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Oxotrichloro[(dimethylsulfide)triphenylphosphine oxide]rhenium(V) - 97%, high purity , CAS No.108695-90-5
Basic Description Specifications & Purity 97% Product Description Description
Catalyst for:Enantioselective reduction of ketones and iminesMeyer-Schuster rearrangement of propargylic alcohols to α, β-unsaturated carbonyl compoundsSynthesis of 2-deoxy-α glycosidesSulfurization of phosphorous(III) compounds with thiiranesReactant for synthesis of mono and dinuclear compoundsReagent for rhenium-cyclized somatostatine derivative series synthesis
Names and Identifiers INCHI 1S/C18H15OP.C2H6S.3ClH.O.Re/c19-20(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-3-2;;;;;/h1-15H;1-2H3;3*1H;;/q;;;;;;+3/p-3 InChi Key GIBDGLAUIKUJJX-UHFFFAOYSA-K Canonical SMILES CSC.Cl[Re](Cl)(Cl)=O.O=P(c1ccccc1)(c2ccccc2)c3ccccc3 Molecular Weight 648.98
Chemical and Physical Properties Flash Point(°F) Not applicable Flash Point(°C) Not applicable
Safety and Hazards(GHS) Pictogram(s) GHS07 Signal Warning Hazard Statements H315: Causes skin irritation
H319: Causes serious eye irritation
H335: May cause respiratory irritation
Precautionary Statements P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.
P302+P352: IF ON SKIN: wash with plenty of water.
RIDADR NONH for all modes of transport
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