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Methanesulfonato[2-(di-t-butylphosphino)-2''-(N,N-dimethylamino)-1,1''-biphenyl](2''-amino-1,1''-biphenyl-2-yl)palladium(II) dichloromethane adduct - 98%, high purity , CAS No.1445085-92-6

  • ≥98%
Item Number
M282938
Grouped product items
SKUSizeAvailabilityPrice Qty
M282938-100mg
100mg
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$36.90
M282938-250mg
250mg
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$69.90
M282938-1g
1g
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$208.90
M282938-5g
5g
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$832.90

Catalysts & Chiral Catalysts

Basic Description

Synonymst-BuDavePhos G3 Palladacycle, t-BuDavePhos Palladacycle;tBuDavePhos Pd G3
Specifications & Purity98%
Legal InformationPatents: PCT/US2013/030779, US Serial No. 13/799620
Storage TempStore at 2-8°C,Protected from light,Argon charged
Shipped InWet ice
Product Description

Product Describtion:

tBuDavePhos Pd G3 is a third generation (G3) Buchwald precatalyst. It is air, moisture and thermally-stable and is highly soluble in a wide range of common organic solvents. It has a long life in solutions. tBuDavePhos Pd G3 is an excellent reagent for palladium catalyzed cross-coupling reactions. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio.


Product Application:

tBuDavePhos Pd G3 has been used as a precatalyst for the Synthesis of Aryl Sulfonamides via Palladium-Catalyzed Chlorosulfonylation of Arylboronic Acids. It may also be used for a variety of C-C and C-N cross-coupling reactions.

Names and Identifiers

IUPAC Name 2-(2-ditert-butylphosphanylphenyl)-N,N-dimethylaniline;methanesulfonic acid;palladium;2-phenylaniline
INCHI InChI=1S/C22H32NP.C12H10N.CH4O3S.Pd/c1-21(2,3)24(22(4,5)6)20-16-12-10-14-18(20)17-13-9-11-15-19(17)23(7)8;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h9-16H,1-8H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;-1;;
InChi Key JIFWMTDBDBVFGA-UHFFFAOYSA-N
Canonical SMILES CC(C)(C)P(C1=CC=CC=C1C2=CC=CC=C2N(C)C)C(C)(C)C.CS(=O)(=O)O.C1=CC=C([C-]=C1)C2=CC=CC=C2N.[Pd]
PubChem CID 155885089
Molecular Weight 711.20

Certificates

Certificate of Analysis(COA)

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Chemical and Physical Properties

SensitivityAir sensitive;light sensitive

Related Documents

Solution Calculators