhang, Ruixue Cui, Meijie Tan, Song Guo, Hongjuan Wang, Jiqing Jiao, Tongbu Lu.  (2022)  Regulating the coordination metal center in immobilized molecular complexes as single-atomic electrocatalysts for highly active, selective and durable electrochemical CO2 reduction.  JOURNAL OF POWER SOURCES,  519  (230788).  [PMID:] [10.1016/j.jpowsour.2021.230788]
17. Zhong Fang, Yang Yang, Tianle Zheng, Nan Wang, Congxiao Wang, Xiaoli Dong, Yonggang Wang, Yongyao Xia.  (2021)  An all-climate CFx/Li battery with mechanism-guided electrolyte.  Energy Storage Materials,  42  (477).  [PMID:] [10.1016/j.ensm.2021.08.002]
18. Zhaoquan Zheng, Bingyu Wang, Jing Chen, Yan Wang, Ziyue Miao, Cenyao Shang, Qiang Zhang.  (2021)  Facile synthesis of Antibacterial, Biocompatible, quaternized Poly(ionic liquid)s with pendant saccharides.  EUROPEAN POLYMER JOURNAL,  158  (110702).  [PMID:] [10.1016/j.eurpolymj.2021.110702]
19. Weixia Lv, Caijian Zhu, Jun Chen, Caixia Ou, Qian Zhang, Shengwen Zhong.  (2021)  High performance of low-temperature electrolyte for lithium-ion batteries using mixed additives.  CHEMICAL ENGINEERING JOURNAL,  418  (129400).  [PMID:] [10.1016/j.cej.2021.129400]
20. Shujuan Han, Miriding Mutailipu, Abudukadi Tudi, Zhihua Yang, Shilie Pan.  (2020)  PbB5O7F3: A High-Performing Short-Wavelength Nonlinear Optical Material.  CHEMISTRY OF MATERIALS,  32  (5): (2172–2179).  [PMID:] [10.1021/acs.chemmater.0c00150]
21. Yunhui Shi, Yutian Wang, Yifan Gu, Liting Zheng, Shaoshuai Ma, Xinhua Xu.  (2020)  Self-healable and stretchable ionogels serve as electrolytes and substrates for integrated all-in-one micro-supercapacitors.  CHEMICAL ENGINEERING JOURNAL,  392  (123645).  [PMID:] [10.1016/j.cej.2019.123645]
22. Yunju Wang, Jiayu Li, Yuhao Huang, Hongyu Wang.  (2019)  Anion Storage Behavior of Graphite Electrodes in LiBF4/Sulfone/Ethyl Methyl Carbonate Solutions.  LANGMUIR,  35  (46): (14804–14811).  [PMID:31660747] [10.1021/acs.langmuir.9b02758]
23. Zenghong Song, Meirong Cai, Yongmin Liang, Mingjin Fan, Feng Zhou, Weimin Liu.  (2013)  In situ preparation of anti-corrosion ionic liquids as the lubricant additives in multiply-alkylated cyclopentanes.  RSC Advances,  (44): (21715-21721).  [PMID:] [10.1039/C3RA42092B]
24. Lijuan Shi, Liqiang Zheng.  (2012)  Aggregation Behavior of Surface Active Imidazolium Ionic Liquids in Ethylammonium Nitrate: Effect of Alkyl Chain Length, Cations, and Counterions.  JOURNAL OF PHYSICAL CHEMISTRY B,  116  (7): (2162–2172).  [PMID:22268528] [10.1021/jp211338k]

Solution Calculators