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N-Allyl-N,N-bis(trimethylsilyl)amine - 95%, high purity , CAS No.7688-51-9

  • ≥95%
Item Number
N300846
Grouped product items
SKUSizeAvailabilityPrice Qty
N300846-1g
1g
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$35.90
N300846-5g
5g
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$137.90
N300846-25g
25g
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$619.90

Basic Description

Synonyms7688-51-9|N-Allyl-N,N-bis(trimethylsilyl)amine|N,N-Bis(trimethylsilyl)allylamine|N,N-bis(trimethylsilyl)prop-2-en-1-amine|N-Allyl-1,1,1-trimethyl-N-(trimethylsilyl)silylamine|N-ALLYL-N N-BIS(TRIMETHYLSILYL)AMINE|EINECS 231-699-2|Allylbis(trimethylsilyl)am
Specifications & Purity95%
Storage TempArgon charged
Shipped InNormal
Product Description

Application:

N-Allyl-N,N-bis(trimethylsilyl)amine or N,N-bis(trimethylsilyl)prop-2-en-1-amine (AHMDS) can be used as a nucleophilic reagent to prepare:

• Complex bicyclic scaffolds by reacting with aryl aldehydes via imine formation followed by efficient multicomponent reactions.

• Dithiasuccinoyl (Dts) heterocycle by reacting with bisthiocarbamoyl chloride.

• Allyl selenide by reacting with aryl selenium salt in the presence of a ruthenium catalyst; Allyl selenide is utilized as a key intermediate in organic synthesis.

AHMDS can also be used as a reagent in hydrosilylation and hydroboration reaction. It may be also used as an electrolyte additive.

Names and Identifiers

IUPAC Name N,N-bis(trimethylsilyl)prop-2-en-1-amine
INCHI InChI=1S/C9H23NSi2/c1-8-9-10(11(2,3)4)12(5,6)7/h8H,1,9H2,2-7H3
InChi Key CVNCFZIIZGNVFD-UHFFFAOYSA-N
Canonical SMILES C[Si](C)(C)N(CC=C)[Si](C)(C)C
Isomeric SMILES C[Si](C)(C)N(CC=C)[Si](C)(C)C
WGK Germany 3
PubChem CID 82125
Molecular Weight 201.46

Certificates

Certificate of Analysis(COA)

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12 results found

Lot NumberCertificate TypeDateItem
I2402547Certificate of AnalysisAug 23, 2024 N300846
I2402548Certificate of AnalysisAug 23, 2024 N300846
E2416308Certificate of AnalysisMay 08, 2024 N300846
E2416310Certificate of AnalysisMay 08, 2024 N300846
E2416323Certificate of AnalysisMay 08, 2024 N300846
E2416324Certificate of AnalysisMay 08, 2024 N300846
E2416325Certificate of AnalysisMay 08, 2024 N300846
E2416331Certificate of AnalysisMay 08, 2024 N300846
E2108164Certificate of AnalysisFeb 13, 2023 N300846
F2214427Certificate of AnalysisMay 28, 2022 N300846
F2214428Certificate of AnalysisMay 28, 2022 N300846
F2214663Certificate of AnalysisMay 28, 2022 N300846

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Chemical and Physical Properties

SensitivityMoisture sensitive
Refractive Indexn20/D 1.440 (lit.)
Flash Point(°F)107.6 °F
Flash Point(°C)42 °C
Boil Point(°C)72°C/15 mmHg (lit.)

Safety and Hazards(GHS)

Pictogram(s) GHS07,   GHS02
Signal Warning
Hazard Statements

H315:Causes skin irritation

H319:Causes serious eye irritation

H335:May cause respiratory irritation

H226:Flammable liquid and vapor

Precautionary Statements

P261:Avoid breathing dust/fume/gas/mist/vapors/spray.

P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.

P280:Wear protective gloves/protective clothing/eye protection/face protection.

P370+P378:In case of fire: Use ... to extinguish.

P210:Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking.

P302+P352:IF ON SKIN: wash with plenty of water.

P321:Specific treatment (see ... on this label).

P405:Store locked up.

P501:Dispose of contents/container to ...

P233:Keep container tightly closed.

P240:Ground/bond container and receiving equipment.

P264:Wash hands [and …] thoroughly after handling.

P403+P235:Store in a well-ventilated place. Keep cool.

P303+P361+P353:IF ON SKIN (or hair): Take off Immediately all contaminated clothing. Rinse SKIN with water [or shower].

P271:Use only outdoors or in a well-ventilated area.

P241:Use explosion-proof [electrical/ventilating/lighting/.../] equipment.

P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P403+P233:Store in a well-ventilated place. Keep container tightly closed.

P362+P364:Take off contaminated clothing and wash it before reuse.

P242:Use only non-sparking tools.

P243:Take precautionary measures against static discharge.

P264+P265:Wash hands [and …] thoroughly after handling. Do not touch eyes.

P337+P317:If eye irritation persists: Get medical help.

P332+P317:If skin irritation occurs: Get medical help.

P319:Get medical help if you feel unwell.

WGK Germany 3
RIDADR UN1993C3/PGIII

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