N,N-Dimethylformamide-d₇ - D,99.5%, high purity , CAS No.4472-41-7

1 Citations
  • ≥99.5 atom% D
Item Number
N102258
Grouped product items
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N102258-0.6ml
0.6ml
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$65.90
N102258-1g
1g
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$85.90
N102258-5g
5g
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N102258-5×1g
5×1g
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N102258-10ml
10ml
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$925.90

Basic Description

SynonymsN,N-Dimethylformamide-d7 | 4472-41-7 | DMF-d7 | N,N-Di(2H3)methyl(2H)formamide | Deuterated DMF | Heptadeutero-N,N-dimethylformamide | 1-deuterio-N,N-bis(trideuteriomethyl)formamide | N,N-Dimethylformamide-d7 99.5atom%D | MFCD00003286 | N,N-Dimethylformamide-d7 (DMF-d7) | Di
Specifications & PurityD,99.5%
Storage TempArgon charged
Shipped InNormal
Product Description

N,N-Dimethylformamide-d7 (DMF-d7) is a deuterated derivative of N,N-dimethylformamide. It has an isotopic purity of 99.5atom%D. It is a standard purity solvent suitable for routine NMR analyses (conducted at ambient temperatures where quality is less critical). It participates as a solvent to evaluate the solvation of 1.7molar solution of lithium chloride (LiCl) by pulsed neutron diffraction studies. Quadrupole splittings and quadrupole coupling constants of DMF-d7 oriented in a nematic phase have been evaluated by deuteron magnetic resonance studies. DMF-d7 is being considered as a potent anti-cancer drug.

Names and Identifiers

IUPAC Name 1-deuterio-N,N-bis(trideuteriomethyl)formamide
INCHI InChI=1S/C3H7NO/c1-4(2)3-5/h3H,1-2H3/i1D3,2D3,3D
InChi Key ZMXDDKWLCZADIW-YYWVXINBSA-N
Canonical SMILES CN(C)C=O
Isomeric SMILES [2H]C(=O)N(C([2H])([2H])[2H])C([2H])([2H])[2H]
WGK Germany 3
Alternate CAS 68-12-2(unlabelled)
PubChem CID 78225
UN Number 2265
Molecular Weight 80.14
Beilstein 1908468

Certificates

Certificate of Analysis(COA)

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17 results found

Lot NumberCertificate TypeDateItem
D2410391Certificate of AnalysisApr 03, 2024 N102258
D2410384Certificate of AnalysisApr 03, 2024 N102258
D2410385Certificate of AnalysisApr 03, 2024 N102258
D2410386Certificate of AnalysisApr 03, 2024 N102258
D2410387Certificate of AnalysisApr 03, 2024 N102258
D2410388Certificate of AnalysisApr 03, 2024 N102258
D2410389Certificate of AnalysisApr 03, 2024 N102258
D2410390Certificate of AnalysisApr 03, 2024 N102258
A2111123Certificate of AnalysisApr 10, 2023 N102258
H2212506Certificate of AnalysisJul 21, 2022 N102258
H2212505Certificate of AnalysisJul 21, 2022 N102258
H2212403Certificate of AnalysisJul 21, 2022 N102258
A2309515Certificate of AnalysisJul 21, 2022 N102258
E2331132Certificate of AnalysisDec 29, 2021 N102258
A2214116Certificate of AnalysisDec 29, 2021 N102258
A2214115Certificate of AnalysisDec 29, 2021 N102258
A2214114Certificate of AnalysisDec 29, 2021 N102258

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Chemical and Physical Properties

SolubilitySoluble in water.
SensitivityHygroscopic
Refractive Index1.428
Flash Point(°F)136.4 °F
Flash Point(°C)58°C
Boil Point(°C)153°C

Safety and Hazards(GHS)

Pictogram(s) GHS08,   GHS07,   GHS02
Signal Danger
Hazard Statements

H319:Causes serious eye irritation

H312:Harmful in contact with skin

H226:Flammable liquid and vapor

H332:Harmful if inhaled

H360:May damage fertility or the unborn child

H312+H332:Harmful in contact with skin or if inhaled

Precautionary Statements

P261:Avoid breathing dust/fume/gas/mist/vapors/spray.

P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.

P280:Wear protective gloves/protective clothing/eye protection/face protection.

P370+P378:In case of fire: Use ... to extinguish.

P210:Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking.

P302+P352:IF ON SKIN: wash with plenty of water.

P321:Specific treatment (see ... on this label).

P405:Store locked up.

P501:Dispose of contents/container to ...

P233:Keep container tightly closed.

P240:Ground/bond container and receiving equipment.

P403+P235:Store in a well-ventilated place. Keep cool.

P303+P361+P353:IF ON SKIN (or hair): Take off Immediately all contaminated clothing. Rinse SKIN with water [or shower].

P271:Use only outdoors or in a well-ventilated area.

P241:Use explosion-proof [electrical/ventilating/lighting/.../] equipment.

P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P362+P364:Take off contaminated clothing and wash it before reuse.

P242:Use only non-sparking tools.

P243:Take precautionary measures against static discharge.

P203:Obtain, read and follow all safety instructions before use.

P264+P265:Wash hands [and …] thoroughly after handling. Do not touch eyes.

P318:if exposed or concerned, get medical advice.

P317:Get emergency medical help.

P337+P317:If eye irritation persists: Get medical help.

WGK Germany 3

Related Documents

Citations of This Product

1. Xie Wenhe, Ren Yuan, Jiang Fengluan, Huang Xin-Yu, Yu Bingjie, Liu Jianhong, Li Jichun, Chen Keyu, Zou Yidong, Hu Bingwen, Deng Yonghui.  (2023)  Solvent-pair surfactants enabled assembly of clusters and copolymers towards programmed mesoporous metal oxides.  Nature Communications,  14  (1): (1-9).  [PMID:38129402]

References

1. Sean E Doris,Jared J Lynch,Changyi Li,Andrew W Wills,Jeffrey J Urban,Brett A Helms.  (2014-10-11)  Mechanistic insight into the formation of cationic naked nanocrystals generated under equilibrium control..  Journal of the American Chemical Society,  136  ((44)): (15702-15710).  [PMID:25302526]
2. Seung Bin Baek,Dohyun Moon,Robert Graf,Woo Jong Cho,Sung Woo Park,Tae-Ung Yoon,Seung Joo Cho,In-Chul Hwang,Youn-Sang Bae,Hans W Spiess,Hee Cheon Lee,Kwang S Kim.  (2015-11-19)  High-temperature in situ crystallographic observation of reversible gas sorption in impermeable organic cages..  Proceedings of the National Academy of Sciences of the United States of America,  112  ((46)): (14156-14161).  [PMID:26578758]
3. Małgorzata Fabijańska,Kazimierz Studzian,Leszek Szmigiero,Agnieszka J Rybarczyk-Pirek,Arno Pfitzner,Barbara Cebula-Obrzut,Piotr Smolewski,Elżbieta Zyner,Justyn Ochocki.  (2014-08-12)  trans-Platinum(II) complex of 3-aminoflavone - synthesis, X-ray crystal structure and biological activities in vitro..  Dalton transactions (Cambridge, England : 2003),  44  ((3)): (938-947).  [PMID:25110914]
4. Xie Wenhe, Ren Yuan, Jiang Fengluan, Huang Xin-Yu, Yu Bingjie, Liu Jianhong, Li Jichun, Chen Keyu, Zou Yidong, Hu Bingwen, Deng Yonghui.  (2023)  Solvent-pair surfactants enabled assembly of clusters and copolymers towards programmed mesoporous metal oxides.  Nature Communications,  14  (1): (1-9).  [PMID:38129402]

Solution Calculators