N-Heptafluorobutyrylimidazole - 97%, high purity , CAS No.32477-35-3

  • ≥97%
Item Number
H121495
Grouped product items
SKUSizeAvailabilityPrice Qty
H121495-1g
1g
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$31.90
H121495-5g
5g
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$109.90
H121495-25g
25g
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$429.90

Basic Description

SynonymsDTXSID40186211 | SY027465 | UNII-5I2481UOO8 | 1-(Pyridin-3-yl)ethanone oxime | beta-styrylboronic acid pinacol ester | PS-11103 | N-(Heptafluorobutyryl)imidazole | 4-[(E)-2-[(1R,4aS,5R,6R,8aR)-6-hydroxy-5-(hydroxymethyl)-5,8a-dimethyl-2-methylidene-3,4,4a
Specifications & Purity≥97%
Biochemical and Physiological Mechanisms1-(Heptafluorobutyryl)imidazole is a mild reagent used to derivatize amine-groups, and a non-acidic by-product that prevents decomposition and reduces GC column degradation.
Storage TempStore at 2-8°C,Argon charged
Shipped InWet ice

Names and Identifiers

IUPAC Name 2,2,3,3,4,4,4-heptafluoro-1-imidazol-1-ylbutan-1-one
INCHI InChI=1S/C7H3F7N2O/c8-5(9,6(10,11)7(12,13)14)4(17)16-2-1-15-3-16/h1-3H
InChi Key MSYHGYDAVLDKCE-UHFFFAOYSA-N
Canonical SMILES C1=CN(C=N1)C(=O)C(C(C(F)(F)F)(F)F)(F)F
Isomeric SMILES C1=CN(C=N1)C(=O)C(C(C(F)(F)F)(F)F)(F)F
WGK Germany 3
PubChem CID 94431
Molecular Weight 264.10
Beilstein 4488026
Reaxy-Rn 4488026

Certificates

Certificate of Analysis(COA)

Enter Lot Number to search for COA:

Find and download the COA for your product by matching the lot number on the packaging.

14 results found

Lot NumberCertificate TypeDateItem
D2429274Certificate of AnalysisMay 20, 2024 H121495
D2429275Certificate of AnalysisMay 20, 2024 H121495
D2429276Certificate of AnalysisMay 20, 2024 H121495
J2320433Certificate of AnalysisOct 24, 2023 H121495
J2320434Certificate of AnalysisOct 24, 2023 H121495
J2320435Certificate of AnalysisOct 24, 2023 H121495
F2301702Certificate of AnalysisJun 08, 2023 H121495
F2302224Certificate of AnalysisJun 08, 2023 H121495
F2302225Certificate of AnalysisJun 08, 2023 H121495
D2326028Certificate of AnalysisJun 10, 2022 H121495
D2328035Certificate of AnalysisJun 10, 2022 H121495
E2231449Certificate of AnalysisJun 10, 2022 H121495
E2231465Certificate of AnalysisJun 10, 2022 H121495
E2231470Certificate of AnalysisJun 10, 2022 H121495

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Chemical and Physical Properties

SolubilityMiscible with chloroform and methanol.
SensitivityAir & Moisture & Light & Heat Sensitive
Refractive Index1.385
Flash Point(°F)170.6 °F
Flash Point(°C)77°C
Boil Point(°C)160-162°C
Melt Point(°C)10-13°C

Safety and Hazards(GHS)

Pictogram(s) GHS07
Signal Warning
Hazard Statements

H315:Causes skin irritation

H319:Causes serious eye irritation

H335:May cause respiratory irritation

Precautionary Statements

P261:Avoid breathing dust/fume/gas/mist/vapors/spray.

P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.

P280:Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352:IF ON SKIN: wash with plenty of water.

P321:Specific treatment (see ... on this label).

P405:Store locked up.

P501:Dispose of contents/container to ...

P264:Wash hands [and …] thoroughly after handling.

P271:Use only outdoors or in a well-ventilated area.

P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P403+P233:Store in a well-ventilated place. Keep container tightly closed.

P362+P364:Take off contaminated clothing and wash it before reuse.

P264+P265:Wash hands [and …] thoroughly after handling. Do not touch eyes.

P337+P317:If eye irritation persists: Get medical help.

P332+P317:If skin irritation occurs: Get medical help.

P319:Get medical help if you feel unwell.

WGK Germany 3
Reaxy-Rn 4488026

Related Documents

Citations of This Product

1. Zhongfei Zhang, Puyu Yang, Boyan Gao, Guoren Huang, Man Liu, Liangli Lucy Yu.  (2019)  Synthesis of 2-Monochloropanol Fatty Acid Esters and Their Acute Oral Toxicities in Swiss Mice.  JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY,  67  (13): (3789–3795).  [PMID:30874433]

References

1. T Górski,T J Goehl,C W Jameson,B J Collins,J Bursey,R Moseman.  (1990-06-22)  Gas chromatographic determination of 2-ethylhexanol and 2-ethylhexanoic acid as derivatives suitable for electron-capture and nitrogen-phosphorus detection after single reaction with heptafluorobutyrylimidazole..  Journal of chromatography,  509  ((2)): (383-389).  [PMID:2211902]
2. Y Luo,J L Feng,F Liu,X Y Hu.  (1995-05-19)  Identification of dihydroetorphine in biological fluids by gas chromatography-mass spectrometry..  Journal of chromatography. B, Biomedical applications,  667  ((2)): (344-348).  [PMID:7663710]
3. Xinxin Li,Sen Hou,Xizeng Feng,Yong Yu,Jingjian Ma,Lanying Li.  (2009-09-01)  Patterning of neural stem cells on poly(lactic-co-glycolic acid) film modified by hydrophobin..  Colloids and surfaces. B, Biointerfaces,  74  ((1)): (370-374).  [PMID:19716276]
4. Zhiyong Nie,Qin Liu,Jianwei Xie.  (2011-07-06)  Improvements in monitoring the N-terminal valine adduct in human globin after exposure to sulfur mustard and synthesis of reference chemicals..  Talanta,  85  ((2)): (1154-1159).  [PMID:21726752]
5. Jussi J Joensuu,Andrew J Conley,Markus B Linder,Rima Menassa.  (2011-12-14)  Bioseparation of recombinant proteins from plant extract with hydrophobin fusion technology..  Methods in molecular biology (Clifton, N.J.),  824  (527-534).  [PMID:22160918]
6. J W Mayhew,S L Gorbach.  (1978-04-11)  Gas-liquid chromatographic method for the assay of aminoglycoside antibiotics in serum..  Journal of chromatography,  151  ((2)): (133-146).  [PMID:641129]
7. J V Johnson,R A Yost,O Beck,K F Faull.  (1985-01-01)  The use of tandem mass spectrometry for the identification and quantitation of tryptolines (tetrahydro-beta-carbolines) in tissue extracts..  Progress in clinical and biological research,  183  (161-177).  [PMID:4048182]
8. P H Degen,J R DoAmaral,J D Barchas.  (1972-02-01)  A gas-liquid chromatographic assay of melatonin and indoleamines using heptafluorobutyryl derivatives..  Analytical biochemistry,  45  ((2)): (634-644).  [PMID:5060611]
9. P M Scott,P Y Lau,S R Kanhere.  (1981-11-01)  Gas chromatography with electron capture and mass spectrometric detection of deoxynivalenol in wheat and other grains..  Journal - Association of Official Analytical Chemists,  64  ((6)): (1364-1371).  [PMID:7309655]
10. A Fidder,D Noort,A G Hulst,L P de Jong,H P Benschop.  (2000-08-26)  Biomonitoring of exposure to lewisite based on adducts to haemoglobin..  Archives of toxicology,  74  ((4-5)): (207-214).  [PMID:10959794]
11. Minjia Huang,Guibin Jiang,Bin He,Jingfu Liu,Qingxiang Zhou,Wusheng Fu,Yongning Wu.  (2005-12-02)  Determination of 3-chloropropane-1,2-diol in liquid hydrolyzed vegetable proteins and soy sauce by solid-phase microextraction and gas chromatography/mass spectrometry..  Analytical sciences : the international journal of the Japan Society for Analytical Chemistry,  21  ((11)): (1343-1347).  [PMID:16317903]
12. Zhongfei Zhang, Puyu Yang, Boyan Gao, Guoren Huang, Man Liu, Liangli Lucy Yu.  (2019)  Synthesis of 2-Monochloropanol Fatty Acid Esters and Their Acute Oral Toxicities in Swiss Mice.  JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY,  67  (13): (3789–3795).  [PMID:30874433]

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