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Mattson Boronate Urea Pinacol Ester , CAS No.1538637-10-3

Item Number
M486738
Grouped product items
SKUSizeAvailabilityPrice Qty
M486738-250mg
250mg
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$173.90

Basic Description

Storage TempStore at 2-8°C
Shipped InWet ice
Product Description

Description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency.Click herefor more information.1-(3,5-bis(trifluoromethyl)phenyl)-3-(2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)urea is a user-friendly, bench stable white solid. When compared to conventional ureas, this urea is moderately acidic (pKa(DMSO) = 9.5) and benefits from improved catalytic abilities and stability in select reactions.

Names and Identifiers

INCHI 1S/C21H21BF6N2O3/c1-18(2)19(3,4)33-22(32-18)15-7-5-6-8-16(15)30-17(31)29-14-10-12(20(23,24)25)9-13(11-14)21(26,27)28/h5-11H,1-4H3,(H2,29,30,31)
InChi Key OJFYKTGJRXTBRH-UHFFFAOYSA-N
Canonical SMILES CC(O1)(C)C(C)(C)OB1C2=CC=CC=C2NC(NC3=CC(C(F)(F)F)=CC(C(F)(F)F)=C3)=O
Molecular Weight 474.2

Certificates

Certificate of Analysis(COA)

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Chemical and Physical Properties

Flash Point(°F)Not applicable
Flash Point(°C)Not applicable
Melt Point(°C)230.39℃

Safety and Hazards(GHS)

RIDADR NONH for all modes of transport

Related Documents

References

1. Sonia S So,Julie A Burkett,Anita E Mattson.  (2011-01-14)  Internal Lewis acid assisted hydrogen bond donor catalysis..  Organic letters,  13  ((4)): (716-719).  [PMID:21226464]
2. David M Nickerson,Veronica V Angeles,Tyler J Auvil,Sonia S So,Anita E Mattson.  (2012-12-01)  Internal Lewis acid assisted ureas: tunable hydrogen bond donor catalysts..  Chemical communications (Cambridge, England),  49  ((39)): (4289-4291).  [PMID:23198283]
3. Andrea M Hardman, Sonia S So, Anita E Mattson,.  (2013-08-03)  Urea-catalyzed construction of oxazinanes..  Organic & biomolecular chemistry,  11  ((35)): ( 5793-5797 ).  [PMID:23907178]
4. Tyler J Auvil,Sonia S So,Anita E Mattson.  (2013-09-17)  Arylation of diazoesters by a transient N-H insertion organocascade..  Angewandte Chemie (International ed. in English),  52  ((43)): (11317-11320).  [PMID:24038873]
5. Sonia S So,Tyler J Auvil,Victoria J Garza,Anita E Mattson.  (2012-01-03)  Boronate urea activation of nitrocyclopropane carboxylates..  Organic letters,  14  ((2)): (444-447).  [PMID:22208166]
6. Sonia S So,Shameema Oottikkal,Jovica D Badjić,Christopher M Hadad,Anita E Mattson.  (2014-05-07)  Urea-catalyzed N-H insertion-arylation reactions of nitrodiazoesters..  The Journal of organic chemistry,  79  ((11)): (4832-4842).  [PMID:24797352]

Solution Calculators