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N-[[1,1'-Biphenyl]-4-yl]-9,9-dimethyl-N-[4-(9-phenyl-9H-carbazol-3-yl)phenyl]-9H-fluoren-2-amine - 98%, high purity , CAS No.1242056-42-3

  • ≥98%
Item Number
H398625
Grouped product items
SKUSizeAvailabilityPrice Qty
H398625-1g
1g
In stock
$18.90
H398625-5g
5g
In stock
$55.90
H398625-25g
25g
In stock
$251.90

Discover N-[[1,1'-Biphenyl]-4-yl]-9,9-dimethyl-N-[4-(9-phenyl-9H-carbazol-3-yl)phenyl]-9H-fluoren-2-amine by Aladdin Scientific in 98% for only $18.90. Available - in Ligands at Aladdin Scientific. Tags: Fluorene.

View related series
Fluorene

Basic Description

Synonyms1242056-42-3|N-([1,1'-Biphenyl]-4-yl)-9,9-dimethyl-N-(4-(9-phenyl-9H-carbazol-3-yl)phenyl)-9H-fluoren-2-amine|n-(biphenyl-4-yl)-9,9-dimethyl-n-(4-(9-phenyl-9h-carbazol-3-yl)phenyl)-9h-fluoren-2-amine|9,9-dimethyl-N-[4-(9-phenylcarbazol-3-yl)phenyl]-N-(4-p
Specifications & Purity98%
Storage TempStore at 2-8°C,Protected from light
Shipped InWet ice
Product Description

Application:

N-([1,1′-biphenyl]-4-yl)-9,9-dimethyl-N-(4-(9-phenyl-9H-carbazol-3-yl)phenyl)-9H-fluoren-2-amine (BCFN) is an electron-rich material, with the HOMO energy level of 5.3 eV, the LUMO energy level of 2.2 eV and high hole mobility of 5.43 × 10-5 cm2V-1s-1. As a result, it is used as a hole-transport and hole-injection material in organic light-emitting diodes. BCFN has shown its advantages in improving the hole mobility of polymer-based hole transport layer; lower driving voltage of device, better efficiency, and higher EQE due to exciplex formation by utilizing in EML; and better device lifetimes in the combination of Ir(piq)2(acac) to act as an electron scavenger layer for an reported device.

BCFN is a good morphologically stable material with Tg of 125 °C and Td of 375 °C.

With a ET of 2.58 eV, BCFN is also a very good charge transporting layer material due to its large band gap (Eg = 3.1 eV) 2 for green, red and white phosphorescent organic light-emitting diodes (PhOLEDs).

OLED Device Performance:

BCFN increase the hole transport mobility of PVK (pure PVK: 2.09×10-9 V cm-1 S-1; 30% of BCFN in PVK: 9.86×10-7 V cm-1 S-1; 50% of BCFN in PVK: 1.15×10-5 V cm-1 S-1):

1. ITO/PEDOT:PSS (40 nm)/PVK:BCFN (3:7, 20 nm)/BCFN:PFO (x:1-x, 80 nm)/CsF (1.5 nm)/Al (120 nm)

Color: Blue

BCFN in combination of ET1 to act as EML in forming exciplex and improve device performance:

2. ITO/HIL/HTL/(ET1+P1) or (ET1+BCFN+P1(doped)/ETL/ LiF/Al

Color: red

Device emission area of 81cm2, and at 1000 cd m-2, the efficiency exceeds 200 lm/W and the EQE exceeds 50 %.

lifespan@95: from 71h to 133h

BCFN in combination with Ir(piq)2(acac) as electron scavenger layer:

3. ITO/NDP series in BCFN (3wt.%, 10nm)/BCFN(160nm) or BCFN(130nm)+BCFN:Ir(piq)2(acac)(2wt.%, 10nm)+BCFN(20)/ [Ir(TMSBppy)ppy2]:BPTZBC (10 wt.%, 40nm))/ TPBi:Liq (1:1 wt. % ratio, 36nm)/ Liq (0.1nm)/Al (60 nm)

Color: yellow

Efficiencies are not affected.

lifespan@95: from 71h to 133h

Names and Identifiers

Pubchem Sid488201882
IUPAC Name 9,9-dimethyl-N-[4-(9-phenylcarbazol-3-yl)phenyl]-N-(4-phenylphenyl)fluoren-2-amine
INCHI InChI=1S/C51H38N2/c1-51(2)47-19-11-9-17-43(47)44-31-30-42(34-48(44)51)52(40-26-21-36(22-27-40)35-13-5-3-6-14-35)41-28-23-37(24-29-41)38-25-32-50-46(33-38)45-18-10-12-20-49(45)53(50)39-15-7-4-8-16-39/h3-34H,1-2H3
InChi Key GJWBRYKOJMOBHH-UHFFFAOYSA-N
Canonical SMILES CC1(C2=CC=CC=C2C3=C1C=C(C=C3)N(C4=CC=C(C=C4)C5=CC=CC=C5)C6=CC=C(C=C6)C7=CC8=C(C=C7)N(C9=CC=CC=C98)C1=CC=CC=C1)C
Isomeric SMILES CC1(C2=CC=CC=C2C3=C1C=C(C=C3)N(C4=CC=C(C=C4)C5=CC=CC=C5)C6=CC=C(C=C6)C7=CC8=C(C=C7)N(C9=CC=CC=C98)C1=CC=CC=C1)C
PubChem CID 57746495
Molecular Weight 678.86
Reaxy-Rn 23350798

Certificates

Certificate of Analysis(COA)

Enter Lot Number to search for COA:

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5 results found

Lot NumberCertificate TypeDateItem
B2302733Certificate of AnalysisOct 29, 2022 H398625
B2302739Certificate of AnalysisOct 29, 2022 H398625
B2302744Certificate of AnalysisOct 29, 2022 H398625
B2302745Certificate of AnalysisOct 29, 2022 H398625
B2302752Certificate of AnalysisOct 29, 2022 H398625

Chemical and Physical Properties

Sensitivitylight sensitive
Melt Point(°C)156 °C

Safety and Hazards(GHS)

Pictogram(s) GHS07
Signal Warning
Hazard Statements

H315:Causes skin irritation

H319:Causes serious eye irritation

H335:May cause respiratory irritation

H302:Harmful if swallowed

Precautionary Statements

P261:Avoid breathing dust/fume/gas/mist/vapors/spray.

P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.

P280:Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352:IF ON SKIN: wash with plenty of water.

P321:Specific treatment (see ... on this label).

P405:Store locked up.

P501:Dispose of contents/container to ...

P264:Wash hands [and …] thoroughly after handling.

P271:Use only outdoors or in a well-ventilated area.

P270:Do not eat, drink or smoke when using this product.

P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P403+P233:Store in a well-ventilated place. Keep container tightly closed.

P362+P364:Take off contaminated clothing and wash it before reuse.

P330:Rinse mouth.

P264+P265:Wash hands [and …] thoroughly after handling. Do not touch eyes.

P301+P317:IF SWALLOWED: Get medical help.

P337+P317:If eye irritation persists: Get medical help.

P332+P317:If skin irritation occurs: Get medical help.

P319:Get medical help if you feel unwell.

Reaxy-Rn 23350798

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