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n-Butyllithium solution - 1.6M in hexane(15% solution), high purity , CAS No.109-72-8(solution)

  • 1.6M in hexane(15% solution)
Item Number
B107552
Grouped product items
SKUSizeAvailabilityPrice Qty
B107552-100ml
100ml
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$51.90
B107552-500ml
500ml
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$126.90

Basic Description

Specifications & Purity1.6M in hexane(15% solution)
Storage TempStore at 2-8°C,Argon charged
Shipped InWet ice

Names and Identifiers

UN Number 3394
Packing Group I
Molecular Weight 64.06

Certificates

Certificate of Analysis(COA)

Enter Lot Number to search for COA:

To view the certificate results,please click on a Lot number.For Lot numbers from past orders,please use our order status section

18 results found

Lot NumberCertificate TypeDateItem
H2409312Certificate of AnalysisSep 09, 2024 B107552
H2409315Certificate of AnalysisSep 09, 2024 B107552
H2409314Certificate of AnalysisJul 29, 2024 B107552
H2415109Certificate of AnalysisJul 13, 2024 B107552
D2420039Certificate of AnalysisJun 04, 2024 B107552
D2420103Certificate of AnalysisJun 04, 2024 B107552
I2306100Certificate of AnalysisNov 13, 2023 B107552
I2306101Certificate of AnalysisAug 25, 2023 B107552
G2319037Certificate of AnalysisAug 16, 2023 B107552
H2315320Certificate of AnalysisApr 10, 2023 B107552
C23101150Certificate of AnalysisFeb 23, 2023 B107552
C23101164Certificate of AnalysisFeb 23, 2023 B107552
K2212116Certificate of AnalysisOct 17, 2022 B107552
K2212115Certificate of AnalysisOct 17, 2022 B107552
G2209042Certificate of AnalysisJul 04, 2022 B107552
G2209040Certificate of AnalysisJul 04, 2022 B107552
B2211229Certificate of AnalysisJan 22, 2022 B107552
B2211214Certificate of AnalysisJan 22, 2022 B107552

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Chemical and Physical Properties

SensitivityAir & Moisture & Heat Sensitive
Flash Point(°F)-7°F
Flash Point(°C)-21°C
Boil Point(°C)80 °C

Safety and Hazards(GHS)

Pictogram(s) GHS08,   GHS09,   GHS05,   GHS07,   GHS02
Signal Danger
Hazard Statements

H315:Causes skin irritation

H373:Causes damage to organs through prolonged or repeated exposure

H411:Toxic to aquatic life with long lasting effects

H225:Highly Flammable liquid and vapor

H336:May cause drowsiness or dizziness

H304:May be fatal if swallowed and enters airways

H361:Suspected of damaging fertility or the unborn child

Precautionary Statements

P273:Avoid release to the environment.

P280:Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310:IF SWALLOWED: Immediately call a POISON CENTER/doctor/...

P370+P378:In case of fire: Use ... to extinguish.

P210:Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking.

P405:Store locked up.

P501:Dispose of contents/container to ...

P312:Call a POISON CENTER or doctor/... if you feel unwell.

P233:Keep container tightly closed.

P240:Ground/bond container and receiving equipment.

P264:Wash hands [and …] thoroughly after handling.

P403+P235:Store in a well-ventilated place. Keep cool.

P260:Do not breathe dust/fume/gas/mist/vapors/spray.

P303+P361+P353:IF ON SKIN (or hair): Take off Immediately all contaminated clothing. Rinse SKIN with water [or shower].

P201:Obtain special instructions before use.

P308+P313:IF exposed or concerned: Get medical advice/attention.

P271:Use only outdoors or in a well-ventilated area.

P241:Use explosion-proof [electrical/ventilating/lighting/.../] equipment.

P331:Do NOT induce vomiting.

P270:Do not eat, drink or smoke when using this product.

P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P403+P233:Store in a well-ventilated place. Keep container tightly closed.

P332+P313:IF SKIN irritation occurs: Get medical advice/attention.

P391:Collect spillage.

P202:Do not handle until all safety precautions have been read and understood.

P242:Use only non-sparking tools.

P243:Take precautionary measures against static discharge.

Class 4.2(4.3)

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References

1. J P Parente,P Cardon,Y Leroy,J Montreuil,B Fournet,G Ricart.  (1985-08-15)  A convenient method for methylation of glycoprotein glycans in small amounts by using lithium methylsulfinyl carbanion..  Carbohydrate research,  141  ((1)): (41-47).  [PMID:4042112]
2. Madeleine A Jacobson,Paul G Williard.  (2002-01-05)  Synthesis of 2,3-disubstituted pyrroles from 3,N-dilithio-N-(tert-butyldimethylsilyl)-2-buten-1-amine..  The Journal of organic chemistry,  67  ((1)): (32-37).  [PMID:11777436]
3. Jennifer L Rutherford,Daniele Hoffmann,David B Collum.  (2002-01-10)  Consequences of correlated solvation on the structures and reactivities of RLi-diamine complexes: 1,2-addition and alpha-lithiation reactions of imines by TMEDA-solvated n-butyllithium and phenyllithium..  Journal of the American Chemical Society,  124  ((2)): (264-271).  [PMID:11782178]
4. Shinichi Itsuno,Satoshi Tanaka,Akira Hirao.  (2002-06-28)  Preparation of polymer-supported benzyllithium reagents..  Bioorganic & medicinal chemistry letters,  12  ((14)): (1853-1856).  [PMID:12086833]
5. Lawrence M Pratt,Anthony Newman,Jason St Cyr,Harry Johnson,Benjamin Miles,April Lattier,Elizabeth Austin,Susan Henderson,Brad Hershey,Ming Lin,Yuvaraju Balamraju,Laurel Sammonds,Jeffery Cheramie,Jonathan Karnes,Ellen Hymel,Brittini Woodford,Carl Carter.  (2003-08-05)  Ketone enolization with lithium dialkylamides: the effects of structure, solvation, and mixed aggregates with excess butyllithium..  The Journal of organic chemistry,  68  ((16)): (6387-6391).  [PMID:12895075]
6. Madeleine A Jacobson,Ivan Keresztes,Paul G Williard.  (2005-03-31)  On the mechanism of THF catalyzed vinylic lithiation of allylamine derivatives: structural studies using 2-D and diffusion-ordered NMR spectroscopy..  Journal of the American Chemical Society,  127  ((13)): (4965-4975).  [PMID:15796563]
7. Mark A Forman,Caitlin Moran,Joseph P Herres,Jason Stairs,Emily Chopko,Anthony Pozzessere,Michael Kerrigan,Carisa Kelly,Lisa Lowchyj,Kerry Salandria,Annemarie Gallo,Elizabeth Loutzenhiser.  (2007-03-16)  Generation and reactions of Pentacyclo[4.3.0.0(2,4).0(3,8).0(5,7)]non-4-ene..  The Journal of organic chemistry,  72  ((8)): (2996-3005).  [PMID:17358080]
8. Petra Rönnholm,Mikael Södergren,Göran Hilmersson.  (2007-08-19)  Improved and efficient synthesis of chiral N,P-ligands via cyclic sulfamidates for asymmetric addition of butyllithium to benzaldehyde..  Organic letters,  ((19)): (3781-3783).  [PMID:17696545]
9. Deyu Li,Chengzao Sun,Jia Liu,Russell Hopson,Weibin Li,Paul G Williard.  (2008-02-26)  Aggregation studies of complexes containing a chiral lithium amide and n-Butyllithium..  The Journal of organic chemistry,  73  ((6)): (2373-2381).  [PMID:18294002]
10. Bernhard J Ueberbacher,Herfried Griengl,Hansjörg Weber.  (2008-07-16)  Ortho-lithiation of free ferrocenyl alcohols: a new method for the synthesis of planar chiral ferrocene derivatives..  Chemical communications (Cambridge, England),    ((28)(28)): (3287-3289).  [PMID:18622446]
11. Przemysław J Boratyński,Ilona Turowska-Tyrk,Jacek Skarzewski.  (2008-08-09)  Stereoselective C9 carbon-carbon couplings of quinine: synthesis and conformational analysis of new C2-symmetric dimers..  The Journal of organic chemistry,  73  ((18)): (7357-7360).  [PMID:18687001]
12. Michiko Sasaki,Hidaka Ikemoto,Masatoshi Kawahata,Kentaro Yamaguchi,Kei Takeda.  (2009-03-21)  [2,3]-Wittig rearrangement of enantiomerically enriched 3-substituted 1-propenyloxy-1-phenyl-2-propen-1-yl carbanions: effect of heteroatoms and conjugating groups on planarization of an alpha-oxy-benzylcarbanion through a double bond..  Chemistry (Weinheim an der Bergstrasse, Germany),  15  ((18)): (4663-4666).  [PMID:19301333]
13. Subramanian Devaraj,Rajendra C Jagdhane,Mysore S Shashidhar.  (2009-06-11)  Relative reactivity of hydroxyl groups in inositol derivatives: role of metal ion chelation..  Carbohydrate research,  344  ((10)): (1159-1166).  [PMID:19508911]
14. Ke Kong,Daniel Romo,Changsuk Lee.  (2009-09-04)  Enantioselective total synthesis of the marine toxin (-)-gymnodimine employing a Barbier-type macrocyclization..  Angewandte Chemie (International ed. in English),  48  ((40)): (7402-7405).  [PMID:19728353]
15. Michael A Tarselli,Glenn C Micalizio.  (2009-10-09)  Aliphatic imines in titanium-mediated reductive cross-coupling: unique reactivity of Ti(O-i-Pr)4/n-BuLi..  Organic letters,  11  ((20)): (4596-4599).  [PMID:19810765]
16. Stefan Marchart,Alexey Gromov,Johann Mulzer.  (2010-02-11)  Total synthesis of the antibiotic branimycin..  Angewandte Chemie (International ed. in English),  49  ((11)): (2050-2053).  [PMID:20146291]
17. Christian Unkelbach,Hannah S Rosenbaum,Carsten Strohmann.  (2012-09-21)  Direct benzylic metalation of a phenethylamine derivative: potassium as the key to both generation and stabilization of a labile anion..  Chemical communications (Cambridge, England),  48  ((86)): (10612-10614).  [PMID:22992791]
18. Carl Redshaw,Oliver Rowe,David L Hughes,Anna-Marie Fuller,Ilich A Ibarra,Simon M Humphrey.  (2013-01-03)  New structural motifs in lithium and zinc calix[4]arene chemistry..  Dalton transactions (Cambridge, England : 2003),  42  ((6)): (1983-1986).  [PMID:23280484]
19. Shigeo Hayashi, Naomi Ueno, Akio Murase, Junji Takada,.  (2014-02-13)  Design, synthesis and structure-activity relationship studies of novel and diverse cyclooxygenase-2 inhibitors as anti-inflammatory drugs..  Journal of enzyme inhibition and medicinal chemistry,  29  ((6)): ( 846-867 ).  [PMID:24517373]
20. Mostafa Shahin,Nazila Safaei-Nikouei,Afsaneh Lavasanifar.  (2014-06-01)  Polymeric micelles for pH-responsive delivery of cisplatin..  Journal of drug targeting,  22  ((7)): (629-637).  [PMID:24878378]
21. Hiroki Mandai,Kazuhiro Omori,Daisuke Yamamoto,Toki Tsumura,Kyouta Murota,Satoshi Yamamoto,Koichi Mitsudo,Soichiro Ibaragi,Akira Sasaki,Hiroshi Maeda,Shogo Takashiba,Seiji Suga.  (2014-08-26)  Synthetic (+)-terrein suppresses interleukin-6/soluble interleukin-6 receptor induced-secretion of vascular endothelial growth factor in human gingival fibroblasts..  Bioorganic & medicinal chemistry,  22  ((19)): (5338-5344).  [PMID:25151086]
22. Hyojung Cha,Hyoung Nam Kim,Tae Kyu An,Moon Sung Kang,Soon-Ki Kwon,Yun-Hi Kim,Chan Eon Park.  (2014-08-26)  Effects of cyano-substituents on the molecular packing structures of conjugated polymers for bulk-heterojunction solar cells..  ACS applied materials & interfaces,  ((18)): (15774-15782).  [PMID:25153511]
23. André M Bienfait,Christoph Schädle,Cäcilia Maichle-Mössmer,Karl W Törnroos,Reiner Anwander.  (2014-10-17)  Europium bis(dimethylsilyl)amides including mixed-valent Eu3[N(SiHMe2)2]6[μ-N(SiHMe2)2]2..  Dalton transactions (Cambridge, England : 2003),  43  ((46)): (17324-17332).  [PMID:25318830]
24. B J Reeves,D M Shircliff,J L Shott,B M Boardman.  (2014-11-13)  Synthesis and investigation of cobalt chalcogenide clusters with thienyl phosphine ligands as new acceptor materials for P3HT..  Dalton transactions (Cambridge, England : 2003),  44  ((2)): (718-724).  [PMID:25388872]
25. Akram Ayoub,Jadson Moreira Pereira,Laurie-Eve Rioux,Sylvie L Turgeon,Martin Beaulieu,Véronique J Moulin.  (2015-01-21)  Role of seaweed laminaran from Saccharina longicruris on matrix deposition during dermal tissue-engineered production..  International journal of biological macromolecules,  75  (13-20).  [PMID:25603140]
26. Paolo Boggio,Antonio Toppino,Simonetta Geninatti Crich,Diego Alberti,Domenica Marabello,Claudio Medana,Cristina Prandi,Paolo Venturello,Silvio Aime,Annamaria Deagostino.  (2015-02-04)  The hydroboration reaction as a key for a straightforward synthesis of new MRI-NCT agents..  Organic & biomolecular chemistry,  13  ((11)): (3288-3297).  [PMID:25645198]
27. Lin Zhu,Xiao Tang,Qi Yu,Wen Lv,Hong Yan,Qiang Zhao,Wei Huang.  (2015-02-11)  Tuning the optical properties of 2-thienylpyridyl iridium complexes through carboranes and anions..  Chemistry (Weinheim an der Bergstrasse, Germany),  21  ((12)): (4721-4730).  [PMID:25663604]
28. Torben Steenbock,Alejandra Escribano,Jürgen Heck,Carmen Herrmann.  (2015-02-24)  Photoswitching Behavior of a Cyclohexene-Bridged versus a Cyclopentene-Bridged Dithienylethene System..  Chemphyschem : a European journal of chemical physics and physical chemistry,  16  ((7)): (1491-1501).  [PMID:25704168]
29. Xudong Guo,Xin Zhang,Shuangqing Wang,Shayu Li,Rui Hu,Yi Li,Guoqiang Yang.  (2015-03-31)  Sensing for intracellular thiols by water-insoluble two-photon fluorescent probe incorporating nanogel..  Analytica chimica acta,  869  (81-88).  [PMID:25818143]
30. E Ashley Gaulding,Benjamin T Diroll,E D Goodwin,Zachary J Vrtis,Cherie R Kagan,Christopher B Murray.  (2015-03-31)  Deposition of wafer-scale single-component and binary nanocrystal superlattice thin films via dip-coating..  Advanced materials (Deerfield Beach, Fla.),  27  ((18)): (2846-2851).  [PMID:25820834]
31. Erik Selander, Julia Kubanek, Mats Hamberg, Mats X Andersson, Gunnar Cervin, Henrik Pavia,.  (2015-04-29)  Predator lipids induce paralytic shellfish toxins in bloom-forming algae..  Proceedings of the National Academy of Sciences of the United States of America,  112  ((20)): ( 6395-6400 ).  [PMID:25918403]
32. Shouli Ming,Shijie Zhen,Kaiwen Lin,Li Zhao,Jingkun Xu,Baoyang Lu.  (2015-05-09)  Thiadiazolo[3,4-c]pyridine as an Acceptor toward Fast-Switching Green Donor-Acceptor-Type Electrochromic Polymer with Low Bandgap..  ACS applied materials & interfaces,  ((21)): (11089-11098).  [PMID:25955881]
33. Holger Braunschweig,Charlotte Brückner,Mehmet Ali Celik,Klaus Dück,Florian Hupp,Thomas Kramer,Johannes Krebs,Ivo Krummenacher.  (2015-06-26)  Ansa-bridged bis(benzene) titanium complexes..  Chemistry (Weinheim an der Bergstrasse, Germany),  21  ((31)): (11056-11064).  [PMID:26111216]
34. Thomas Pugh, Floriana Tuna, Liviu Ungur, David Collison, Eric J L McInnes, Liviu F Chibotaru, Richard A Layfield,.  (2015-07-02)  Influencing the properties of dysprosium single-molecule magnets with phosphorus donor ligands..  Nature communications,    ( 7492-7492 ).  [PMID:26130418]
35. Chee Shan Lim,Zdeněk Sofer,Vlastimil Mazánek,Martin Pumera.  (2015-07-04)  Layered titanium diboride: towards exfoliation and electrochemical applications..  Nanoscale,  ((29)): (12527-12534).  [PMID:26137856]
36. Xiaotian Hu,Lie Chen,Licheng Tan,Yong Zhang,Lin Hu,Bing Xie,Yiwang Chen.  (2015-07-17)  Versatile MoS2 Nanosheets in ITO-Free and Semi-transparent Polymer Power-generating Glass..  Scientific reports,  (12161-12161).  [PMID:26177887]
37. Shigeki Kawai,Shohei Saito,Shinichiro Osumi,Shigehiro Yamaguchi,Adam S Foster,Peter Spijker,Ernst Meyer.  (2015-08-26)  Atomically controlled substitutional boron-doping of graphene nanoribbons..  Nature communications,  (8098-8098).  [PMID:26302943]
38. Debabrata Jana,Shatabdi Boxi,Partha P Parui,Binay K Ghorai.  (2015-09-09)  Planar-rotor architecture based pyrene-vinyl-tetraphenylethylene conjugated systems: photophysical properties and aggregation behavior..  Organic & biomolecular chemistry,  13  ((43)): (10663-10674).  [PMID:26347380]

Solution Calculators