| SKU | Size | Availability | Price | Qty |
|---|---|---|---|---|
| P485533-100mg | 100mg | Available within 8-12 weeks(?) Production requires sourcing of materials. We appreciate your patience and understanding. | $369.90 |
| Specifications & Purity | New Iridium, ≥97% |
|---|---|
| Legal Information | 专利申请PCT/US2016/058245。与New Iridium Inc.合作出售。如需大于25克的订单，请通过chern@newiridium.com与New Iridium联系，或访问https://www.newiridium.com。Phenox O-PC is a trademark of New Iridium LLC |
| Product Description | Description This phenoxazine-based organic photoredox catalyst (in addition to the dihydrophenazine catalyst901112) was designed to be a strong excited-state reductant and possesses advanced photophysical and electrochemical properties, enabling it to serve as a sustainable replacement for ruthenium- or iridium-based photoredox catalysts. For example, dihydrophenazine and phenoxazine derivatives were demonstrated to replace ruthenium or iridium complexes in the application of photoredox-catalyzed atom transfer radical polymerization (ATRP) for controlled polymer synthesis and small molecule transformations such as trifluoromethylation, atom transfer radical addition, and dual Nickel/photoredox catalyzed C-N and C-S cross-couplings. Dihydrophenazine- and phenoxazine-based organic photoredox catalysts were introduced in collaboration with theMiyakeResearch Group. |
| IUPAC Name | 10-naphthalen-1-yl-3,7-bis(4-phenylphenyl)phenoxazine |
|---|---|
| INCHI | InChI=1S/C46H31NO/c1-3-10-32(11-4-1)34-18-22-36(23-19-34)39-26-28-43-45(30-39)48-46-31-40(37-24-20-35(21-25-37)33-12-5-2-6-13-33)27-29-44(46)47(43)42-17-9-15-38-14-7-8-16-41(38)42/h1-31H |
| InChi Key | IGGSSEOAGCUGDJ-UHFFFAOYSA-N |
| Canonical SMILES | C1=CC=C(C=C1)C2=CC=C(C=C2)C3=CC4=C(C=C3)N(C5=C(O4)C=C(C=C5)C6=CC=C(C=C6)C7=CC=CC=C7)C8=CC=CC9=CC=CC=C98 |
| PubChem CID | 129057445 |
| Molecular Weight | 613.74 |
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| Flash Point(°F) | Not applicable |
|---|---|
| Flash Point(°C) | Not applicable |
| Melt Point(°C) | 171℃ |
| RIDADR | NONH for all modes of transport |
|---|
| 1. Sarah Z Tasker,Eric A Standley,Timothy F Jamison. (2014-05-16) Recent advances in homogeneous nickel catalysis.. Nature, 509 ((7500)): (299-309). [PMID:24828188] |
| 2. Jordan C Theriot,Chern-Hooi Lim,Haishen Yang,Matthew D Ryan,Charles B Musgrave,Garret M Miyake. (2016-04-02) Organocatalyzed atom transfer radical polymerization driven by visible light.. Science (New York, N.Y.), 352 ((6289)): (1082-1086). [PMID:27033549] |
| 3. Chern-Hooi Lim,Matthew D Ryan,Blaine G McCarthy,Jordan C Theriot,Steven M Sartor,Niels H Damrauer,Charles B Musgrave,Garret M Miyake. (2016-12-16) Intramolecular Charge Transfer and Ion Pairing in N,N-Diaryl Dihydrophenazine Photoredox Catalysts for Efficient Organocatalyzed Atom Transfer Radical Polymerization.. Journal of the American Chemical Society, 139 ((1)): (348-355). [PMID:27973788] |
| 4. Ryan M Pearson,Chern-Hooi Lim,Blaine G McCarthy,Charles B Musgrave,Garret M Miyake. (2016-08-25) Organocatalyzed Atom Transfer Radical Polymerization Using N-Aryl Phenoxazines as Photoredox Catalysts.. Journal of the American Chemical Society, 138 ((35)): (11399-11407). [PMID:27554292] |
| 5. Ya Du,Ryan M Pearson,Chern-Hooi Lim,Steven M Sartor,Matthew D Ryan,Haishen Yang,Niels H Damrauer,Garret M Miyake. (2017-06-28) Strongly Reducing, Visible-Light Organic Photoredox Catalysts as Sustainable Alternatives to Precious Metals.. Chemistry (Weinheim an der Bergstrasse, Germany), 23 ((46)): (10962-10968). [PMID:28654171] |
