Grouped product items

SKU

Size

Availability

Price

Qty

M106182-25g

25g

In stock

$42.90

M106182-100g

100g

Available within 4-8 weeks(?)

$129.90

M106182-250g

250g

Available within 4-8 weeks(?)

$259.90

M106182-500g

500g

Available within 8-12 weeks(?)

$418.90

Basic Description

Synonyms	14284-89-0\|Manganese(III)acetylacetonate\|Manganese(3+);(Z)-4-oxopent-2-en-2-olate\|(Z)-4-hydroxypent-3-en-2-one;manganese\|tris(((Z)-4-oxopent-2-en-2-yl)oxy)manganese\|MFCD00000023\|Mn(acac)3\|AKOS025311027\|H10683\|Manganese(III) acetylacetonate, technical grad
Specifications & Purity	97%
Shipped In	Normal
Product Description	Oxidant used to oxidize phenols, β-dicarbonyl compounds, and thiols.

Names and Identifiers

Pubchem Sid	488197096
Pubchem Sid Url	https://pubchem.ncbi.nlm.nih.gov/substance/488197096
IUPAC Name	(Z)-4-hydroxypent-3-en-2-one;manganese
INCHI	InChI=1S/3C5H8O2.Mn/c31-4(6)3-5(2)7;/h33,6H,1-2H3;/b3*4-3-;
InChi Key	RDMHXWZYVFGYSF-LNTINUHCSA-N
Canonical SMILES	CC(=CC(=O)C)O.CC(=CC(=O)C)O.CC(=CC(=O)C)O.[Mn]
Isomeric SMILES	C/C(=C/C(=O)C)/O.C/C(=C/C(=O)C)/O.C/C(=C/C(=O)C)/O.[Mn]
WGK Germany	3
PubChem CID	11046384
Molecular Weight	352.26
Beilstein	1783

Certificates

Certificate of Analysis(COA)

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13 results found

Lot Number	Certificate Type	Date	Item
H2408599	Certificate of Analysis	Jul 29, 2024	M106182
H2408600	Certificate of Analysis	Jul 29, 2024	M106182
H2408601	Certificate of Analysis	Jul 29, 2024	M106182
H2408602	Certificate of Analysis	Jul 29, 2024	M106182
H2408603	Certificate of Analysis	Jul 29, 2024	M106182
D2412301	Certificate of Analysis	Mar 15, 2024	M106182
A2305103	Certificate of Analysis	Jun 01, 2022	M106182
A2426050	Certificate of Analysis	Jun 01, 2022	M106182
G2220545	Certificate of Analysis	Jun 01, 2022	M106182
G2220553	Certificate of Analysis	Jun 01, 2022	M106182
G2220554	Certificate of Analysis	Jun 01, 2022	M106182
G2220556	Certificate of Analysis	Jun 01, 2022	M106182
E23291159	Certificate of Analysis	Sep 19, 2021	M106182

Chemical and Physical Properties

Solubility	Solubility：Methanol
Melt Point(°C)	159-161°C

Safety and Hazards(GHS)

Pictogram(s)	GHS07
Signal	Warning
Hazard Statements	H315:Causes skin irritation H319:Causes serious eye irritation H335:May cause respiratory irritation H302:Harmful if swallowed
Precautionary Statements	P261:Avoid breathing dust/fume/gas/mist/vapors/spray. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of water. P321:Specific treatment (see ... on this label). P405:Store locked up. P501:Dispose of contents/container to ... P264:Wash hands [and …] thoroughly after handling. P271:Use only outdoors or in a well-ventilated area. P270:Do not eat, drink or smoke when using this product. P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing. P403+P233:Store in a well-ventilated place. Keep container tightly closed. P362+P364:Take off contaminated clothing and wash it before reuse. P330:Rinse mouth. P264+P265:Wash hands [and …] thoroughly after handling. Do not touch eyes. P301+P317:IF SWALLOWED: Get medical help. P337+P317:If eye irritation persists: Get medical help. P332+P317:If skin irritation occurs: Get medical help. P319:Get medical help if you feel unwell.
WGK Germany	3

References

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2. Chih-Chia Huang,Wileen Huang,Chia-Hao Su,Chieh-Ning Feng,Wen-Shuo Kuo,Chen-Sheng Yeh. (2009-06-09) A general approach to silicate nanoshells: gadolinium silicate and gadolinium silicate:europium nanoshells for dual-modality optical and MR imaging.. Chemical communications (Cambridge, England), ((23)(23)): (3360-3362). [PMID:19503870]
3. S S Arandjelovic,K S Bjelogrlic,N N Malesevic,Lj Z Tesic,S S Radulovic. (2009-08-04) Antitumor activity of Ru(III) complexes carrying beta-diketonato ligands in vitro and in vivo.. Journal of B.U.ON. : official journal of the Balkan Union of Oncology, 14 ((2)): (271-279). [PMID:19650178]
4. Nathan A Mathew,Lena A Yurs,Stephen B Block,Andrei V Pakoulev,Kathryn M Kornau,Edwin L Sibert,John C Wright. (2009-12-03) Fully and partially coherent pathways in multiply enhanced odd-order wave-mixing spectroscopy.. The journal of physical chemistry. A, 114 ((2)): (817-832). [PMID:19950915]
5. Sebastian Reineke,Thomas C Rosenow,Björn Lüssem,Karl Leo. (2010-06-10) Improved high-brightness efficiency of phosphorescent organic LEDs comprising emitter molecules with small permanent dipole moments.. Advanced materials (Deerfield Beach, Fla.), 22 ((29)): (3189-3193). [PMID:20533421]
6. Nan Tian,Yaroslav V Aulin,Daniel Lenkeit,Simon Pelz,Oleksandr V Mikhnenko,Paul W M Blom,Maria Antonietta Loi,Elisabeth Holder. (2010-08-19) Cyclometalated red iridium(III) complexes containing carbazolyl-acetylacetonate ligands: efficiency enhancement in polymer LED devices.. Dalton transactions (Cambridge, England : 2003), 39 ((37)): (8613-8615). [PMID:20717556]
7. Gong-Jun Chen,Xin Qiao,Jin-Lei Tian,Jing-Yuan Xu,Wen Gu,Xin Liu,Shi-Ping Yan. (2010-10-06) Synthesis, DNA binding, photo-induced DNA cleavage and cytotoxicity studies of europium(III) complexes.. Dalton transactions (Cambridge, England : 2003), 39 ((44)): (10637-10643). [PMID:20922220]
8. Mukul Pradhan,Mrinmoyee Basu,Sougata Sarkar,Arun Kumar Sinha,Tarasankar Pal. (2010-10-30) Solvent effect on the optical property of uranyl acetylacetonate monohydrate.. Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 78 ((1)): (205-210). [PMID:21030297]
9. Ik-Soo Shin,Yeung-Tae Kang,Jin-Kyu Lee,Hasuck Kim,Tae Hyun Kim,Jong Seung Kim. (2011-03-25) Evaluation of electrogenerated chemiluminescence from a neutral Ir(III) complex for quantitative analysis in flowing streams.. The Analyst, 136 ((10)): (2151-2155). [PMID:21431210]
10. Zhonglan Gao,Chengyue Zhang,Siwang Yu,Xiaoda Yang,Kui Wang. (2011-04-23) Vanadyl bisacetylacetonate protects β cells from palmitate-induced cell death through the unfolded protein response pathway.. Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry, 16 ((5)): (789-798). [PMID:21512771]
11. Katja Höflich,Ren Bin Yang,Andreas Berger,Gerd Leuchs,Silke Christiansen. (2011-05-04) The direct writing of plasmonic gold nanostructures by electron-beam-induced deposition.. Advanced materials (Deerfield Beach, Fla.), 23 ((22-23)): (2657-2661). [PMID:21538585]
12. Gui-Ge Hou,Yue Liu,Qi-Kui Liu,Jian-Ping Ma,Yu-Bin Dong. (2011-08-27) NbO lattice MOFs based on octahedral M(II) and ditopic pyridyl substituted diketonate ligands: structure, encapsulation and guest-driven luminescent property.. Chemical communications (Cambridge, England), 47 ((38)): (10731-10733). [PMID:21869961]
13. Abu T Khan,Shahzad Ali,R Sidick Basha,Md Musawwer Khan,Mohan Lal. (2011-10-11) VO(acac)(2)/H(2)O(2)/NaI: a mild and efficient combination for the cleavage of dithioacetal derivatives of sugars.. Carbohydrate research, 346 ((16)): (2629-2632). [PMID:21982463]
14. Hamid Golchoubian,Golasa Moayyedi,Hakimeh Fazilati. (2011-10-18) Spectroscopic studies on Solvatochromism of mixed-chelate copper(II) complexes using MLR technique.. Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 85 ((1)): (25-30). [PMID:22000637]
15. Xue-Lan Mei,Yue Ma,Li-Cun Li,Dai-Zheng Liao. (2011-11-02) Ligand field-tuned single-molecule magnet behaviour of 2p-4f complexes.. Dalton transactions (Cambridge, England : 2003), 41 ((2)): (505-511). [PMID:22041888]
16. Wouter Bult, Hendrik de Leeuw, Olav M Steinebach, Martijn J van der Bom, Hubert Th Wolterbeek, Ron M A Heeren, Chris J G Bakker, Alfred D van Het Schip, Wim E Hennink, J Frank W Nijsen,. (2011-11-10) Radioactive holmium acetylacetonate microspheres for interstitial microbrachytherapy: an in vitro and in vivo stability study.. Pharmaceutical research, 29 ((3)): ( 827-836 ). [PMID:22068276]
17. Yanfang Li,Yang Liu,Ming Zhou. (2012-02-24) Acid induced acetylacetonato replacement in biscyclometalated iridium(III) complexes.. Dalton transactions (Cambridge, England : 2003), 41 ((13)): (3807-3816). [PMID:22358149]
18. Kazuharu Sugawara,Asako Yugami,Toshihiko Kadoya. (2012-03-28) Voltammetric sensing of phosphoproteins using a gallium(III) acetylacetonate-modified carbon paste electrode.. Analytical sciences : the international journal of the Japan Society for Analytical Chemistry, 28 ((3)): (251-255). [PMID:22451365]
19. Hiroya Nakata,Dmitri G Fedorov,Takeshi Nagata,Satoshi Yokojima,Koji Ogata,Kazuo Kitaura,Shinichiro Nakamura. (2012-08-03) Unrestricted Hartree-Fock based on the fragment molecular orbital method: energy and its analytic gradient.. The Journal of chemical physics, 137 ((4)): (044110-044110). [PMID:22852600]
20. Wouter Bult,Maarten A D Vente,Eva Vandermeulen,Ingrid Gielen,Peter R Seevinck,Jimmy Saunders,Alfred D van Het Schip,Chris J G Bakker,Gerard C Krijger,Kathelijne Peremans,Johannes F W Nijsen. (2012-09-25) Microbrachytherapy using holmium-166 acetylacetonate microspheres: a pilot study in a spontaneous cancer animal model.. Brachytherapy, 12 ((2)): (171-177). [PMID:22999975]
21. Anthony J Di Pasqua,Hong Yuan,Younjee Chung,Jin-Ki Kim,James E Huckle,Chenxi Li,Matthew Sadgrove,Thanh Huyen Tran,Michael Jay,Xiuling Lu. (2012-10-27) Neutron-activatable holmium-containing mesoporous silica nanoparticles as a potential radionuclide therapeutic agent for ovarian cancer.. Journal of nuclear medicine : official publication, Society of Nuclear Medicine, 54 ((1)): (111-116). [PMID:23100452]
22. Zofia Kowalewska,Bernhard Welz,Ivan N B Castilho,Eduardo Carasek. (2012-12-04) Effect of magnesium acetylacetonate on the signal of organic forms of vanadium in graphite furnace atomic absorption spectrometry.. Talanta, 103 (66-74). [PMID:23200359]
23. Wouter Bult,Stephanie G C Kroeze,Mattijs Elschot,Peter R Seevinck,Freek J Beekman,Hugo W A M de Jong,Donald R A Uges,Jos G W Kosterink,Peter R Luijten,Wim E Hennink,Alfred D van het Schip,J L H Ruud Bosch,J Frank W Nijsen,Judith J M Jans. (2013-01-16) Intratumoral administration of holmium-166 acetylacetonate microspheres: antitumor efficacy and feasibility of multimodality imaging in renal cancer.. PloS one, 8 ((1)): (e52178-e52178). [PMID:23320070]
24. Yi Wang,Jie Hu,Yuepiao Cai,Shanmei Xu,Bixia Weng,Kesong Peng,Xiaoyan Wei,Tao Wei,Huiping Zhou,Xiaokun Li,Guang Liang. (2013-11-28) An oxygen-chelate complex, palladium bis-acetylacetonate, induces apoptosis in H460 cells via endoplasmic reticulum stress pathway rather than interacting with DNA.. Journal of medicinal chemistry, 56 ((23)): (9601-9611). [PMID:24274598]

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Manganese acetylacetonate - 97%, high purity , CAS No.14284-89-0