Basic Description

Synonyms	EINECS 233-108-3 \| MPCRDALPQLDDFX-UHFFFAOYSA-L \| Perchlorate de magnesium [French] \| FT-0628102 \| MAGNESIUM PERCHLORATE [HSDB] \| Anhydrous magnesium perchlorate \| Perchlorate de magnesium \| HSDB 661 \| 7N77Z541YF \| Magnesium Perchlorate, Anhydrous \| Magnes
Specifications & Purity	puriss., ≥99%(calc. based on dry substance,KT), Powder
Storage Temp	Store at 2-8°C
Shipped In	Wet ice
Grade	puriss.
Product Description	General Description Magnesium perchlorate (Mg(ClO 4 ) 2 ) is widely used as drying agent for gases. It can remove water from gases (with no organic contaminants) at the rate of 0.001mgwater/l. Application filler for drying tubes (especially for elemental analysis) Magnesium perchlorate (Mg(ClO 4 ) 2 ) may be employed as a catalyst in the following studies: Preparation of a-aminophosphonates. Enantioselective Diels-Alder reaction between cyclopentadiene and 3-acryloyl-1,3-oxazolin-2-one. Preparation of imines and phenylhydrazones. Protection of alcohols in the form of t -butyl ethers.

Names and Identifiers

IUPAC Name	magnesium;diperchlorate
INCHI	InChI=1S/2ClHO4.Mg/c22-1(3,4)5;/h2(H,2,3,4,5);/q;;+2/p-2
InChi Key	MPCRDALPQLDDFX-UHFFFAOYSA-L
Canonical SMILES	[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[Mg+2]
Isomeric SMILES	[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[Mg+2]
WGK Germany	1
RTECS	SC8925000
PubChem CID	24840
UN Number	1475
Packing Group	II
Molecular Weight	223.21

Certificates

Certificate of Analysis(COA)

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Chemical and Physical Properties

Melt Point(°C)	251°C

Safety and Hazards(GHS)

Pictogram(s)	GHS07, GHS03
Signal	Danger
Hazard Statements	H315:Causes skin irritation H319:Causes serious eye irritation H335:May cause respiratory irritation H302:Harmful if swallowed H272:May intensify fire; oxidizer H271:May cause fire or explosion; strong Oxidizer
Precautionary Statements	P261:Avoid breathing dust/fume/gas/mist/vapors/spray. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing. P280:Wear protective gloves/protective clothing/eye protection/face protection. P370+P378:In case of fire: Use ... to extinguish. P210:Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking. P302+P352:IF ON SKIN: wash with plenty of water. P321:Specific treatment (see ... on this label). P405:Store locked up. P501:Dispose of contents/container to ... P264:Wash hands [and …] thoroughly after handling. P220:Keep away from clothing and other combustible materials. P271:Use only outdoors or in a well-ventilated area. P270:Do not eat, drink or smoke when using this product. P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing. P403+P233:Store in a well-ventilated place. Keep container tightly closed. P362+P364:Take off contaminated clothing and wash it before reuse. P371+P380+P375:In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion. P283:Wear fire resistant or flame retardant clothing. P420:Store separately. P330:Rinse mouth. P306+P360:IF ON CLOTHING: Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before removing clothes. P264+P265:Wash hands [and …] thoroughly after handling. Do not touch eyes. P301+P317:IF SWALLOWED: Get medical help. P337+P317:If eye irritation persists: Get medical help. P332+P317:If skin irritation occurs: Get medical help. P319:Get medical help if you feel unwell.
WGK Germany	1
RTECS	SC8925000
Class	5.1

Citations of This Product

How to Cite Aladdin Scientific Products?

1. Jiajun Xu, Meifen Huang, Liang Jiao, Haijun Pang, Xia Wang, Rui Duan, Qiong Wu. (2023) Supramolecular Dimer as High-Performance pH Probe: Study on the Fluorescence Properties of Halogenated Ligands in Rigid Schiff Base Complex. INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES, 24 (11): (9480). [PMID:37298432] [10.3390/ijms24119480]
2. Qi Liu, Yatong Liu, Zhiyong Xing, Yuntong Huang, Li Ling, Xinglin Mo. (2023) A novel dual-function probe for fluorescent turn-on recognition and differentiation of Al3+ and Ga3+ and its application. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 287 (122076). [PMID:36368269] [10.1016/j.saa.2022.122076]
3. Huie Jiang, Lijuan Chen, Zhijian Li, Junwei Li, Huaiqin Ma, Lulu Ning, Nihao Li, Xinhua Liu. (2022) A facile AIE fluorescent probe with large Stokes shift for the detection of Cd2+ in real water samples and living cells. JOURNAL OF LUMINESCENCE, 243 (118672). [PMID:] [10.1016/j.jlumin.2021.118672]
4. Yingxue Li, Jingjie Zhou, Yong Zhang, Huibin Liang, Jinyuan Sun, Yuqi Liu, Gerardino D’Errico, Yongqiang Sun, Martino Di Serio. (2021) Synthesis and Properties of Primary Alcohol Ethoxylates Using Different Catalytic Systems. ACS Omega, 6 (44): (29774–29780). [PMID:34778650] [10.1021/acsomega.1c04232]
5. Yaqi Li, Pengjian Zuo, Ruinan Li, Hua Huo, Yulin Ma, Chunyu Du, YunZhi Gao, Geping Yin, Robert S. Weatherup. (2021) Formation of an Artificial Mg2+-Permeable Interphase on Mg Anodes Compatible with Ether and Carbonate Electrolytes. ACS Applied Materials & Interfaces, 13 (21): (24565–24574). [PMID:34009930] [10.1021/acsami.0c22520]
6. Jingling Ma, Pengfei Hu, Xingliang Jia, Chenfei Zhang, Guangxin Wang. (2021) Organic/inorganic double solutions for magnesium–air batteries. RSC Advances, 11 (13): (7502-7510). [PMID:35423265] [10.1039/D0RA10528G]
7. Ma Jingling, Jia Xingliang, Ma Mingsheng, Zhang Chenfei, Ren Fengzhang, Wang Guangxin. (2021) Mg(ClO4)2-N,N-Dimethylformamide (Acetonitrile)/NaCl Double Electrolytes for Magnesium–Air Batteries. JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE, 30 (2): (1567-1576). [PMID:] [10.1007/s11665-020-05447-9]
8. Ting Yin, Sheng Zhang, Mengxuan Li, Carl Redshaw, Xin-Long Ni. (2019) Macrocycle encapsulation triggered supramolecular pKa shift: A fluorescence indicator for detecting octreotide in aqueous solution. SENSORS AND ACTUATORS B-CHEMICAL, 281 (568). [PMID:] [10.1016/j.snb.2018.10.136]
9. Pengfei Yang, Guangming Zhu, Xuelin Shen, Xiaogang Yan, Jing Nie. (2016) Poly(ε-caprolactone)-based shape memory polymers crosslinked by polyhedral oligomeric silsesquioxane. RSC Advances, 6 (93): (90212-90219). [PMID:] [10.1039/C6RA20431G]

References

1. V R Nikolaevskaia,L D Volkova. (1990-05-01) [The experimental effect of growth stimulants on protein assimilation].. Voprosy pitaniia, ((3)): (58-60). [PMID:2169143]
2. T Theophanides. (1996-12-01) Biological implications of magnesium salts at the molecular level.. Magnesium research, 9 ((4)): (259-262). [PMID:9247873]
3. J D Anastassopoulou. (1990-03-01) Magnesium perchlorate and cis-platinum as radiosensitizers in in vitro radiolysis of nucleotides.. Magnesium research, 3 ((1)): (19-21). [PMID:2168728]
4. Giuseppe Bartoli,Marcella Bosco,Manuela Locatelli,Enrico Marcantoni,Paolo Melchiorre,Letizia Sambri. (2005-01-28) Unusual and unexpected reactivity of t-butyl dicarbonate (Boc2O) with alcohols in the presence of magnesium perchlorate. A new and general route to t-butyl ethers.. Organic letters, 7 ((3)): (427-430). [PMID:15673256]
5. Srikant Bhagat,Asit K Chakraborti. (2007-01-27) An extremely efficient three-component reaction of aldehydes/ketones, amines, and phosphites (Kabachnik-Fields reaction) for the synthesis of alpha-aminophosphonates catalyzed by magnesium perchlorate.. The Journal of organic chemistry, 72 ((4)): (1263-1270). [PMID:17253748]
6. Roland Messer,Cyril A Fuhrer,Robert Häner. (2007-12-11) Transformation of D-(-)-ribose into a natural product-like scaffold via a Lewis acid catalyzed intramolecular hetero-Diels-Alder reaction.. Nucleosides, nucleotides & nucleic acids, 26 ((6-7)): (701-704). [PMID:18066883]
7. F Javier Céspedes-Guirao,Kei Ohkubo,Shunichi Fukuzumi,Angela Sastre-Santos,Fernando Fernández-Lázaro. (2009-07-29) Synthesis and photoinduced electron transfer of phthalocyanine-perylenebisimide pentameric arrays.. The Journal of organic chemistry, 74 ((16)): (5871-5880). [PMID:19634885]
8. Sungnam Park,Minbiao Ji,Kelly J Gaffney. (2010-04-30) Ligand exchange dynamics in aqueous solution studied with 2DIR spectroscopy.. The journal of physical chemistry. B, 114 ((19)): (6693-6702). [PMID:20426448]
9. Yutaro Kohno,Miyabi Fujii,Chihiro Matsuoka,Haruka Hashimoto,Aya Ouchi,Shin-ichi Nagaoka,Kazuo Mukai. (2011-07-12) Notable effects of the metal salts on the formation and decay reactions of α-tocopheroxyl radical in acetonitrile solution. The complex formation between α-tocopheroxyl and metal cations.. The journal of physical chemistry. B, 115 ((32)): (9880-9888). [PMID:21739987]
10. Andreas T Messmer,Sabrina Steinwand,Katharina M Lippert,Peter R Schreiner,Jens Bredenbeck. (2012-12-04) Ultrafast two-dimensional infrared spectroscopy resolves the conformational change of an Evans auxiliary induced by Mg(ClO4)2.. The Journal of organic chemistry, 77 ((24)): (11091-11095). [PMID:23198854]
11. Jeffrey A Therrien,Michael O Wolf,Brian O Patrick. (2014-10-23) Electrocatalytic reduction of CO2 with palladium bis-N-heterocyclic carbene pincer complexes.. Inorganic chemistry, 53 ((24)): (12962-12972). [PMID:25337973]
12. C Pac,I Miyamoto,Y Masaki,S Furusho,S Yanagida,T Ohno,A Yoshimura. (1990-11-01) Chloranil-photosensitized monomerization of dimethylthymine cyclobutane dimers and effect of magnesium perchlorate.. Photochemistry and photobiology, 52 ((5)): (973-979). [PMID:1962858]
13. K Miyake,Y Masaki,I Miyamoto,S Yanagida,T Ohno,A Yoshimura,C Pac. (1993-11-01) Flavin-photosensitized monomerization of dimethylthymine cyclobutane dimer in the presence of magnesium perchlorate.. Photochemistry and photobiology, 58 ((5)): (631-636). [PMID:8284317]
14. Jiajun Xu, Meifen Huang, Liang Jiao, Haijun Pang, Xia Wang, Rui Duan, Qiong Wu. (2023) Supramolecular Dimer as High-Performance pH Probe: Study on the Fluorescence Properties of Halogenated Ligands in Rigid Schiff Base Complex. INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES, 24 (11): (9480). [PMID:37298432] [10.3390/ijms24119480]
15. Qi Liu, Yatong Liu, Zhiyong Xing, Yuntong Huang, Li Ling, Xinglin Mo. (2023) A novel dual-function probe for fluorescent turn-on recognition and differentiation of Al3+ and Ga3+ and its application. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 287 (122076). [PMID:36368269] [10.1016/j.saa.2022.122076]
16. Huie Jiang, Lijuan Chen, Zhijian Li, Junwei Li, Huaiqin Ma, Lulu Ning, Nihao Li, Xinhua Liu. (2022) A facile AIE fluorescent probe with large Stokes shift for the detection of Cd2+ in real water samples and living cells. JOURNAL OF LUMINESCENCE, 243 (118672). [PMID:] [10.1016/j.jlumin.2021.118672]
17. Yingxue Li, Jingjie Zhou, Yong Zhang, Huibin Liang, Jinyuan Sun, Yuqi Liu, Gerardino D’Errico, Yongqiang Sun, Martino Di Serio. (2021) Synthesis and Properties of Primary Alcohol Ethoxylates Using Different Catalytic Systems. ACS Omega, 6 (44): (29774–29780). [PMID:34778650] [10.1021/acsomega.1c04232]
18. Yaqi Li, Pengjian Zuo, Ruinan Li, Hua Huo, Yulin Ma, Chunyu Du, YunZhi Gao, Geping Yin, Robert S. Weatherup. (2021) Formation of an Artificial Mg2+-Permeable Interphase on Mg Anodes Compatible with Ether and Carbonate Electrolytes. ACS Applied Materials & Interfaces, 13 (21): (24565–24574). [PMID:34009930] [10.1021/acsami.0c22520]
19. Jingling Ma, Pengfei Hu, Xingliang Jia, Chenfei Zhang, Guangxin Wang. (2021) Organic/inorganic double solutions for magnesium–air batteries. RSC Advances, 11 (13): (7502-7510). [PMID:35423265] [10.1039/D0RA10528G]
20. Ma Jingling, Jia Xingliang, Ma Mingsheng, Zhang Chenfei, Ren Fengzhang, Wang Guangxin. (2021) Mg(ClO4)2-N,N-Dimethylformamide (Acetonitrile)/NaCl Double Electrolytes for Magnesium–Air Batteries. JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE, 30 (2): (1567-1576). [PMID:] [10.1007/s11665-020-05447-9]
21. Ting Yin, Sheng Zhang, Mengxuan Li, Carl Redshaw, Xin-Long Ni. (2019) Macrocycle encapsulation triggered supramolecular pKa shift: A fluorescence indicator for detecting octreotide in aqueous solution. SENSORS AND ACTUATORS B-CHEMICAL, 281 (568). [PMID:] [10.1016/j.snb.2018.10.136]
22. Pengfei Yang, Guangming Zhu, Xuelin Shen, Xiaogang Yan, Jing Nie. (2016) Poly(ε-caprolactone)-based shape memory polymers crosslinked by polyhedral oligomeric silsesquioxane. RSC Advances, 6 (93): (90212-90219). [PMID:] [10.1039/C6RA20431G]

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Magnesium perchlorate - puriss.,powder, ≥99.0% (calc. based on dry substance, KT), high purity , CAS No.10034-81-8

Basic Description

Names and Identifiers

Certificates

Certificate of Analysis(COA)

Chemical and Physical Properties

Safety and Hazards(GHS)

Related Documents

Citations of This Product

References

Solution Calculators

Molarity Calculator

Dilution Calculator

Reconstitution Calculator

SKU	Size	Availability	Price	Qty
M431154-100g	100g	Available within 8-12 weeks(?) Production requires sourcing of materials. We appreciate your patience and understanding.	$360.90
M431154-500g	500g	Available within 8-12 weeks(?) Production requires sourcing of materials. We appreciate your patience and understanding.	$652.90