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O-(2,3,4,5,6-Pentafluorobenzyl)hydroxylamine hydrochloride - ≥98%, high purity , CAS No.57981-02-9

  • ≥98%
Item Number
P113762
Grouped product items
SKUSizeAvailabilityPrice Qty
P113762-250mg
250mg
In stock
$37.90
P113762-1g
1g
In stock
$115.90
P113762-5g
5g
In stock
$442.90
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Aromatic Ring Compounds Fluorinated Building Blocks Functional group compounds Hydroxylamines

Basic Description

Synonyms57981-02-9|O-(2,3,4,5,6-Pentafluorobenzyl)hydroxylamine hydrochloride|Florox Reagent|O-((Perfluorophenyl)methyl)hydroxylamine hydrochloride|O-[(2,3,4,5,6-pentafluorophenyl)methyl]hydroxylamine;hydrochloride|Hydroxylamine, O-[(pentafluorophenyl)methyl]-, h
Specifications & Purity≥98%
Storage TempArgon charged
Shipped InNormal
Product Description

for Oxime Preparation

Names and Identifiers

Pubchem Sid488187670
Pubchem Sid Urlhttps://pubchem.ncbi.nlm.nih.gov/substance/488187670
IUPAC Name O-[(2,3,4,5,6-pentafluorophenyl)methyl]hydroxylamine;hydrochloride
INCHI InChI=1S/C7H4F5NO.ClH/c8-3-2(1-14-13)4(9)6(11)7(12)5(3)10;/h1,13H2;1H
InChi Key HVMVKNXIMUCYJA-UHFFFAOYSA-N
Canonical SMILES C(C1=C(C(=C(C(=C1F)F)F)F)F)ON.Cl
Isomeric SMILES C(C1=C(C(=C(C(=C1F)F)F)F)F)ON.Cl
WGK Germany 3
PubChem CID 122307
Molecular Weight 249.57
Beilstein 4031190

Certificates

Certificate of Analysis(COA)

Enter Lot Number to search for COA:

To view the certificate results,please click on a Lot number.For Lot numbers from past orders,please use our order status section

13 results found

Lot NumberCertificate TypeDateItem
F2428354Certificate of AnalysisJun 19, 2024 P113762
F2428355Certificate of AnalysisJun 19, 2024 P113762
K2309514Certificate of AnalysisOct 31, 2023 P113762
K2309515Certificate of AnalysisOct 31, 2023 P113762
K2309516Certificate of AnalysisOct 31, 2023 P113762
K2309524Certificate of AnalysisOct 31, 2023 P113762
K2309525Certificate of AnalysisOct 31, 2023 P113762
K2309546Certificate of AnalysisOct 31, 2023 P113762
J1928171Certificate of AnalysisAug 04, 2023 P113762
D1523030Certificate of AnalysisDec 13, 2022 P113762
D2324737Certificate of AnalysisJun 05, 2022 P113762
G2215416Certificate of AnalysisJun 05, 2022 P113762
G2215420Certificate of AnalysisJun 05, 2022 P113762

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Chemical and Physical Properties

SolubilitySoluble in water
Melt Point(°C)212-218°C

Safety and Hazards(GHS)

Pictogram(s) GHS07
Signal Warning
Hazard Statements

H315:Causes skin irritation

H319:Causes serious eye irritation

H335:May cause respiratory irritation

Precautionary Statements

P261:Avoid breathing dust/fume/gas/mist/vapors/spray.

P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.

P280:Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352:IF ON SKIN: wash with plenty of water.

P321:Specific treatment (see ... on this label).

P405:Store locked up.

P501:Dispose of contents/container to ...

P264:Wash hands [and …] thoroughly after handling.

P271:Use only outdoors or in a well-ventilated area.

P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P403+P233:Store in a well-ventilated place. Keep container tightly closed.

P362+P364:Take off contaminated clothing and wash it before reuse.

P264+P265:Wash hands [and …] thoroughly after handling. Do not touch eyes.

P337+P317:If eye irritation persists: Get medical help.

P332+P317:If skin irritation occurs: Get medical help.

P319:Get medical help if you feel unwell.

WGK Germany 3

Related Documents

 SDS

 Specification Sheet

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  5. 2,3,4,5,6-Pentafluorobenzylzinc chloride solution
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  6. 2,3,4,5,6-Pentafluorobenzylzinc bromide solution
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References

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14. Elena Gómez Alvarez,Mónica Vázquez Moreno,Sasho Gligorovski,Henri Wortham,Miguel Valcárcel Cases.  (2012-01-24)  Characterisation and calibration of active sampling Solid Phase Microextraction applied to sensitive determination of gaseous carbonyls..  Talanta,  88  (252-258).  [PMID:22265495]
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18. K T Koshy,D G Kaiser,A L VanDerSlik.  (1975-02-01)  0-(2,3,4,5,6-pentafluorobenzyl)hydroxylamine hydrochloride as a sensitive derivatizing agent for the electron capture gas liquid chromatographic analysis of keto steroids..  Journal of chromatographic science,  13  ((2)): (97-104).  [PMID:1150849]
19. B A Gallasch,G Spiteller.  (2000-10-12)  Synthesis of 9,12-dioxo-10(Z)-dodecenoic acid, a new fatty acid metabolite derived from 9-hydroperoxy-10,12-octadecadienoic acid in lentil seed (Lens culinaris Medik.).  Lipids,  35  ((9)): (953-960).  [PMID:11026615]
20. S Strassnig,T Wenzl,E P Lankmayr.  (2000-10-24)  Microwave-assisted derivatization of volatile carbonyl compounds with O-(2,3,4,5,6-pentafluorobenzyl)hydroxylamine..  Journal of chromatography. A,  891  ((2)): (267-273).  [PMID:11043787]
21. P Spiteller,W Kern,J Reiner,G Spiteller.  (2001-04-28)  Aldehydic lipid peroxidation products derived from linoleic acid..  Biochimica et biophysica acta,  1531  ((3)): (188-208).  [PMID:11325611]
22. Petr Vesely,Lance Lusk,Gabriela Basarova,John Seabrooks,David Ryder.  (2003-11-13)  Analysis of aldehydes in beer using solid-phase microextraction with on-fiber derivatization and gas chromatography/mass spectrometry..  Journal of agricultural and food chemistry,  51  ((24)): (6941-6944).  [PMID:14611150]
23. T Gabrio,A Bertsch.  (2004-09-25)  Determination of carbonyl compounds in pool water with O-(2,3,4,5,6-pentafluorobenzyl)hydroxyamine hydrochloride and gas chromatographic-tandem mass spectrometric analysis..  Journal of chromatography. A,  1046  ((1-2)): (293-296).  [PMID:15387201]
24. Chunhui Deng,Ning Li,Xiaochuan Wang,Xiangmin Zhang,Jia Zeng.  (2005-02-09)  Rapid determination of acetone in human blood by derivatization with pentafluorobenzyl hydroxylamine followed by headspace liquid-phase microextraction and gas chromatography/mass spectrometry..  Rapid communications in mass spectrometry : RCM,  19  ((5)): (647-653).  [PMID:15700238]
25. Fabienne Reisen,Sara M Aschmann,Roger Atkinson,Janet Arey.  (2005-07-29)  1,4-hydroxycarbonyl products of the OH radical initiated reactions of C5-C8 n-alkanes in the presence of NO..  Environmental science & technology,  39  ((12)): (4447-4453).  [PMID:16047780]
26. Birgit Schulze,Ryan Lauchli,Mesmin Mekem Sonwa,Annika Schmidt,Wilhelm Boland.  (2005-11-26)  Profiling of structurally labile oxylipins in plants by in situ derivatization with pentafluorobenzyl hydroxylamine..  Analytical biochemistry,  348  ((2)): (269-283).  [PMID:16307716]
27. Riccardo Flamini,Antonio Dalla Vedova,Annarita Panighel,Nicola Perchiazzi,Stefano Ongarato.  (2005-12-02)  Monitoring of the principal carbonyl compounds involved in malolactic fermentation of wine by solid-phase microextraction and positive ion chemical ionization GC/MS analysis..  Journal of mass spectrometry : JMS,  40  ((12)): (1558-1564).  [PMID:16320303]
28. Vicente Ferreira,Laura Culleré,Natalia Loscos,Juan Cacho.  (2006-05-20)  Critical aspects of the determination of pentafluorobenzyl derivatives of aldehydes by gas chromatography with electron-capture or mass spectrometric detection: Validation of an optimized strategy for the determination of oxygen-related odor-active aldehydes in wine..  Journal of chromatography. A,  1122  ((1-2)): (255-265).  [PMID:16709416]
29. Julián Zapata,Laura Mateo-Vivaracho,Juan Cacho,Vicente Ferreira.  (2010-01-28)  Comparison of extraction techniques and mass spectrometric ionization modes in the analysis of wine volatile carbonyls..  Analytica chimica acta,  660  ((1-2)): (197-205).  [PMID:20103163]

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