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2-Mercaptobenzothiazole - 98%, high purity , CAS No.149-30-4

≥98%

CAS#: 149-30-4
Formula: C₇H₅NS₂
Molecular Weight: 167.25
Beilstein Registry Number: 119484
EC Number: 205-736-8
MDL number: MFCD00005781
PubChem CID: 697993
PubChem SID: 488191178

Item Number

M104864

Grouped product items
SKU	Size	Availability	Price
M104864-25g	25g	In stock	$9.90
M104864-100g	100g	In stock	$27.90
M104864-250g	250g	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$48.90
M104864-500g	500g	In stock	$69.90

View related series

Benzothiazoles Five-Membered Heterocyclic Compounds Thiazoles

Basic Description

Synonyms	2-Mercaptobenzothiazole \| 149-30-4 \| 2-Benzothiazolethiol \| Benzo[d]thiazole-2(3H)-thione \| Captax \| Benzothiazolethiol \| Benzo[d]thiazole-2-thiol \| MERCAPTOBENZOTHIAZOLE \| 1,3-Benzothiazole-2-thiol \| 2(3H)-Benzothiazolethione \| Dermacid \| Benzothiazole-2-thiol \| Sulfadene \| 11809
Specifications & Purity	≥98%
Storage Temp	Argon charged
Shipped In	Normal
Product Description	2-Mercaptobenzothiazole (MBT) has been used in the synthesis of MBT functionalized mesoporous silica which can be used as an adsorbent for the removal of Hg(II) from aqueous solution. It can also be used as a: • Reference compound in photocatalytic activity tests under UV or visible light irradiation. • Starting material for the synthesis of conjugates of 2-MBT for antitubercular activity studies. • Starting material for the synthesis of 4-thiazolidinones.

Associated Targets(Human)

Vitamin D receptor 26531 Activities

Activity Type	Relation	Activity value	Units	Action Type	Journal	PubMed Id	doi	Assay Aladdin ID

Peroxisome proliferator-activated receptor gamma 15191 Activities

Activity Type	Relation	Activity value	Units	Action Type	Journal	PubMed Id	doi	Assay Aladdin ID

Thyroid hormone receptor beta-1 7926 Activities

Activity Type	Relation	Activity value	Units	Action Type	Journal	PubMed Id	doi	Assay Aladdin ID

Retinoid X receptor alpha 3637 Activities

Activity Type	Relation	Activity value	Units	Action Type	Journal	PubMed Id	doi	Assay Aladdin ID

Aryl hydrocarbon receptor 1071 Activities

Activity Type	Relation	Activity value	Units	Action Type	Journal	PubMed Id	doi	Assay Aladdin ID

Arachidonate 15-lipoxygenase, type II 7244 Activities

Activity Type	Relation	Activity value	Units	Action Type	Journal	PubMed Id	doi	Assay Aladdin ID

Aldehyde dehydrogenase 1A1 77053 Activities

Activity Type	Relation	Activity value	Units	Action Type	Journal	PubMed Id	doi	Assay Aladdin ID

Arachidonate 15-lipoxygenase 7108 Activities

Activity Type	Relation	Activity value	Units	Action Type	Journal	PubMed Id	doi	Assay Aladdin ID

Pyruvate dehydrogenase kinase isoform 1 2021 Activities

Activity Type	Relation	Activity value	Units	Action Type	Journal	PubMed Id	doi	Assay Aladdin ID

Cytochrome P450 3A4 53859 Activities

Activity Type	Relation	Activity value	Units	Action Type	Journal	PubMed Id	doi	Assay Aladdin ID

MCF7 126967 Activities

Activity Type	Relation	Activity value	Units	Action Type	Journal	PubMed Id	doi	Assay Aladdin ID

HeLa 62764 Activities

Activity Type	Relation	Activity value	Units	Action Type	Journal	PubMed Id	doi	Assay Aladdin ID

Proteasome Macropain subunit MB1 2451 Activities

Activity Type	Relation	Activity value	Units	Action Type	Journal	PubMed Id	doi	Assay Aladdin ID

UDP-glucuronosyltransferase 2B7 787 Activities

Activity Type	Relation	Activity value	Units	Action Type	Journal	PubMed Id	doi	Assay Aladdin ID

Indoleamine 2,3-dioxygenase 6650 Activities

Activity Type	Relation	Activity value	Units	Action Type	Journal	PubMed Id	doi	Assay Aladdin ID

DNA-(apurinic or apyrimidinic site) lyase 38016 Activities

Activity Type	Relation	Activity value	Units	Action Type	Journal	PubMed Id	doi	Assay Aladdin ID

Proteasome subunit beta type-8 743 Activities

Activity Type	Relation	Activity value	Units	Action Type	Journal	PubMed Id	doi	Assay Aladdin ID

Histone-lysine N-methyltransferase, H3 lysine-9 specific 3 93046 Activities

Activity Type	Relation	Activity value	Units	Action Type	Journal	PubMed Id	doi	Assay Aladdin ID

Tyrosyl-DNA phosphodiesterase 1 345557 Activities

Activity Type	Relation	Activity value	Units	Action Type	Journal	PubMed Id	doi	Assay Aladdin ID

Lysine-specific demethylase 4D-like 40243 Activities

Activity Type	Relation	Activity value	Units	Action Type	Journal	PubMed Id	doi	Assay Aladdin ID

15-hydroxyprostaglandin dehydrogenase [NAD+] 24926 Activities

Activity Type	Relation	Activity value	Units	Action Type	Journal	PubMed Id	doi	Assay Aladdin ID

Solute carrier organic anion transporter family member 1B1 2672 Activities

Activity Type	Relation	Activity value	Units	Action Type	Journal	PubMed Id	doi	Assay Aladdin ID

Solute carrier organic anion transporter family member 1B3 2517 Activities

Activity Type	Relation	Activity value	Units	Action Type	Journal	PubMed Id	doi	Assay Aladdin ID

Runt-related transcription factor 1/Core-binding factor subunit beta 7867 Activities

Activity Type	Relation	Activity value	Units	Action Type	Journal	PubMed Id	doi	Assay Aladdin ID

Associated Targets(non-human)

Histone deacetylase 6 222 Activities

Activity Type	Relation	Activity value	Units	Action Type	Journal	PubMed Id	doi	Assay Aladdin ID

Aspergillus flavus 8875 Activities

Activity Type	Relation	Activity value	Units	Action Type	Journal	PubMed Id	doi	Assay Aladdin ID

Mycobacterium avium 4587 Activities

Activity Type	Relation	Activity value	Units	Action Type	Journal	PubMed Id	doi	Assay Aladdin ID

Mycobacterium kansasii 6484 Activities

Activity Type	Relation	Activity value	Units	Action Type	Journal	PubMed Id	doi	Assay Aladdin ID

Mycobacterium tuberculosis 203094 Activities

Activity Type	Relation	Activity value	Units	Action Type	Journal	PubMed Id	doi	Assay Aladdin ID

Candida albicans 78123 Activities

Activity Type	Relation	Activity value	Units	Action Type	Journal	PubMed Id	doi	Assay Aladdin ID

Mus musculus 284745 Activities

Activity Type	Relation	Activity value	Units	Action Type	Journal	PubMed Id	doi	Assay Aladdin ID

Histone acetyltransferase GCN5 89 Activities

Activity Type	Relation	Activity value	Units	Action Type	Journal	PubMed Id	doi	Assay Aladdin ID

Luciferin 4-monooxygenase 66902 Activities

Activity Type	Relation	Activity value	Units	Action Type	Journal	PubMed Id	doi	Assay Aladdin ID

Replicase polyprotein 1ab 378 Activities

Activity Type	Relation	Activity value	Units	Action Type	Journal	PubMed Id	doi	Assay Aladdin ID

Putative uncharacterized protein 49 Activities

Activity Type	Relation	Activity value	Units	Action Type	Journal	PubMed Id	doi	Assay Aladdin ID

Nuclear factor erythroid 2-related factor 2 214 Activities

Activity Type	Relation	Activity value	Units	Action Type	Journal	PubMed Id	doi	Assay Aladdin ID

Nuclear receptor ROR-gamma 89407 Activities

Activity Type	Relation	Activity value	Units	Action Type	Journal	PubMed Id	doi	Assay Aladdin ID

SARS-CoV-2 38078 Activities

Activity Type	Relation	Activity value	Units	Action Type	Journal	PubMed Id	doi	Assay Aladdin ID

Names and Identifiers

Pubchem Sid	488191178
Pubchem Sid Url	https://pubchem.ncbi.nlm.nih.gov/substance/488191178
IUPAC Name	3H-1,3-benzothiazole-2-thione
INCHI	InChI=1S/C7H5NS2/c9-7-8-5-3-1-2-4-6(5)10-7/h1-4H,(H,8,9)
InChi Key	YXIWHUQXZSMYRE-UHFFFAOYSA-N
Canonical SMILES	C1=CC=C2C(=C1)NC(=S)S2
Isomeric SMILES	C1=CC=C2C(=C1)NC(=S)S2
WGK Germany	2
RTECS	DL6475000
Alternate CAS	118090-09-8
PubChem CID	697993
UN Number	2811
Packing Group	I
Molecular Weight	167.25
Beilstein	119484
Reaxy-Rn	508810

Certificates

Certificate of Analysis(COA)

Enter Lot Number to search for COA:

To view the certificate results,please click on a Lot number.For Lot numbers from past orders,please use our order status section

12 results found

Lot Number	Certificate Type	Date	Item
H2401465	Certificate of Analysis	Jun 17, 2024	M104864
H2408680	Certificate of Analysis	Jun 14, 2024	M104864
H2408681	Certificate of Analysis	Jun 14, 2024	M104864
H2423490	Certificate of Analysis	Jun 14, 2024	M104864
H2423491	Certificate of Analysis	Jun 14, 2024	M104864
H2423492	Certificate of Analysis	Jun 14, 2024	M104864
H2423493	Certificate of Analysis	Jun 14, 2024	M104864
H2423494	Certificate of Analysis	Jun 14, 2024	M104864
J2325397	Certificate of Analysis	Oct 13, 2023	M104864
J2325398	Certificate of Analysis	Oct 13, 2023	M104864
I1813063	Certificate of Analysis	Jul 14, 2022	M104864
B2302334	Certificate of Analysis	Dec 08, 2021	M104864

Chemical and Physical Properties

Solubility	Soluble in ethanol, diethyl ether, benzene, carbon tetrachloride, alkali and alkaline solutions. Slightly soluble in acetone, naphtha and glacial acetic acid. Insoluble in water and gasoline.
Sensitivity	Air Sensitive;Light Sensitive
Flash Point(°F)	392 °F
Flash Point(°C)	243 °C
Boil Point(°C)	>260℃
Melt Point(°C)	178.0to183.0℃

Safety and Hazards(GHS)

Pictogram(s)	GHS09, GHS07
Signal	Warning
Hazard Statements	H317:May cause an allergic skin reaction H400:Very toxic to aquatic life H410:Very toxic to aquatic life with long lasting effects
Precautionary Statements	P261:Avoid breathing dust/fume/gas/mist/vapors/spray. P273:Avoid release to the environment. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of water. P321:Specific treatment (see ... on this label). P501:Dispose of contents/container to ... P272:Contaminated work clothing should not be allowed out of the workplace. P333+P313:IF SKIN irritation or rash occurs: Get medical advice/attention. P362+P364:Take off contaminated clothing and wash it before reuse. P391:Collect spillage.
WGK Germany	2
RTECS	DL6475000
Reaxy-Rn	508810
Class	6.1
Merck Index	5868

FAQs and Articles

FAQ

1,3-Thiazole building blocks in natural products and synthetic materials

Categories: Technical articles

Tags:

1,3-Thiazole building blocks

Citations of This Product

1. Chunyuan Song,Zhuyuan Wang,Jing Yang,Ruohu Zhang,Yiping Cui. (2010-08-07) Preparation of 2-mercaptobenzothiazole-labeled immuno-Au aggregates for SERS-based immunoassay.. Colloids and surfaces. B, Biointerfaces, 81 ((1)): (285-288). [PMID:20688492]
2. Jianghao Zhou, Jing Guo, Govinda Ghimire, Alexander M. Mebel, Shuai Chang, Jin He. (2023) Plasmon-mediated dehydrogenation of the aromatic methyl group and benzyl radical formation. Chemical Science, 14 (47): (13951-13961). [PMID:38075667]
3. Peng Wang, Baoluo He, Xiaozhi Zhang, Shujuan Liu, Qian Ye, Feng Zhou, Weimin Liu. (2023) Size-Regulated Metal–Organic Frameworks with Mercaptobenzothiazole for Ga-Based Liquid Metal Encapsulation: A High Performance Oil-Based Additive. ACS Applied Materials & Interfaces, 15 (48): (56192–56202). [PMID:38000784]
4. Ding Ding, Xu Wenzong, Qin Zhongqiong, Cheng Zihao, Zhang Zhihui, Qiao Mengxia. (2023) Improvement of flame retardancy and thermal conductivity of SBR by piperazine pyrophosphate-modified boron nitride synergistic expandable graphite. IRANIAN POLYMER JOURNAL, (1-14). [PMID:10375507]
5. Guang-Rong Wu, Jia-Kun Xu, Li-Juan Sun, Ying-Fu Li, Shu-Qin Gao, Ying-Wu Lin. (2023) Application of engineered heme enzymes based on myoglobin with high peroxidase activity for efficient degradation of various emerging pollutants. Journal of Environmental Chemical Engineering, 11 (17): (111471). [PMID:9751059]
6. Acan Liu, Xiaodong Li, Wenxiao Zhang, Hui Yang, Xuemin Guo, Chunyan Lu, Haobo Yuan, Wei Ou-Yang, Junfeng Fang. (2023) Ag Electrode Anticorrosion in Inverted Perovskite Solar Cells. ADVANCED FUNCTIONAL MATERIALS, (2307310). [PMID:16055502]
7. Yixin Wang, Shenghua Xue, Sha Liu, Fei Xu, Shujuan Liu, Qian Ye, Feng Zhou, Weimin Liu. (2023) Polystyrene-derived porous graphite carbon nanospheres with corrosion resistance as a lubricant additive for efficient friction and wear reduction. TRIBOLOGY INTERNATIONAL, 189 (108957). [PMID:20215441]
8. Peng Wang, Baoluo He, Biwen Wang, Shujuan Liu, Qian Ye, Feng Zhou, Weimin Liu. (2023) MXene/Metal–Organic framework based composite coating with photothermal self-healing performances for antifouling application. CHEMICAL ENGINEERING JOURNAL, 474 (30): (145835). [PMID:11972023]
9. Juan Zhou, Peng Deng, Hongxing Gui, Junxiao Xu, Jianhe Liao, Aiwu Ding. (2023) Enhanced Ozone Aging Resistance of Natural Rubber with 2-Mercaptobenzothiazole as the Constant-Viscosity Agent. Journal of Chemistry, 2023 (3648596). [PMID:]
10. Meng-Zhen Zhou, Hao-Ran Wang, Xing Guo, Yan-Chan Wei, Shuangquan Liao. (2023) Synergistic effect of thermal oxygen and UV aging on natural rubber. E-POLYMERS, 23 (1): [PMID:]
11. Yu-Fei Li, Can-Jun Zou, Xing-Biao Liu, Feng Gan, Ping-Ping Fang. (2023) Highly Sensitive and Selective Detection of Pharmaceuticals on Au/MIL-101(Cr) by SERS. ANALYTICAL CHEMISTRY, 95 (20): (7933–7940). [PMID:37159411]
12. Haoran Dong, Shunyan Ning, Zengyuan Li, Sizhi Xu, Shichang Zhang, Xinpeng Wang, Youbin Wang, Lifeng Chen, Xiangbiao Yin, Toyohisa Fujita, Mohammed F. Hamza, Yuezhou Wei. (2023) Efficient separation of palladium from high-level liquid waste with novel adsorbents prepared by sulfhydryl organic ligands containing imidazole, thiazole and oxazole composited with XAD7HP. Journal of Water Process Engineering, 53 (103681). [PMID:]
13. Chen Yang, Xuefeng Hu, Yaxing Bai, Beichuan Cai, Yujie Li. (2023) Fe Single Atoms Reduced by NaBH4 Mediate g-C3N4 Electron Transfer and Effectively Remove 2-Mercaptobenzothiazole. Catalysts, 13 (3): (619). [PMID:]
14. Chen Yang, Xuefeng Hu, Yao Huang, Baiyu Liu, Junhan Yang. (2023) Pyrrole nitrogen coordinated Fe on carbon nitride mediated singlet oxygen formation for efficient degradation of 2-mercaptobenzothiazole. Journal of Environmental Chemical Engineering, 11 (109694). [PMID:]
15. Jie Wei, Zhiting Liu, Yanxing Zhang, Zongxian Yang, Zehao Sun, Yunpeng Li, Zhenxiang Cheng. (2023) Unraveling charge transfer pathways and mechanisms in CdS@CoWO4 Z-scheme heterojunction photocatalysts for high-efficiency environmental remediation. SEPARATION AND PURIFICATION TECHNOLOGY, 306 (122664). [PMID:]
16. Jinming Piao, Wei Wang, Lin Cao, Xude Qin, Tong Wang, Shougang Chen. (2022) Self-healing performance and long-term corrosive resistance of Polyvinylidene fluoride nanofiber alkyd coating. COMPOSITES COMMUNICATIONS, 36 (101404). [PMID:]
17. Selvaraj Muthusamy, Kanagaraj Rajalakshmi, Yeonggil Seo, Meng Xie, Palanisamy Kannan, Rathna Silviya Lodi, Jong-Won Song, Yuanguo Xu. (2022) Push-pull electronic effects on benzothiazole derived probes for the detection of Zn2+: Exploring the sensing strategies and its applications. DYES AND PIGMENTS, 207 (110709). [PMID:]
18. Lingwei Ma, Jinke Wang, Yajie Wang, Xin Guo, Shanghao Wu, Dongmei Fu, Dawei Zhang. (2022) Enhanced active corrosion protection coatings for aluminum alloys with two corrosion inhibitors co-incorporated in nanocontainers. CORROSION SCIENCE, 208 (110663). [PMID:]
19. Xiaojing Li, Zhuozhuo Wang, Xiaojia Huang. (2022) Preparation of monolith-based adsorbent containing abundant functional groups for field entrapment of nitrogen and sulfur containing aromatic compounds in environmental aqueous samples with portable multichannel in-tip microextraction device. JOURNAL OF CHROMATOGRAPHY A, 1676 (463260). [PMID:35772365]
20. Peng Wang, Baoluo He, Yixuan Du, Biwen Wang, Jingde Gao, Shujuan Liu, Qian Ye, Feng Zhou. (2022) Functionalized Ti3C2Tx-based nanocomposite coatings for anticorrosion and antifouling applications. CHEMICAL ENGINEERING JOURNAL, 448 (137668). [PMID:]
21. Yan-Chan Wei, Wen-Yi Xie, Meng-Fan He, Ding Zhu, Shuang Liu, Ling Zhang, Shuangquan Liao. (2022) The role of non-rubber components acting as endogenous antioxidants on thermal-oxidative aging behavior of natural rubber. POLYMER TESTING, 111 (107614). [PMID:]
22. Xiu-Xiu Liu, Meng-Fan He, Ming-Chao Luo, Yan-Chan Wei, Shuangquan Liao. (2022) The role of natural rubber endogenous proteins in promoting the formation of vulcanization networks. E-POLYMERS, 22 (1): (445-453). [PMID:]
23. Xiaoyu Zhao, Haoqiang Gao, Yongdan Hou, Yanfei Wang, Liang Zhu. (2022) In-situ analysis of self-assembled monolayer induced polymorphism in controlled crystallization of carbamazepine using quartz crystal microbalance technique. APPLIED SURFACE SCIENCE, 593 (153445). [PMID:]
24. Huiqin Liu, Junyi Zeng, Liping Song, Lingli Zhang, Zihai Chen, Jianhua Li, Zhidong Xiao, Fengmei Su, Youju Huang. (2022) Etched-spiky Au@Ag plasmonic-superstructure monolayer films for triple amplification of surface-enhanced Raman scattering signals. Nanoscale Horizons, 7 (5): (554-561). [PMID:35347336]
25. Yan-Chan Wei, Ding Zhu, Wen-Yi Xie, Jie-Hui Xia, Meng-Fan He, Shuangquan Liao. (2022) In-situ observation of spatial organization of natural rubber latex particles and exploring the relationship between particle size and mechanical properties of natural rubber. INDUSTRIAL CROPS AND PRODUCTS, 180 (114737). [PMID:]
26. Yanjun Yang, Chunyuan Song, Jingjing Zhang, Jie Chao, Hoang Mai Luong, Yiping Zhao, Lianhui Wang. (2022) DNA self-assembled Au nanoparticle clusters on silver nanorod arrays for high-sensitive and multiplex detection of cancer-related biomarkers. Nanoscale, 14 (12): (4538-4547). [PMID:35257132]
27. Demian I Njoku,Miaomiao Cui,Haigang Xiao,Baihui Shang,Ying Li. (2017-11-17) Understanding the anticorrosive protective mechanisms of modified epoxy coatings with improved barrier, active and self-healing functionalities: EIS and spectroscopic techniques.. Scientific reports, 7 ((1)): (15597-15597). [PMID:29142312]

References

1. Albert Isidro-Llobet,Xavier Just-Baringo,Ariel Ewenson,Mercedes Alvarez,Fernando Albericio. (2007-03-27) Fmoc-2-mercaptobenzothiazole, for the introduction of the Fmoc moiety free of side-reactions.. Biopolymers, 88 ((5)): (733-737). [PMID:17385207]
2. H Parham,B Aibaghi,J Ghasemi. (2007-07-27) Simultaneous square wave voltammetric determination of 2-mercaptobenzothiazole and 2-mercaptobenzoxazole by partial least squares method in water samples.. Journal of hazardous materials, 151 ((2-3)): (636-641). [PMID:17651895]
3. Xugang Wang,Chengshuai Liu,Xiaomin Li,Fangbai Li,Shungui Zhou. (2007-10-05) Photodegradation of 2-mercaptobenzothiazole in the gamma-Fe(2)O(3)/oxalate suspension under UVA light irradiation.. Journal of hazardous materials, 153 ((1-2)): (426-433). [PMID:17913355]
4. Itai Chipinda,Xing-Dong Zhang,Reuben H Simoyi,Paul D Siegel. (2008-06-24) Mercaptobenzothiazole allergenicity-role of the thiol group.. Cutaneous and ocular toxicology, 27 ((2)): (103-116). [PMID:18568896]
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16. Leila El-Bassi,Hironori Iwasaki,Hirosuke Oku,Naoya Shinzato,Toru Matsui. (2010-08-10) Biotransformation of benzothiazole derivatives by the Pseudomonas putida strain HKT554.. Chemosphere, 81 ((1)): (109-113). [PMID:20692014]
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18. Mohammad Mousa Al-Ansari,A Steevensz,K E Taylor,J K Bewtra,N Biswas. (2010-12-15) Soybean peroxidase-catalyzed removal of an aromatic thiol, 2-mercaptobenzothiazole, from water.. Water environment research : a research publication of the Water Environment Federation, 82 ((11)): (2285-2289). [PMID:21141391]
19. Fei Wang,Shangjun Cai,Zhipeng Wang,Chanjuan Xi. (2011-05-20) Synthesis of 2-mercaptobenzothiazoles via DBU-promoted tandem reaction of o-haloanilines and carbon disulfide.. Organic letters, 13 ((12)): (3202-3205). [PMID:21591631]
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22. Michael Mah,Wei Chuan Tan,Sim Heng Ong,Yiong Huak Chan,Kelvin Foong. (2013-06-19) Three-dimensional analysis of the change in the curvature of the smiling line following orthodontic treatment in incisor class II division 1 malocclusion.. European journal of orthodontics, 36 ((6)): (657-664). [PMID:23771899]
23. Hooshang Parham,Farzaneh Khoshnam. (2013-08-21) Solid phase extraction-preconcentration and high performance liquid chromatographic determination of 2-mercapto-(benzothiazole, benzoxazole and benzimidazole) using copper oxide nanoparticles.. Talanta, 114 (90-94). [PMID:23953446]
24. Attilio Naccarato,Emanuela Gionfriddo,Giovanni Sindona,Antonio Tagarelli. (2014-03-19) Simultaneous determination of benzothiazoles, benzotriazoles and benzosulfonamides by solid phase microextraction-gas chromatography-triple quadrupole mass spectrometry in environmental aqueous matrices and human urine.. Journal of chromatography. A, 1338 (164-173). [PMID:24636758]
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