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Pentaerythritol tetrakis (3,5-di-tert-butyl-4-hydroxyhydrocinnamate) - ≥95.0%(HPLC), high purity , CAS No.6683-19-8

21 Citations

≥95%(HPLC)

CAS#: 6683-19-8
Formula: C₇₃H₁₀₈O₁₂
Molecular Weight: 1177.66
MDL number: MFCD00059345
PubChem CID: 64819
PubChem SID: 488183643

Item Number

P136696

Grouped product items
SKU	Size	Availability	Price
P136696-25g	25g	In stock	$10.90
P136696-100g	100g	In stock	$29.90
P136696-500g	500g	In stock	$103.90

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Phenolics Polymer / polymer reagent

Basic Description

Synonyms	Tetraalkofen BPE \| Pentaerythritol tetrakis(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate) \| Tetrakis[methylene-3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate]methane \| 2,2-Bis(((3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoyl)oxy)methyl)propane-1,3-diy
Specifications & Purity	≥95%(HPLC)
Shipped In	Normal
Product Description	Pentaerythritol tetrakis(3,5-di-tert-butyl-4-hydroxyhydrocinnamate) (PT) is a sterically hindered phenolic antioxidant and a heat stabilizer mainly used to enhance the oxidative resistance and protection against the toxicity of solvents. It has a glass transition temperature of 50 ℃and can be annealed at room temperature. Application： PT can be used as an additive to protect biaxially-oriented propylene (BOPP) capacitor film from thermal oxidation on UV exposure. It can also be used as a standard material to study the gas-cluster ion sputtering (GCIS) using X-ray photoelectron microscopy (XPS) and Atomic force microscopy (AFM).

Names and Identifiers

Pubchem Sid	488183643
Pubchem Sid Url	https://pubchem.ncbi.nlm.nih.gov/substance/488183643
IUPAC Name	[3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate
INCHI	InChI=1S/C73H108O12/c1-65(2,3)49-33-45(34-50(61(49)78)66(4,5)6)25-29-57(74)82-41-73(42-83-58(75)30-26-46-35-51(67(7,8)9)62(79)52(36-46)68(10,11)12,43-84-59(76)31-27-47-37-53(69(13,14)15)63(80)54(38-47)70(16,17)18)44-85-60(77)32-28-48-39-55(71(19,20)21)64(81)56(40-48)72(22,23)24/h33-40,78-81H,25-32,41-44H2,1-24H3
InChi Key	BGYHLZZASRKEJE-UHFFFAOYSA-N
Canonical SMILES	CC(C)(C)C1=CC(=CC(=C1O)C(C)(C)C)CCC(=O)OCC(COC(=O)CCC2=CC(=C(C(=C2)C(C)(C)C)O)C(C)(C)C)(COC(=O)CCC3=CC(=C(C(=C3)C(C)(C)C)O)C(C)(C)C)COC(=O)CCC4=CC(=C(C(=C4)C(C)(C)C)O)C(C)(C)C
Isomeric SMILES	CC(C)(C)C1=CC(=CC(=C1O)C(C)(C)C)CCC(=O)OCC(COC(=O)CCC2=CC(=C(C(=C2)C(C)(C)C)O)C(C)(C)C)(COC(=O)CCC3=CC(=C(C(=C3)C(C)(C)C)O)C(C)(C)C)COC(=O)CCC4=CC(=C(C(=C4)C(C)(C)C)O)C(C)(C)C
RTECS	DA8340900
PubChem CID	64819
Molecular Weight	1177.66
Reaxy-Rn	2035465

Certificates

Certificate of Analysis(COA)

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16 results found

Lot Number	Certificate Type	Date	Item
I2409350	Certificate of Analysis	Aug 31, 2024	P136696
I2409351	Certificate of Analysis	Aug 31, 2024	P136696
F2302774	Certificate of Analysis	Jun 13, 2023	P136696
F2302775	Certificate of Analysis	Jun 13, 2023	P136696
F2302776	Certificate of Analysis	Jun 13, 2023	P136696
F2302777	Certificate of Analysis	Jun 13, 2023	P136696
F2302780	Certificate of Analysis	Jun 13, 2023	P136696
F2302781	Certificate of Analysis	Jun 13, 2023	P136696
F2302782	Certificate of Analysis	Jun 13, 2023	P136696
F2129325	Certificate of Analysis	Apr 14, 2023	P136696
F2129326	Certificate of Analysis	Apr 14, 2023	P136696
F2129327	Certificate of Analysis	Apr 14, 2023	P136696
K2010157	Certificate of Analysis	Sep 16, 2022	P136696
J2215434	Certificate of Analysis	Jul 25, 2022	P136696
J2215475	Certificate of Analysis	Jul 25, 2022	P136696
J2215477	Certificate of Analysis	Jul 25, 2022	P136696

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Chemical and Physical Properties

Solubility	Insoluble in water; Degree of Solubility in water: 0.3 g/l 20 °C; Soluble in Chloroform,Acetone,Toluene
Melt Point(°C)	113°C-120°C

Safety and Hazards(GHS)

Pictogram(s)	GHS07
Signal	Warning
Hazard Statements	H315:Causes skin irritation H412:Harmful to aquatic life with long lasting effects H302:Harmful if swallowed
RTECS	DA8340900
Reaxy-Rn	2035465

Citations of This Product

How to Cite Aladdin Scientific Products?

1. Chengpeng Zhang, Tianyi Zhou, Guozhang Gu, Chaoyi Cai, Dongdong Hao, Guoxiang Zou, Jinchun Li, Rong Yang. (2024) Super-tough poly(lactic acid)/silicone rubber thermoplastic vulcanizates: The organic and inorganic synergistic interfacial compatibilization. INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 258 (129110). [PMID:38161016] [10.1016/j.ijbiomac.2023.129110]
2. Yang Haoyu, Zhang Xiaoqi, Liu Yiming, Mao Lu, He Suqin, Huang Miaoming, Liu Hao, Xu Wanlin, Liu Wentao. (2024) Synthesis and comprehensive characterization of bio-based polyamide 56/6 Copolymer: Mechanical, Thermal, and processing properties. EUROPEAN POLYMER JOURNAL, 202 (5): (112593). [PMID:20444281] [10.1016/j.eurpolymj.2023.112593]
3. Junyi Lu, Hongyi Tu, Guangxin Gu. (2023) Synthesis of brominated flame retardants with different brominated structures and study on flame retardancy of polystyrene resin. REACTIVE & FUNCTIONAL POLYMERS, 193 (105769). [PMID:15685250] [10.1016/j.reactfunctpolym.2023.105769]
4. Qingyang Luan, Han Hu, Xiaoyu Jiang, Chen Lin, Xiaoqin Zhang, Qianfeng Wang, Yunxiao Dong, Jinggang Wang, Jin Zhu. (2023) Melt polycondensation of poly (butylene oxalate-co-succinate) with great potential in curbing marine plastic pollution. JOURNAL OF HAZARDOUS MATERIALS, 457 (131801). [PMID:37302185] [10.1016/j.jhazmat.2023.131801]
5. Jing Cao, Jingwen Zou, Siying Zheng, Na Wen, Weijie Xu, Yuying Zheng. (2023) Preparation of clay-supported sodium benzoate and its effect on the rheology, crystallization and foaming of long chain branched polypropylene. JOURNAL OF CELLULAR PLASTICS, [PMID:] [10.1177/0021955X231162187]
6. Jiacai Li, Zhicheng Si, Kai Shang, Yang Feng, Shihang Wang, Shengtao Li. (2023) Kinetic and thermodynamic investigation on diffusion-limited crosslinking reaction behaviors of peroxide-induced low-density polyethylene. POLYMER TESTING, 124 (108095). [PMID:] [10.1016/j.polymertesting.2023.108095]
7. Jiacai Li, Zhicheng Si, Shihang Wang, Shengtao Li, Hong Zhou, Jiajun Liu. (2023) Effect of hindered phenolic antioxidants on crosslinking characteristics of low-density polyethylene initiated by peroxide. Energy Reports, 9 (159). [PMID:] [10.1016/j.egyr.2023.04.275]
8. Zhen Zhou, Xiaoqing Wang, Xiaomeng Li, Chang Liu, Guoping Li, Yunjun Luo. (2023) Tribological and Mechanical Applications of Liquid-Crystal-Polymer-Modified Carbon-Fiber-Reinforced Polyamide–Polyurethane Composites. Polymers, 15 (9): (2033). [PMID:37177180] [10.3390/polym15092033]
9. Hui Fang, Guifeng Li, Kai Wang, Fangjuan Wu. (2023) Significant Improvement of Thermal Conductivity of Polyamide 6/Boron Nitride Composites by Adding a Small Amount of Stearic Acid. Polymers, 15 (8): (1887). [PMID:37112035] [10.3390/polym15081887]
10. Yi Cui, Yang Sui, Peng Wei, Yinan Lv, Chuanbo Cong, Xiaoyu Meng, Hai-Mu Ye, Qiong Zhou. (2023) Rationalizing the Dependence of Poly (Vinylidene Difluoride) (PVDF) Rheological Performance on the Nano-Silica. Nanomaterials, 13 (6): (1096). [PMID:36985990] [10.3390/nano13061096]
11. Zhehong Lu, Yubing Hu, Tengyue Zhang, Hao Li, Haoran Bai, Guangpu Zhang, Fan Guo, Wei Jiang. (2022) Preparation and anti-migration performance of ethylene propylene diene terpolymer composites modified with GO-SiO2 hybrid nanomaterials. JOURNAL OF APPLIED POLYMER SCIENCE, 140 (3): (e53341). [PMID:] [10.1002/app.53341]
12. Yi Zhuwu, Liu Yuejun, Liu Xiaochao, Fan Shuhong, Yang Jian, Mao Long, Lin Xintu, Peng Simei, zheng Wei. (2023) Biaxially stretched polyamide 6/ethylene vinyl alcohol copolymer films with improved oxygen barrier and mechanical properties. POLYMER BULLETIN, 80 (3): (3085-3101). [PMID:] [10.1007/s00289-022-04199-x]
13. Rong Yang, Guozhang Gu, Chen Tang, Zhicheng Miao, Hongwei Cao, Guoxiang Zou, Jinchun Li. (2022) Super-tough and flame-retardant poly(lactic acid) materials using a phosphorus-containing malic acid-based copolyester by reactive blending. POLYMER DEGRADATION AND STABILITY, 198 (109889). [PMID:] [10.1016/j.polymdegradstab.2022.109889]
14. Yanru Chen, Linbo Wu, Bo-Geng Li. (2021) Poly(1,5-pentylene-co-2,2,4,4-tetramethyl cyclobutylene terephthalate) copolyesters with high Tg and improved ductility and thermal stability. POLYMER, 232 (124152). [PMID:] [10.1016/j.polymer.2021.124152]
15. Guozhang Wu, Yuanbiao Liu, Gaopeng Shi. (2021) New Experimental Evidence for Thermodynamic Links to the Kinetic Fragility of Glass-Forming Polymers. MACROMOLECULES, 54 (12): (5595–5606). [PMID:] [10.1021/acs.macromol.1c00670]
16. Huimin Xia, Kun Sui, Tengteng Ge, Fazong Wu, Qiqi Sun, Zhongwei Wang, Liang Song, Xiaowen Huang, Qing Yu. (2020) Natural compounds from Punica granatum peel as multiple stabilizers for polyethylene. POLYMER ENGINEERING AND SCIENCE, 60 (11): (2761-2769). [PMID:] [10.1002/pen.25506]
17. Meng Yang, Weizhi Zou, Jing Guo, Zhenchao Qian, Heng Luo, Shijia Yang, Ning Zhao, Lorenzo Pattelli, Jian Xu, Diederik S. Wiersma. (2020) Bioinspired “Skin” with Cooperative Thermo-Optical Effect for Daytime Radiative Cooling. ACS Applied Materials & Interfaces, 12 (22): (25286–25293). [PMID:32378874] [10.1021/acsami.0c03897]
18. Huang Chongxing, Dang Xiujie, Bei Ronghua, Zhao Yuan, Li Cuicui, Chen Qiang, Wang Shuangfei. (2019) Effect of SiOx layer on preventing the migration of plasticizer and antioxidant from polyethylene terephthalate films. IRANIAN POLYMER JOURNAL, 28 (2): (173-182). [PMID:] [10.1007/s13726-019-00688-5]
19. Zhou Xie, Yiting Xu, Yihu Song, Qiang Zheng. (2018) Influence of annealing time on linear rheology and morphology of silica filled polyisoprene rubber and ethylene-propylene rubber. JOURNAL OF APPLIED POLYMER SCIENCE, 135 (35): (46679). [PMID:] [10.1002/app.46679]
20. Fei Liu, Junwu Zhang, Jinggang Wang, Haining Na, Jin Zhu. (2015) Incorporation of 1,4-cyclohexanedicarboxylic acid into poly(butylene terephthalate)-b-poly(tetramethylene glycol) to alter thermal properties without compromising tensile and elastic properties. RSC Advances, 5 (114): (94091-94098). [PMID:] [10.1039/C5RA18389H]
21. Zhang Jun-wu, Liu Fei, Wang Jing-gang, Na Hai-ning, Zhu Jin. (2015) Synthesis of poly(butylene terephthalate)-poly(tetramethylene glycol) copolymers using terephthalic acid as starting material: A comparation between two synthetic strategies. CHINESE JOURNAL OF POLYMER SCIENCE, 33 (9): (1283-1293). [PMID:] [10.1007/s10118-015-1673-4]

References

1. Chengpeng Zhang, Tianyi Zhou, Guozhang Gu, Chaoyi Cai, Dongdong Hao, Guoxiang Zou, Jinchun Li, Rong Yang. (2024) Super-tough poly(lactic acid)/silicone rubber thermoplastic vulcanizates: The organic and inorganic synergistic interfacial compatibilization. INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 258 (129110). [PMID:38161016] [10.1016/j.ijbiomac.2023.129110]
2. Yang Haoyu, Zhang Xiaoqi, Liu Yiming, Mao Lu, He Suqin, Huang Miaoming, Liu Hao, Xu Wanlin, Liu Wentao. (2024) Synthesis and comprehensive characterization of bio-based polyamide 56/6 Copolymer: Mechanical, Thermal, and processing properties. EUROPEAN POLYMER JOURNAL, 202 (5): (112593). [PMID:20444281] [10.1016/j.eurpolymj.2023.112593]
3. Junyi Lu, Hongyi Tu, Guangxin Gu. (2023) Synthesis of brominated flame retardants with different brominated structures and study on flame retardancy of polystyrene resin. REACTIVE & FUNCTIONAL POLYMERS, 193 (105769). [PMID:15685250] [10.1016/j.reactfunctpolym.2023.105769]
4. Qingyang Luan, Han Hu, Xiaoyu Jiang, Chen Lin, Xiaoqin Zhang, Qianfeng Wang, Yunxiao Dong, Jinggang Wang, Jin Zhu. (2023) Melt polycondensation of poly (butylene oxalate-co-succinate) with great potential in curbing marine plastic pollution. JOURNAL OF HAZARDOUS MATERIALS, 457 (131801). [PMID:37302185] [10.1016/j.jhazmat.2023.131801]
5. Jing Cao, Jingwen Zou, Siying Zheng, Na Wen, Weijie Xu, Yuying Zheng. (2023) Preparation of clay-supported sodium benzoate and its effect on the rheology, crystallization and foaming of long chain branched polypropylene. JOURNAL OF CELLULAR PLASTICS, [PMID:] [10.1177/0021955X231162187]
6. Jiacai Li, Zhicheng Si, Kai Shang, Yang Feng, Shihang Wang, Shengtao Li. (2023) Kinetic and thermodynamic investigation on diffusion-limited crosslinking reaction behaviors of peroxide-induced low-density polyethylene. POLYMER TESTING, 124 (108095). [PMID:] [10.1016/j.polymertesting.2023.108095]
7. Jiacai Li, Zhicheng Si, Shihang Wang, Shengtao Li, Hong Zhou, Jiajun Liu. (2023) Effect of hindered phenolic antioxidants on crosslinking characteristics of low-density polyethylene initiated by peroxide. Energy Reports, 9 (159). [PMID:] [10.1016/j.egyr.2023.04.275]
8. Zhen Zhou, Xiaoqing Wang, Xiaomeng Li, Chang Liu, Guoping Li, Yunjun Luo. (2023) Tribological and Mechanical Applications of Liquid-Crystal-Polymer-Modified Carbon-Fiber-Reinforced Polyamide–Polyurethane Composites. Polymers, 15 (9): (2033). [PMID:37177180] [10.3390/polym15092033]
9. Hui Fang, Guifeng Li, Kai Wang, Fangjuan Wu. (2023) Significant Improvement of Thermal Conductivity of Polyamide 6/Boron Nitride Composites by Adding a Small Amount of Stearic Acid. Polymers, 15 (8): (1887). [PMID:37112035] [10.3390/polym15081887]
10. Yi Cui, Yang Sui, Peng Wei, Yinan Lv, Chuanbo Cong, Xiaoyu Meng, Hai-Mu Ye, Qiong Zhou. (2023) Rationalizing the Dependence of Poly (Vinylidene Difluoride) (PVDF) Rheological Performance on the Nano-Silica. Nanomaterials, 13 (6): (1096). [PMID:36985990] [10.3390/nano13061096]
11. Zhehong Lu, Yubing Hu, Tengyue Zhang, Hao Li, Haoran Bai, Guangpu Zhang, Fan Guo, Wei Jiang. (2022) Preparation and anti-migration performance of ethylene propylene diene terpolymer composites modified with GO-SiO2 hybrid nanomaterials. JOURNAL OF APPLIED POLYMER SCIENCE, 140 (3): (e53341). [PMID:] [10.1002/app.53341]
12. Yi Zhuwu, Liu Yuejun, Liu Xiaochao, Fan Shuhong, Yang Jian, Mao Long, Lin Xintu, Peng Simei, zheng Wei. (2023) Biaxially stretched polyamide 6/ethylene vinyl alcohol copolymer films with improved oxygen barrier and mechanical properties. POLYMER BULLETIN, 80 (3): (3085-3101). [PMID:] [10.1007/s00289-022-04199-x]
13. Rong Yang, Guozhang Gu, Chen Tang, Zhicheng Miao, Hongwei Cao, Guoxiang Zou, Jinchun Li. (2022) Super-tough and flame-retardant poly(lactic acid) materials using a phosphorus-containing malic acid-based copolyester by reactive blending. POLYMER DEGRADATION AND STABILITY, 198 (109889). [PMID:] [10.1016/j.polymdegradstab.2022.109889]
14. Yanru Chen, Linbo Wu, Bo-Geng Li. (2021) Poly(1,5-pentylene-co-2,2,4,4-tetramethyl cyclobutylene terephthalate) copolyesters with high Tg and improved ductility and thermal stability. POLYMER, 232 (124152). [PMID:] [10.1016/j.polymer.2021.124152]
15. Guozhang Wu, Yuanbiao Liu, Gaopeng Shi. (2021) New Experimental Evidence for Thermodynamic Links to the Kinetic Fragility of Glass-Forming Polymers. MACROMOLECULES, 54 (12): (5595–5606). [PMID:] [10.1021/acs.macromol.1c00670]
16. Huimin Xia, Kun Sui, Tengteng Ge, Fazong Wu, Qiqi Sun, Zhongwei Wang, Liang Song, Xiaowen Huang, Qing Yu. (2020) Natural compounds from Punica granatum peel as multiple stabilizers for polyethylene. POLYMER ENGINEERING AND SCIENCE, 60 (11): (2761-2769). [PMID:] [10.1002/pen.25506]
17. Meng Yang, Weizhi Zou, Jing Guo, Zhenchao Qian, Heng Luo, Shijia Yang, Ning Zhao, Lorenzo Pattelli, Jian Xu, Diederik S. Wiersma. (2020) Bioinspired “Skin” with Cooperative Thermo-Optical Effect for Daytime Radiative Cooling. ACS Applied Materials & Interfaces, 12 (22): (25286–25293). [PMID:32378874] [10.1021/acsami.0c03897]
18. Huang Chongxing, Dang Xiujie, Bei Ronghua, Zhao Yuan, Li Cuicui, Chen Qiang, Wang Shuangfei. (2019) Effect of SiOx layer on preventing the migration of plasticizer and antioxidant from polyethylene terephthalate films. IRANIAN POLYMER JOURNAL, 28 (2): (173-182). [PMID:] [10.1007/s13726-019-00688-5]
19. Zhou Xie, Yiting Xu, Yihu Song, Qiang Zheng. (2018) Influence of annealing time on linear rheology and morphology of silica filled polyisoprene rubber and ethylene-propylene rubber. JOURNAL OF APPLIED POLYMER SCIENCE, 135 (35): (46679). [PMID:] [10.1002/app.46679]
20. Fei Liu, Junwu Zhang, Jinggang Wang, Haining Na, Jin Zhu. (2015) Incorporation of 1,4-cyclohexanedicarboxylic acid into poly(butylene terephthalate)-b-poly(tetramethylene glycol) to alter thermal properties without compromising tensile and elastic properties. RSC Advances, 5 (114): (94091-94098). [PMID:] [10.1039/C5RA18389H]
21. Zhang Jun-wu, Liu Fei, Wang Jing-gang, Na Hai-ning, Zhu Jin. (2015) Synthesis of poly(butylene terephthalate)-poly(tetramethylene glycol) copolymers using terephthalic acid as starting material: A comparation between two synthetic strategies. CHINESE JOURNAL OF POLYMER SCIENCE, 33 (9): (1283-1293). [PMID:] [10.1007/s10118-015-1673-4]

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