N,N-Dimethylformamide-d₇ - ≥99.5 atom % D, contains 0.03.Flammable liquid % (v/v) TMS, high purity , CAS No.4472-41-7

  • ≥99.5 atom% D
  • contains 0.03% (v/v) TMS
Item Number
N432729
Grouped product items
SKUSizeAvailabilityPrice Qty
N432729-250mg
250mg
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$129.90
N432729-1g
1g
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Production requires sourcing of materials. We appreciate your patience and understanding.
$204.90
N432729-5g
5g
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$699.90
View related series
Deuterated NMR solvents

Basic Description

SynonymsHeptadeutero-N,N-dimethylformamide | 1-deuterio-N,N-bis(trideuteriomethyl)formamide | N,N-Dimethylformamide-d7, >=99.5 atom % D | Q1101322 | EINECS 224-745-8 | N,N-Dimethylformamide-d7 99.5atom%D | N,N-Dimethylformamide-d7, >=99.5 atom % D, contains 1 % (
Specifications & Purity≥99.5 atom% D, contains 0.03% (v/v) TMS
Product Description

N , N -Dimethylformamide-d 7 (DMF- d 7 ) is a deuterated NMR solvent containing 0.03.Flammable liquid% (v/v) TMS (tetramethylsilane). It is useful in NMR-based research and analyses. Pulsed neutron diffraction measurements of different concentrations of molar lithium chloride (LiCl) solutions in DMF- d 7 have been carried out to investigate the chloride ion solvation.


Application

N , N -Dimethylformamide-d 7 may be used to analyze the degree of acrylation by proton NMR during the preparation of polyethylene glycol diacrylate (PEG-DA) from poly(ethylene glycol) (PEG).

Names and Identifiers

IUPAC Name 1-deuterio-N,N-bis(trideuteriomethyl)formamide
INCHI InChI=1S/C3H7NO/c1-4(2)3-5/h3H,1-2H3/i1D3,2D3,3D
InChi Key ZMXDDKWLCZADIW-YYWVXINBSA-N
Canonical SMILES CN(C)C=O
Isomeric SMILES [2H]C(=O)N(C([2H])([2H])[2H])C([2H])([2H])[2H]
WGK Germany 3
Alternate CAS 68-12-2(unlabelled)
PubChem CID 78225
UN Number 2265
Molecular Weight 80.14
Beilstein 1908468

Certificates

Certificate of Analysis(COA)

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Chemical and Physical Properties

Refractive Index1.428
Flash Point(°F)136.4 °F
Flash Point(°C)58°C
Boil Point(°C)153°C

Safety and Hazards(GHS)

Pictogram(s) GHS08,   GHS07,   GHS02
Signal Danger
Hazard Statements

H319:Causes serious eye irritation

H312:Harmful in contact with skin

H226:Flammable liquid and vapor

H332:Harmful if inhaled

H360:May damage fertility or the unborn child

H312+H332:Harmful in contact with skin or if inhaled

Precautionary Statements

P261:Avoid breathing dust/fume/gas/mist/vapors/spray.

P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.

P280:Wear protective gloves/protective clothing/eye protection/face protection.

P370+P378:In case of fire: Use ... to extinguish.

P210:Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking.

P302+P352:IF ON SKIN: wash with plenty of water.

P321:Specific treatment (see ... on this label).

P405:Store locked up.

P501:Dispose of contents/container to ...

P233:Keep container tightly closed.

P240:Ground/bond container and receiving equipment.

P403+P235:Store in a well-ventilated place. Keep cool.

P303+P361+P353:IF ON SKIN (or hair): Take off Immediately all contaminated clothing. Rinse SKIN with water [or shower].

P271:Use only outdoors or in a well-ventilated area.

P241:Use explosion-proof [electrical/ventilating/lighting/.../] equipment.

P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P362+P364:Take off contaminated clothing and wash it before reuse.

P242:Use only non-sparking tools.

P243:Take precautionary measures against static discharge.

P203:Obtain, read and follow all safety instructions before use.

P264+P265:Wash hands [and …] thoroughly after handling. Do not touch eyes.

P318:if exposed or concerned, get medical advice.

P317:Get emergency medical help.

P337+P317:If eye irritation persists: Get medical help.

WGK Germany 3

Related Documents

Citations of This Product

1. Xie Wenhe, Ren Yuan, Jiang Fengluan, Huang Xin-Yu, Yu Bingjie, Liu Jianhong, Li Jichun, Chen Keyu, Zou Yidong, Hu Bingwen, Deng Yonghui.  (2023)  Solvent-pair surfactants enabled assembly of clusters and copolymers towards programmed mesoporous metal oxides.  Nature Communications,  14  (1): (1-9).  [PMID:38129402] [10.1038/s41467-023-44193-z]

References

1. Samuel Furse, Hans Wienk, Rolf Boelens, Anton I P M de Kroon, J Antoinette Killian,.  (2015-08-15)  E. coli MG1655 modulates its phospholipid composition through the cell cycle..  FEBS letters,  589  ((19 Pt B)): ( 2726-2730 ).  [PMID:26272829]
2. Xie Wenhe, Ren Yuan, Jiang Fengluan, Huang Xin-Yu, Yu Bingjie, Liu Jianhong, Li Jichun, Chen Keyu, Zou Yidong, Hu Bingwen, Deng Yonghui.  (2023)  Solvent-pair surfactants enabled assembly of clusters and copolymers towards programmed mesoporous metal oxides.  Nature Communications,  14  (1): (1-9).  [PMID:38129402] [10.1038/s41467-023-44193-z]

Solution Calculators