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p-Toluenesulfonic Anhydride - >95.0%(T), high purity , CAS No.4124-41-8
Basic Description Synonyms p-Toluenesulfonic anhydride|4124-41-8|4-Methylbenzenesulfonic anhydride|4-Toluenesulfonic anhydride|(4-methylphenyl)sulfonyl 4-methylbenzenesulfonate|4-toluenesulfonic acid anhydride|p-toluene sulfonic anhydride|Toluene-p-sulphonic anhydride|Benzenesulfon Specifications & Purity >95.0%(T) Storage Temp Store at 2-8°C,Argon charged Shipped In Wet ice Product Description p-Toluenesulfonic anhydride acts as electrophilic species and activates 2-deoxy-sugar hemiacetals in situ, which reacts stereoselectively with nucleophilic acceptors to afford β-anomers. p-Toluenesulfonic anhydride has been employed as reagent in palladium-catalyzed allylic alkenylation of allylic alcohols with n-butyl acrylate.
Names and Identifiers IUPAC Name (4-methylphenyl)sulfonyl 4-methylbenzenesulfonate INCHI InChI=1S/C14H14O5S2/c1-11-3-7-13(8-4-11)20(15,16)19-21(17,18)14-9-5-12(2)6-10-14/h3-10H,1-2H3 InChi Key PDVFSPNIEOYOQL-UHFFFAOYSA-N Canonical SMILES CC1=CC=C(C=C1)S(=O)(=O)OS(=O)(=O)C2=CC=C(C=C2)C Isomeric SMILES CC1=CC=C(C=C1)S(=O)(=O)OS(=O)(=O)C2=CC=C(C=C2)C WGK Germany 3 PubChem CID 77773 Molecular Weight 326.38 Beilstein 2223700 Reaxy-Rn 2223702
Chemical and Physical Properties Sensitivity Moisture sensitive Melt Point(°C) 121-127°C
Safety and Hazards(GHS) Pictogram(s) GHS05 Signal Danger Hazard Statements H314: Causes severe skin burns and eye damage
Precautionary Statements P280: Wear protective gloves/protective clothing/eye protection/face protection.
P321: Specific treatment (see ... on this label).
P405: Store locked up.
P501: Dispose of contents/container to ...
P264: Wash hands [and …] thoroughly after handling.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P301+P330+P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P363: Wash contaminated clothing before reuse.
P305+P354+P338: IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing.
P302+P361+P354: IF ON SKIN: Take off Immediately all contaminated clothing. Immediately rinse with water for several minutes.
P316: Get emergency medical help immediately.
WGK Germany 3 Reaxy-Rn 2223702
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