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Pentamethylcyclopentadienylrhodium(III) chloride dimer - 99.95% metals basis, high purity , CAS No.12354-85-7 4 Citations
Discover Pentamethylcyclopentadienylrhodium(III) chloride dimer by Aladdin Scientific in 99.95% metals basis for only $219.90. Available - in Ligands at Aladdin Scientific. Tags: .
Basic Description Synonyms Chiralyst P618 Specifications & Purity 99.95% metals basis Legal Information Product of Umicore Storage Temp Room temperature,Argon charged Shipped In Normal Product Description Catalyst for: Oxidative olefination reactions C-C bond cleavage of secondary alcohols Ortho C-H olefination of phenol derivatives Oxidative annulation of pyridines Oxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2 C-H bond Amidation reactions Reductive alkylation reactions
Product class
Reaction type
Chemical properties
Theoretical metal content
Names and Identifiers INCHI 1S/2C10H15.4ClH.2Rh/c2*1-6-7(2)9(4)10(5)8(6)3;;;;;;/h2*1-5H3;4*1H;;/q;;;;;;2*+2/p-4 InChi Key QNIVKTTWBMFSBR-UHFFFAOYSA-J Canonical SMILES Cl[Rh]Cl.Cl[Rh]Cl.C[C]1[C](C)[C](C)[C](C)[C]1C.C[C]2[C](C)[C](C)[C](C)[C]2C WGK Germany 3 Molecular Weight 618.08
Chemical and Physical Properties Solubility Soluble in chloroform and acetone. Slightly soluble in tetrahydrofuran and methanol. Insoluble in water and diethylether Sensitivity Air and moisture sensitive Melt Point(°C) >300°C
Safety and Hazards(GHS) Pictogram(s) GHS07 Signal Warning Hazard Statements H315: Causes skin irritation
H319: Causes serious eye irritation
H335: May cause respiratory irritation
H302+H312+H332: Harmful if swallowed, in contact with skin or if inhaled
Precautionary Statements P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P501: Dispose of contents/container to ...
P312: Call a POISON CENTER or doctor/... if you feel unwell.
P264: Wash hands [and …] thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P270: Do not eat, drink or smoke when using this product.
P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P337+P313: IF eye irritation persists: Get medical advice/attention.
P362+P364: Take off contaminated clothing and wash it before reuse.
P332+P313: IF SKIN irritation occurs: Get medical advice/attention.
P301+P312: IF SWALLOWED: call a POISON CENTER/doctor/... IF you feel unwell.
P301+P312+P330: IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. Rinse mouth.
P302+P352+P312: IF ON SKIN: Wash with plenty of water.Call a POISON CENTER/ doctor if you feel unwell.
P304+P340+P312: IF INHALED: Remove person to fresh air and keep comfortable for breathing.Call a POISON CENTER or doctor. if you feel unwell.
WGK Germany 3
Citations of This Product 1. Ying Zhang, Bin Wei, Hao Liang. (2023) Rhodium-Based MOF-on-MOF Difunctional Core–Shell Nanoreactor for NAD(P)H Regeneration and Enzyme Directed Immobilization. ACS Applied Materials & Interfaces, 15 (2): (3442–3454). [PMID:36609187 ] 2. Jie Xiang, Junyi Zhang, Shunmei Li, Ruo Yuan, Yun Xiang. (2022) Aptamer-based and sensitive label-free colorimetric sensing of phenylalanine via cascaded signal amplifications. ANALYTICA CHIMICA ACTA, 1230 (340393). [PMID:36192064 ] 3. Xiewen Wu, Song Wang, Jing Fang, Hui Chen, Hongbo Liu, Run Li. (2022) Enhanced Photocatalytic Efficiency in Visible-Light-Induced NADH Regeneration by Intramolecular Electron Transfer. ACS Applied Materials & Interfaces, 14 (34): (38895–38904). [PMID:35986690 ] 4. Yuanyuan Zhang, Jian Liu. (2022) Bioinspired Photocatalytic NADH Regeneration by Covalently Metalated Carbon Nitride for Enhanced CO2 Reduction. CHEMISTRY-A EUROPEAN JOURNAL, 28 (55): (e202201430). [PMID:35758216 ]
References 1. Ying Zhang, Bin Wei, Hao Liang. (2023) Rhodium-Based MOF-on-MOF Difunctional Core–Shell Nanoreactor for NAD(P)H Regeneration and Enzyme Directed Immobilization. ACS Applied Materials & Interfaces, 15 (2): (3442–3454). [PMID:36609187 ] 2. Jie Xiang, Junyi Zhang, Shunmei Li, Ruo Yuan, Yun Xiang. (2022) Aptamer-based and sensitive label-free colorimetric sensing of phenylalanine via cascaded signal amplifications. ANALYTICA CHIMICA ACTA, 1230 (340393). [PMID:36192064 ] 3. Xiewen Wu, Song Wang, Jing Fang, Hui Chen, Hongbo Liu, Run Li. (2022) Enhanced Photocatalytic Efficiency in Visible-Light-Induced NADH Regeneration by Intramolecular Electron Transfer. ACS Applied Materials & Interfaces, 14 (34): (38895–38904). [PMID:35986690 ] 4. Yuanyuan Zhang, Jian Liu. (2022) Bioinspired Photocatalytic NADH Regeneration by Covalently Metalated Carbon Nitride for Enhanced CO2 Reduction. CHEMISTRY-A EUROPEAN JOURNAL, 28 (55): (e202201430). [PMID:35758216 ]
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