Grouped product items

SKU

Size

Availability

Price

Qty

P124122-100mg

100mg

Available within 4-8 weeks(?)

$1,081.90

P124122-250mg

250mg

Available within 4-8 weeks(?)

$1,853.90

P124122-500mg

500mg

Available within 4-8 weeks(?)

$3,604.90

P124122-1g

Available within 4-8 weeks(?)

$5,149.90

Basic Description

Synonyms	Chiralyst P618
Specifications & Purity	≥99%
Legal Information	Product of Umicore
Storage Temp	Argon charged
Shipped In	Normal
Product Description	Catalyst for: Oxidative olefination reactions C-C bond cleavage of secondary alcohols Ortho C-H olefination of phenol derivatives Oxidative annulation of pyridines Oxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2 C-H bond Amidation reactions Reductive alkylation reactions Product class M-C, Homogeneous Catalysts, Arene/Aryl Ligands Reaction type Hydrogenation, CH-Activation, Transfer Hydrogenation, Oxidation Chemical properties Chemical formula C20H30Cl4Rh2 Empirical formula [Rh(C5Me5)Cl2]2 Molecular weight 618.08 Metal Rh Theoretical metal content 33 Physical state crystalline Color red

Names and Identifiers

INCHI	1S/2C10H15.4ClH.2Rh/c21-6-7(2)9(4)10(5)8(6)3;;;;;;/h21-5H3;41H;;/q;;;;;;2+2/p-4
InChi Key	QNIVKTTWBMFSBR-UHFFFAOYSA-J
Canonical SMILES	Cl[Rh]Cl.Cl[Rh]Cl.C[C]1[C](C)[C](C)[C](C)[C]1C.C[C]2[C](C)[C](C)[C](C)[C]2C
WGK Germany	3
Molecular Weight	618.08

Certificates

Certificate of Analysis(COA)

Enter Lot Number to search for COA:

Find and download the COA for your product by matching the lot number on the packaging.

7 results found

Lot Number	Certificate Type	Date	Item
L1827081	Certificate of Analysis	Oct 18, 2022	P124122
F2216190	Certificate of Analysis	Feb 21, 2022	P124122
F2216191	Certificate of Analysis	Feb 21, 2022	P124122
F2216192	Certificate of Analysis	Feb 21, 2022	P124122
F2421031	Certificate of Analysis	Sep 15, 2021	P124122
L2320108	Certificate of Analysis	Sep 15, 2021	P124122
L2320142	Certificate of Analysis	Sep 15, 2021	P124122

Chemical and Physical Properties

Solubility	Soluble in chloroform and acetone. Slightly soluble in tetrahydrofuran and methanol. Insoluble in water and diethylether
Sensitivity	Air and moisture sensitive
Melt Point(°C)	>300°C

Safety and Hazards(GHS)

Pictogram(s)	GHS07
Signal	Warning
Hazard Statements	H315:Causes skin irritation H319:Causes serious eye irritation H335:May cause respiratory irritation H302+H312+H332:Harmful if swallowed, in contact with skin or if inhaled
Precautionary Statements	P261:Avoid breathing dust/fume/gas/mist/vapors/spray. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing. P280:Wear protective gloves/protective clothing/eye protection/face protection. P501:Dispose of contents/container to ... P312:Call a POISON CENTER or doctor/... if you feel unwell. P264:Wash hands [and …] thoroughly after handling. P271:Use only outdoors or in a well-ventilated area. P270:Do not eat, drink or smoke when using this product. P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing. P337+P313:IF eye irritation persists: Get medical advice/attention. P362+P364:Take off contaminated clothing and wash it before reuse. P332+P313:IF SKIN irritation occurs: Get medical advice/attention. P301+P312:IF SWALLOWED: call a POISON CENTER/doctor/... IF you feel unwell. P301+P312+P330:IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. Rinse mouth. P302+P352+P312:IF ON SKIN: Wash with plenty of water.Call a POISON CENTER/ doctor if you feel unwell. P304+P340+P312: IF INHALED: Remove person to fresh air and keep comfortable for breathing.Call a POISON CENTER or doctor. if you feel unwell.
WGK Germany	3

Citations of This Product

How to Cite Aladdin Scientific Products?

1. Ying Zhang, Bin Wei, Hao Liang. (2023) Rhodium-Based MOF-on-MOF Difunctional Core–Shell Nanoreactor for NAD(P)H Regeneration and Enzyme Directed Immobilization. ACS Applied Materials & Interfaces, 15 (2): (3442–3454). [PMID:36609187] [10.1021/acsami.2c18440]
2. Jie Xiang, Junyi Zhang, Shunmei Li, Ruo Yuan, Yun Xiang. (2022) Aptamer-based and sensitive label-free colorimetric sensing of phenylalanine via cascaded signal amplifications. ANALYTICA CHIMICA ACTA, 1230 (340393). [PMID:36192064] [10.1016/j.aca.2022.340393]
3. Xiewen Wu, Song Wang, Jing Fang, Hui Chen, Hongbo Liu, Run Li. (2022) Enhanced Photocatalytic Efficiency in Visible-Light-Induced NADH Regeneration by Intramolecular Electron Transfer. ACS Applied Materials & Interfaces, 14 (34): (38895–38904). [PMID:35986690] [10.1021/acsami.2c11174]
4. Yuanyuan Zhang, Jian Liu. (2022) Bioinspired Photocatalytic NADH Regeneration by Covalently Metalated Carbon Nitride for Enhanced CO2 Reduction. CHEMISTRY-A EUROPEAN JOURNAL, 28 (55): (e202201430). [PMID:35758216] [10.1002/chem.202201430]
5. Fang Lan, Qin Wang, Hui Chen, Yi Chen, Yuanyuan Zhang, Bowen Huang, Hongbo Liu, Jian Liu, Run Li. (2020) Preparation of Hydrophilic Conjugated Microporous Polymers for Efficient Visible Light-Driven Nicotinamide Adenine Dinucleotide Regeneration and Photobiocatalytic Formaldehyde Reduction. ACS Catalysis, 10 (21): (12976–12986). [PMID:] [10.1021/acscatal.0c03652]
6. Yizhou Wu, Jesse Ward-Bond, Donglin Li, Shaohua Zhang, Jiafu Shi, Zhongyi Jiang. (2018) g-C3N4@α-Fe2O3/C Photocatalysts: Synergistically Intensified Charge Generation and Charge Transfer for NADH Regeneration. ACS Catalysis, 8 (7): (5664–5674). [PMID:] [10.1021/acscatal.8b00070]

References

1. Ying Zhang, Bin Wei, Hao Liang. (2023) Rhodium-Based MOF-on-MOF Difunctional Core–Shell Nanoreactor for NAD(P)H Regeneration and Enzyme Directed Immobilization. ACS Applied Materials & Interfaces, 15 (2): (3442–3454). [PMID:36609187] [10.1021/acsami.2c18440]
2. Jie Xiang, Junyi Zhang, Shunmei Li, Ruo Yuan, Yun Xiang. (2022) Aptamer-based and sensitive label-free colorimetric sensing of phenylalanine via cascaded signal amplifications. ANALYTICA CHIMICA ACTA, 1230 (340393). [PMID:36192064] [10.1016/j.aca.2022.340393]
3. Xiewen Wu, Song Wang, Jing Fang, Hui Chen, Hongbo Liu, Run Li. (2022) Enhanced Photocatalytic Efficiency in Visible-Light-Induced NADH Regeneration by Intramolecular Electron Transfer. ACS Applied Materials & Interfaces, 14 (34): (38895–38904). [PMID:35986690] [10.1021/acsami.2c11174]
4. Yuanyuan Zhang, Jian Liu. (2022) Bioinspired Photocatalytic NADH Regeneration by Covalently Metalated Carbon Nitride for Enhanced CO2 Reduction. CHEMISTRY-A EUROPEAN JOURNAL, 28 (55): (e202201430). [PMID:35758216] [10.1002/chem.202201430]
5. Fang Lan, Qin Wang, Hui Chen, Yi Chen, Yuanyuan Zhang, Bowen Huang, Hongbo Liu, Jian Liu, Run Li. (2020) Preparation of Hydrophilic Conjugated Microporous Polymers for Efficient Visible Light-Driven Nicotinamide Adenine Dinucleotide Regeneration and Photobiocatalytic Formaldehyde Reduction. ACS Catalysis, 10 (21): (12976–12986). [PMID:] [10.1021/acscatal.0c03652]
6. Yizhou Wu, Jesse Ward-Bond, Donglin Li, Shaohua Zhang, Jiafu Shi, Zhongyi Jiang. (2018) g-C3N4@α-Fe2O3/C Photocatalysts: Synergistically Intensified Charge Generation and Charge Transfer for NADH Regeneration. ACS Catalysis, 8 (7): (5664–5674). [PMID:] [10.1021/acscatal.8b00070]

Solution Calculators

Molarity Calculator

Determine the necessary mass, volume, or concentration for preparing a solution.

Dilution Calculator

Determine the dilution needed to prepare a stock solution.

Pentamethylcyclopentadienylrhodium(III) chloride dimer - 99%, high purity , CAS No.12354-85-7

Basic Description

Names and Identifiers

Certificates

Certificate of Analysis(COA)

Chemical and Physical Properties

Safety and Hazards(GHS)

Related Documents

Citations of This Product

References

Solution Calculators

Molarity Calculator

Dilution Calculator

Reconstitution Calculator

SKU	Size	Availability	Price
P124122-100mg	100mg	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$1,081.90
P124122-250mg	250mg	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$1,853.90
P124122-500mg	500mg	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$3,604.90
P124122-1g	1g	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$5,149.90