Grouped product items

SKU

Size

Availability

Price

Qty

M434248-10ml

10ml

Available within 8-12 weeks(?)

$371.90

M434248-50ml

50ml

Available within 8-12 weeks(?)

$1,533.90

Basic Description

Synonyms	Methanol-d4\|811-98-3\|Tetradeuteromethanol\|Methan-d3-ol-d\|Methyl Alcohol-d4\|trideuterio(deuteriooxy)methane\|Methyl-d3 alcohol d\|CD3OD\|Methanol D4\|methyl-d3 alcohol-d\|MFCD00044637\|(2H4)Methanol\|Perdeuteromethanol\|Methanol-d4, 99.8 atom % D\|Methanol-d4, >=99
Specifications & Purity	99 atom % D
Product Description	General Description Methanol-d 4 (CD 3 OD) is a deuterated NMR solvent. It is useful in NMR-based research and analyses. Absolute infrared absorption intensities of CD 3 OD have been reported between 8000 and 350cm -1 .1 Application Methanol-d 4 may be used as a solvent to analyze the rate of exchange of methoxyl group in camphor and norcamphor dimethyl ketals.

Names and Identifiers

IUPAC Name	trideuterio(deuteriooxy)methane
INCHI	InChI=1S/CH4O/c1-2/h2H,1H3/i1D3,2D
InChi Key	OKKJLVBELUTLKV-MZCSYVLQSA-N
Canonical SMILES	CO
Isomeric SMILES	[2H]C([2H])([2H])O[2H]
WGK Germany	1
PubChem CID	71568
UN Number	1230
Molecular Weight	36.07
Beilstein	1733278

Certificates

Certificate of Analysis(COA)

Enter Lot Number to search for COA:

To view the certificate results,please click on a Lot number.For Lot numbers from past orders,please use our order status section

2 results found

Lot Number	Certificate Type	Date	Item
G2424295	Certificate of Analysis	Aug 08, 2024	M434248
C2420063	Certificate of Analysis	Apr 12, 2024	M434248

Chemical and Physical Properties

Refractive Index	1.326
Flash Point(°F)	51.8 °F
Flash Point(°C)	11°C
Boil Point(°C)	65.4°C
Melt Point(°C)	-98°C

Safety and Hazards(GHS)

Pictogram(s)	GHS06, GHS08, GHS02
Signal	Danger
Hazard Statements	H301:Toxic if swallowed H311:Toxic in contact with skin H331:Toxic if inhaled H225:Highly Flammable liquid and vapor H370:Causes damage to organs
Precautionary Statements	P261:Avoid breathing dust/fume/gas/mist/vapors/spray. P280:Wear protective gloves/protective clothing/eye protection/face protection. P370+P378:In case of fire: Use ... to extinguish. P210:Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking. P302+P352:IF ON SKIN: wash with plenty of water. P321:Specific treatment (see ... on this label). P405:Store locked up. P501:Dispose of contents/container to ... P233:Keep container tightly closed. P240:Ground/bond container and receiving equipment. P264:Wash hands [and …] thoroughly after handling. P403+P235:Store in a well-ventilated place. Keep cool. P260:Do not breathe dust/fume/gas/mist/vapors/spray. P303+P361+P353:IF ON SKIN (or hair): Take off Immediately all contaminated clothing. Rinse SKIN with water [or shower]. P271:Use only outdoors or in a well-ventilated area. P241:Use explosion-proof [electrical/ventilating/lighting/.../] equipment. P270:Do not eat, drink or smoke when using this product. P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing. P403+P233:Store in a well-ventilated place. Keep container tightly closed. P330:Rinse mouth. P242:Use only non-sparking tools. P243:Take precautionary measures against static discharge. P361+P364:Take off immediately all contaminated clothing and wash it before reuse. P301+P316:IF SWALLOWED: Get emergency medical help immediately. P308+P316:IF exposed or concerned: Get emergency medical help immediately. P316:Get emergency medical help immediately.
WGK Germany	1

References

1. Akiko Takagaki,Yuko Kato,Fumio Nanjo. (2014-06-21) Isolation and characterization of rat intestinal bacteria involved in biotransformation of (-)-epigallocatechin.. Archives of microbiology, 196 ((10)): (681-695). [PMID:24947740]
2. Prakash Parajuli,Ramesh Prasad Pandey,Niranjan Koirala,Yeo Joon Yoon,Byung-Gee Kim,Jae Kyung Sohng. (2014-06-21) Enzymatic synthesis of epothilone A glycosides.. AMB Express, 4 (31-31). [PMID:24949266]
3. Yueqiu Liu,Mia Nielsen,Dan Staerk,Anna K Jäger. (2014-07-22) High-resolution bacterial growth inhibition profiling combined with HPLC-HRMS-SPE-NMR for identification of antibacterial constituents in Chinese plants used to treat snakebites.. Journal of ethnopharmacology, 155 ((2)): (1276-1283). [PMID:25043779]
4. Martin Globisch,Marco Schindler,Jana Kreßler,Thomas Henle. (2014-07-30) Studies on the reaction of trans-2-heptenal with peanut proteins.. Journal of agricultural and food chemistry, 62 ((33)): (8500-8507). [PMID:25065678]
5. Ramesh Prasad Pandey,Prakash Parajuli,Ju Yong Shin,Jisun Lee,Seul Lee,Young-Soo Hong,Yong Il Park,Joong Su Kim,Jae Kyung Sohng. (2014-09-23) Enzymatic Biosynthesis of Novel Resveratrol Glucoside and Glycoside Derivatives.. Applied and environmental microbiology, 80 ((23)): (7235-7243). [PMID:25239890]
6. Xijuan Chen,Mònica Escolà Casas,Jeppe Lund Nielsen,Reinhard Wimmer,Kai Bester. (2014-10-13) Identification of Triclosan-O-Sulfate and other transformation products of Triclosan formed by activated sludge.. The Science of the total environment, 505 (39-46). [PMID:25306094]
7. Iwona Kowalska,Lukasz Pecio,Lukasz Ciesla,Wieslaw Oleszek,Anna Stochmal. (2014-10-31) Isolation, chemical characterization, and free radical scavenging activity of phenolics from Triticum aestivum L. aerial parts.. Journal of agricultural and food chemistry, 62 ((46)): (11200-11208). [PMID:25356666]
8. Seong-Hoon Kim,Ha-Na Lyu,Ye Seul Kim,Yong Hyun Jeon,Wanil Kim,Sangjune Kim,Jong-Kwan Lim,Ho Won Lee,Nam-In Baek,Kwan-Yong Choi,Jaetae Lee,Kyong-Tai Kim. (2014-11-06) Brazilin Isolated from Caesalpinia sappan suppresses nuclear envelope reassembly by inhibiting barrier-to-autointegration factor phosphorylation.. The Journal of pharmacology and experimental therapeutics, 352 ((1)): (175-184). [PMID:25369797]
9. Yunpeng Bai,Brandon Findlay,Alma Fernanda Sanchez Maldonado,Andreas Schieber,John C Vederas,Michael G Gänzle. (2014-11-06) Novel pyrano and vinylphenol adducts of deoxyanthocyanidins in sorghum sourdough.. Journal of agricultural and food chemistry, 62 ((47)): (11536-11546). [PMID:25370078]
10. Alexis Lavaud,Pascal Richomme,Julia Gatto,Marie-Christine Aumond,Cyril Poullain,Marc Litaudon,Ramaroson Andriantsitohaina,David Guilet. (2014-12-04) A tocotrienol series with an oxidative terminal prenyl unit from Garcinia amplexicaulis.. Phytochemistry, 109 (103-110). [PMID:25468538]
11. Prabhakar S Achanta,Rajesh Kumar Gattu,Adavi Rao V Belvotagi,Raghuram Rao Akkinepally,Ravi Kumar Bobbala,Appa Rao V N Achanta. (2014-12-08) New malabaricane triterpenes from the oleoresin of Ailanthus malabarica.. Fitoterapia, 100 (166-173). [PMID:25481374]
12. Zeyun Li,Edward Welbeck,Li Yang,Chunyong He,Haijun Hu,Ming Song,Kaishun Bi,Zhengtao Wang. (2014-12-17) A quantitative ¹H nuclear magnetic resonance (qHNMR) method for assessing the purity of iridoids and secoiridoids.. Fitoterapia, 100 (187-194). [PMID:25510321]
13. Cheng-Kun Lin,Li-Wei Cheng,Huang-Yi Li,Wen-Yi Yun,Wei-Chieh Cheng. (2014-12-20) Synthesis of novel polyhydroxylated pyrrolidine-triazole/-isoxazole hybrid molecules.. Organic & biomolecular chemistry, 13 ((7)): (2100-2107). [PMID:25525831]
14. Zheng Pan,Gang Fan,Rong-ping Yang,Wei-zao Luo,Xiang-dong Zhou,Yi Zhang. (2015-02-20) Discriminating Lamiophlomis rotata According to Geographical Origin by (1)H-NMR Spectroscopy and Multivariate Analysis.. Phytochemical analysis : PCA, 26 ((4)): (247-252). [PMID:25693849]
15. Ugo Bussy,Yu-Wen Chung-Davidson,Ke Li,Weiming Li. (2015-03-03) A quantitative assay for reductive metabolism of a pesticide in fish using electrochemistry coupled with liquid chromatography tandem mass spectrometry.. Environmental science & technology, 49 ((7)): (4450-4457). [PMID:25730707]
16. Akiko Takagaki,Fumio Nanjo. (2015-03-10) Biotransformation of (-)-epigallocatechin and (-)-gallocatechin by intestinal bacteria involved in isoflavone metabolism.. Biological & pharmaceutical bulletin, 38 ((2)): (325-330). [PMID:25747993]
17. Athina Dimopoulou,Stella Manta,Vanessa Parmenopoulou,Petros Gkizis,Evdoxia Coutouli-Argyropoulou,Dominique Schols,Dimitri Komiotis. (2015-03-17) Synthesis of novel thiopurine pyranonucleosides: evaluation of their bioactivity.. Nucleosides, nucleotides & nucleic acids, 34 ((4)): (289-308). [PMID:25774721]
18. Silke S Heinzmann,Philippe Schmitt-Kopplin. (2015-03-20) Deep metabotyping of the murine gastrointestinal tract for the visualization of digestion and microbial metabolism.. Journal of proteome research, 14 ((5)): (2267-2277). [PMID:25786653]
19. Naoyuki Nakada,Kazuo Oda. (2015-04-15) Identification and characterization of metabolites of ASP015K, a novel oral Janus kinase inhibitor, in rats, chimeric mice with humanized liver, and humans.. Xenobiotica; the fate of foreign compounds in biological systems, 45 ((9)): (757-765). [PMID:25869242]
20. Noemí Alarcos,Mario Gutierrez,Marta Liras,Félix Sánchez,Abderrazzak Douhal. (2015-04-15) An abnormally slow proton transfer reaction in a simple HBO derivative due to ultrafast intramolecular-charge transfer events.. Physical chemistry chemical physics : PCCP, 17 ((25)): (16257-16269). [PMID:25870162]
21. Elise Ivarsen,Xavier C Fretté,Kathrine B Christensen,Lars P Christensen,Ricarda M Engberg,Kai Grevsen,Anders Kjaer. (2015-04-24) Bioassay-Guided Chromatographic Isolation and Identification of Antibacterial Compounds from Artemisia annua L. That Inhibit Clostridium perfringens Growth.. Journal of AOAC International, 97 ((5)): (1282-1290). [PMID:25902977]
22. Nicholas Fowler,Carmelo Tomas,Daniel Baden,Lisa Campbell,Andrea Bourdelais. (2015-05-20) Chemical analysis of Karenia papilionacea.. Toxicon : official journal of the International Society on Toxinology, 101 (85-91). [PMID:25981346]
23. Jinping Jia,Fusheng Zhang,Zhenyu Li,Xuemei Qin,Liwei Zhang. (2015-06-04) Comparison of Fruits of Forsythia suspensa at Two Different Maturation Stages by NMR-Based Metabolomics.. Molecules (Basel, Switzerland), 20 ((6)): (10065-10081). [PMID:26035103]
24. Shouqiang Ouyang,Consuelo N Beecher,Kang Wang,Cynthia K Larive,Katherine A Borkovich. (2015-07-22) Metabolic Impacts of Using Nitrogen and Copper-Regulated Promoters to Regulate Gene Expression in Neurospora crassa.. G3 (Bethesda, Md.), 5 ((9)): (1899-1908). [PMID:26194204]
25. Ram Jee Sharma,Ramesh C Gupta,Arvind Kumar Bansal,Inder Pal Singh. (2015-07-23) Metabolite Fingerprinting of Eugenia jambolana Fruit Pulp Extracts using NMR, HPLC-PDA-MS, GC-MS, MALDI-TOF-MS and ESI-MS/MS Spectrometry.. Natural product communications, 10 ((6)): (969-976). [PMID:26197529]
26. Jan Vicente,Allison K Stewart,Ryan M van Wagoner,Elizabeth Elliott,Andrea J Bourdelais,Jeffrey L C Wright. (2015-08-01) Monacyclinones, New Angucyclinone Metabolites Isolated from Streptomyces sp. M7_15 Associated with the Puerto Rican Sponge Scopalina ruetzleri.. Marine drugs, 13 ((8)): (4682-4700). [PMID:26230704]
27. Jon Kapla,Olof Engström,Baltzar Stevensson,Jakob Wohlert,Göran Widmalm,Arnold Maliniak. (2015-08-08) Molecular dynamics simulations and NMR spectroscopy studies of trehalose-lipid bilayer systems.. Physical chemistry chemical physics : PCCP, 17 ((34)): (22438-22447). [PMID:26252429]
28. Wenguang Wang,Xiaoli Ma,Xiaoyu Guo,Mingbo Zhao,Pengfei Tu,Yong Jiang. (2015-08-25) A series of strategies for solving the shortage of reference standards for multi-components determination of traditional Chinese medicine, Mahoniae Caulis as a case.. Journal of chromatography. A, 1412 (100-111). [PMID:26298606]
29. Eun Ju Choi,Sang-Jip Nam,Lauren Paul,Deanna Beatty,Christopher A Kauffman,Paul R Jensen,William Fenical. (2015-08-25) Previously Uncultured Marine Bacteria Linked to Novel Alkaloid Production.. Chemistry & biology, 22 ((9)): (1270-1279). [PMID:26299672]
30. Toshikazu Yamaoka,Yoshiaki Kitamura. (2015-09-01) Characterization of a highly sensitive and selective novel trapping reagent, stable isotope labeled glutathione ethyl ester, for the detection of reactive metabolites.. Journal of pharmacological and toxicological methods, 76 (83-95). [PMID:26314789]
31. Shufang Wang,Yunxiang Zhu,Qing Shao,Yi Wang,Xiaohui Fan,Yiyu Cheng. (2015-09-24) Identification of chemical constituents in two traditional Chinese medicine formulae by liquid chromatography-mass spectrometry and off-line nuclear magnetic resonance.. Journal of pharmaceutical and biomedical analysis, 117 (255-265). [PMID:26397205]
32. Shogo Mori,Howard Williams,Davey Cagle,Kristopher Karanovich,F David Horgen,Roger Smith,Coran M H Watanabe. (2015-10-17) Macrolactone Nuiapolide, Isolated from a Hawaiian Marine Cyanobacterium, Exhibits Anti-Chemotactic Activity.. Marine drugs, 13 ((10)): (6274-6290). [PMID:26473885]
33. Thuy Nguyen,Nadezhda German,Ann M Decker,Jun-Xu Li,Jenny L Wiley,Brian F Thomas,Terry P Kenakin,Yanan Zhang. (2015-03-24) Structure-activity relationships of substituted 1H-indole-2-carboxamides as CB1 receptor allosteric modulators.. Bioorganic & medicinal chemistry, 23 ((9)): (2195-2203). [PMID:25797163]

Solution Calculators

Molarity Calculator

Determine the necessary mass, volume, or concentration for preparing a solution.

Dilution Calculator

Determine the dilution needed to prepare a stock solution.

Methanol-d₄ - 99 atom % D, high purity , CAS No.811-98-3