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Basic Description
| Synonyms | DMF-DMA | dimetylformamide dimethyl acetal | DMF dimethylacetal | n,n-dimethylformamid-dimethylacetal | N,N-Dimethylformamidedimethylacetal | n,n-dimethylformamide-dimethylacetal | 1,1-Dimethoxy-N,N-dimethylmethylamine | 1,1-Dimethoxy-N,N-dimethyl-methyla |
|---|---|
| Specifications & Purity | ≥97% |
| Storage Temp | Argon charged |
| Shipped In | Normal |
| Product Description | N,N-Dimethylformamide dimethyl acetal is a reagent for n-dimethylaminomethylene and methyl esters. It is used to catalyze the coupling of epoxides with carbon dioxide under solvent free conditions leading to cyclic carbonates. |
Names and Identifiers
| Pubchem Sid | 488185569 |
|---|---|
| Pubchem Sid Url | https://pubchem.ncbi.nlm.nih.gov/substance/488185569 |
| IUPAC Name | 1,1-dimethoxy-N,N-dimethylmethanamine |
| INCHI | InChI=1S/C5H13NO2/c1-6(2)5(7-3)8-4/h5H,1-4H3 |
| InChi Key | ZSXGLVDWWRXATF-UHFFFAOYSA-N |
| Canonical SMILES | CN(C)C(OC)OC |
| Isomeric SMILES | CN(C)C(OC)OC |
| WGK Germany | 2 |
| PubChem CID | 78373 |
| UN Number | 1993 |
| Molecular Weight | 119.16 |
| Beilstein | 506020 |
| Reaxy-Rn | 506020 |
Certificates
Certificate of Analysis(COA)
Enter Lot Number to search for COA:
Find and download the COA for your product by matching the lot number on the packaging.
| Lot Number | Certificate Type | Date | Item |
|---|---|---|---|
 K2211739 | Certificate of Analysis | Aug 22, 2024 | D106288 |
| K2211643 | Certificate of Analysis | Aug 22, 2024 | D106288 |
| H2430599 | Certificate of Analysis | Aug 20, 2024 | D106288 |
| H2430597 | Certificate of Analysis | Aug 20, 2024 | D106288 |
| G2417676 | Certificate of Analysis | Apr 24, 2024 | D106288 |
| G2417337 | Certificate of Analysis | Apr 24, 2024 | D106288 |
| G2417282 | Certificate of Analysis | Apr 24, 2024 | D106288 |
| F2411322 | Certificate of Analysis | Apr 24, 2024 | D106288 |
| C2202283 | Certificate of Analysis | Dec 11, 2023 | D106288 |
| G2310658 | Certificate of Analysis | Jun 14, 2023 | D106288 |
| G2310674 | Certificate of Analysis | Jun 14, 2023 | D106288 |
| G2310677 | Certificate of Analysis | Jun 14, 2023 | D106288 |
| G2310688 | Certificate of Analysis | Jun 14, 2023 | D106288 |
| G2310694 | Certificate of Analysis | Jun 14, 2023 | D106288 |
| G2310716 | Certificate of Analysis | Jun 14, 2023 | D106288 |
| G2310721 | Certificate of Analysis | Jun 14, 2023 | D106288 |
| A2408130 | Certificate of Analysis | Jun 14, 2023 | D106288 |
| H2125111 | Certificate of Analysis | May 15, 2023 | D106288 |
| G2107111 | Certificate of Analysis | Apr 13, 2023 | D106288 |
| F2126074 | Certificate of Analysis | Apr 11, 2023 | D106288 |
| F2126076 | Certificate of Analysis | Apr 11, 2023 | D106288 |
| K2211746 | Certificate of Analysis | Jul 25, 2022 | D106288 |
| K2211733 | Certificate of Analysis | Jul 25, 2022 | D106288 |
| F23081021 | Certificate of Analysis | Jul 25, 2022 | D106288 |
| D2313830 | Certificate of Analysis | Jul 25, 2022 | D106288 |
| C23311627 | Certificate of Analysis | Jul 25, 2022 | D106288 |
| B2322981 | Certificate of Analysis | Jul 25, 2022 | D106288 |
| H2020098 | Certificate of Analysis | Jun 17, 2022 | D106288 |
| H2020096 | Certificate of Analysis | Jun 17, 2022 | D106288 |
| C23311621 | Certificate of Analysis | Jan 22, 2022 | D106288 |
| C2202278 | Certificate of Analysis | Jan 22, 2022 | D106288 |
| F2126075 | Certificate of Analysis | Mar 29, 2021 | D106288 |
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Chemical and Physical Properties
| Solubility | Miscible with most organic solvents. |
|---|---|
| Sensitivity | Moisture sensitive. |
| Refractive Index | 1.3972 |
| Flash Point(°F) | 42.8 °F |
| Flash Point(°C) | 7℃ |
| Boil Point(°C) | 104-108°C |
| Melt Point(°C) | -85°C |
Safety and Hazards(GHS)
| Pictogram(s) | GHS05, GHS07, GHS02 |
|---|---|
| Signal | Danger |
| Hazard Statements | H315:Causes skin irritation H319:Causes serious eye irritation H335:May cause respiratory irritation H302:Harmful if swallowed H318:Causes serious eye damage H225:Highly Flammable liquid and vapor H317:May cause an allergic skin reaction H332:Harmful if inhaled |
| Precautionary Statements | P261:Avoid breathing dust/fume/gas/mist/vapors/spray. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing. P280:Wear protective gloves/protective clothing/eye protection/face protection. P370+P378:In case of fire: Use ... to extinguish. P210:Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking. P302+P352:IF ON SKIN: wash with plenty of water. P321:Specific treatment (see ... on this label). P405:Store locked up. P501:Dispose of contents/container to ... P233:Keep container tightly closed. P240:Ground/bond container and receiving equipment. P264:Wash hands [and …] thoroughly after handling. P403+P235:Store in a well-ventilated place. Keep cool. P303+P361+P353:IF ON SKIN (or hair): Take off Immediately all contaminated clothing. Rinse SKIN with water [or shower]. P271:Use only outdoors or in a well-ventilated area. P241:Use explosion-proof [electrical/ventilating/lighting/.../] equipment. P270:Do not eat, drink or smoke when using this product. P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing. P403+P233:Store in a well-ventilated place. Keep container tightly closed. P272:Contaminated work clothing should not be allowed out of the workplace. P333+P313:IF SKIN irritation or rash occurs: Get medical advice/attention. P362+P364:Take off contaminated clothing and wash it before reuse. P330:Rinse mouth. P242:Use only non-sparking tools. P243:Take precautionary measures against static discharge. P264+P265:Wash hands [and …] thoroughly after handling. Do not touch eyes. P301+P317:IF SWALLOWED: Get medical help. P305+P354+P338:IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. P317:Get emergency medical help. P337+P317:If eye irritation persists: Get medical help. P332+P317:If skin irritation occurs: Get medical help. P319:Get medical help if you feel unwell. |
| WGK Germany | 2 |
| Reaxy-Rn | 506020 |
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References
| 1. M F Grubb,P S Callery. (1989-05-19) Derivatization of N-methyl and cyclic amino acids with dimethylformamide dimethyl acetal.. Journal of chromatography, 469 (191-196). [PMID:2768368] |
| 2. C Rodier,C Laurent,C Szopa,R Sternberg,F Raulin. (2002-07-12) Chirality and the origin of life: in situ enantiomeric separation for future space missions.. Chirality, 14 ((6)): (527-532). [PMID:12112349] |
| 3. Wim Schepens,Dirk Van Haver,Maurits Vandewalle,Roger Bouillon,Annemieke Verstuyf,Pierre J De Clercq. (2006-09-08) Synthesis of spiro[4.5]decane CF-ring analogues of 1 alpha,25-dihydroxyvitamin D3.. Organic letters, 8 ((19)): (4247-4250). [PMID:16956198] |
| 4. Khadijah M Al-Zaydi,Rita M Borik. (2007-10-26) Microwave assisted condensation reactions of 2-aryl hydrazonopropanals with nucleophilic reagents and dimethyl acetylenedicarboxylate.. Molecules (Basel, Switzerland), 12 ((8)): (2061-2079). [PMID:17960106] |
| 5. Toshiaki Sasada,Norio Sakai,Takeo Konakahara. (2008-07-30) Me3SiCl-promoted three-component coupling reaction of a functionalized enamine, an acetal, and an alkyne: an unprecedented approach to the synthesis of tetrasubstituted pyridines via a [3 + 2 + 1] intermolecular cyclization.. The Journal of organic chemistry, 73 ((17)): (6905-6908). [PMID:18661946] |
| 6. Jie Hu,Yali Zhang,Lili Dong,Zhe Wang,Lingfeng Chen,Dandan Liang,Dengjian Shi,Xiaoou Shan,Guang Liang. (2014-10-21) Design, Synthesis, and Biological Evaluation of Novel Quinazoline Derivatives as Anti-inflammatory Agents against Lipopolysaccharide-induced Acute Lung Injury in Rats.. Chemical biology & drug design, 85 ((6)): (672-684). [PMID:25327896] |
| 7. R J Perchalski,B J Wilder. (1980-01-01) GLC analysis of carbamazepine.. Therapeutic drug monitoring, 2 ((3)): (289-289). [PMID:7222183] |
| 8. Qingfen Zhang,Vicki H Wysocki,Patricia Y Scaraffia,Michael A Wells. (2005-06-01) Fragmentation pathway for glutamine identification: loss of 73 Da from dimethylformamidine glutamine isobutyl ester.. Journal of the American Society for Mass Spectrometry, 16 ((7)): (1192-1203). [PMID:15922620] |
| 9. C Freissinet,A Buch,R Sternberg,C Szopa,C Geffroy-Rodier,C Jelinek,M Stambouli. (2009-12-29) Search for evidence of life in space: analysis of enantiomeric organic molecules by N,N-dimethylformamide dimethylacetal derivative dependant Gas Chromatography-Mass Spectrometry.. Journal of chromatography. A, 1217 ((5)): (731-740). [PMID:20036768] |
| 10. Anirban Sarkar,Sudipta Raha Roy,Dinesh Kumar,Chetna Madaan,Santosh Rudrawar,Asit K Chakraborti. (2011-11-08) Lack of correlation between catalytic efficiency and basicity of amines during the reaction of aryl methyl ketones with DMF-DMA: an unprecedented supramolecular domino catalysis.. Organic & biomolecular chemistry, 10 ((2)): (281-286). [PMID:22057389] |
| 11. Brad S Lambert,Kevin L Shimkus,James D Fluckey,Steven E Riechman,Nicholas P Greene,Jessica M Cardin,Stephen F Crouse. (2014-11-27) Anabolic responses to acute and chronic resistance exercise are enhanced when combined with aquatic treadmill exercise.. American journal of physiology. Endocrinology and metabolism, 308 ((3)): (E192-E200). [PMID:25425002] |