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Pentamethylcyclopentadienylrhodium(III) chloride dimer - 97%, high purity , CAS No.12354-85-7
Basic Description Specifications & Purity ≥97% Product Description Description
Pentamethylcyclopentadienylrhodium(III) chloride dimer can be used as a catalyst for:Oxidative olefination reactionsC-C bond cleavage of secondary alcoholsOrtho C-H olefination of phenol derivativesOxidative annulation of pyridinesOxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2C-H bondAmidation reactionsReductive alkylation reactionsUmicore Precatalysts for Asymmetric and Cross-Coupling CatalysisCatalyst for:Oxidative olefination reactionsC-C bond cleavage of secondary alcoholsOrtho C-H olefination of phenol derivativesOxidative annulation of pyridinesOxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2C-H bondAmidation reactionsReductive alkylation reactions
Names and Identifiers INCHI 1S/2C10H15.4ClH.2Rh/c2*1-6-7(2)9(4)10(5)8(6)3;;;;;;/h2*1-5H3;4*1H;;/q;;;;;;2*+2/p-4 InChi Key QNIVKTTWBMFSBR-UHFFFAOYSA-J Canonical SMILES Cl[Rh]Cl.Cl[Rh]Cl.C[C]1[C](C)[C](C)[C](C)[C]1C.C[C]2[C](C)[C](C)[C](C)[C]2C WGK Germany 3 Molecular Weight 618.08
Chemical and Physical Properties Safety and Hazards(GHS) Pictogram(s) GHS07 Signal Warning Hazard Statements H315: Causes skin irritation
H319: Causes serious eye irritation
H335: May cause respiratory irritation
H302+H312+H332: Harmful if swallowed, in contact with skin or if inhaled
Precautionary Statements P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P501: Dispose of contents/container to ...
P312: Call a POISON CENTER or doctor/... if you feel unwell.
P264: Wash hands [and …] thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P270: Do not eat, drink or smoke when using this product.
P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P337+P313: IF eye irritation persists: Get medical advice/attention.
P362+P364: Take off contaminated clothing and wash it before reuse.
P332+P313: IF SKIN irritation occurs: Get medical advice/attention.
P301+P312: IF SWALLOWED: call a POISON CENTER/doctor/... IF you feel unwell.
P301+P312+P330: IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. Rinse mouth.
P302+P352+P312: IF ON SKIN: Wash with plenty of water.Call a POISON CENTER/ doctor if you feel unwell.
P304+P340+P312: IF INHALED: Remove person to fresh air and keep comfortable for breathing.Call a POISON CENTER or doctor. if you feel unwell.
WGK Germany 3
Citations of This Product 1. Ying Zhang, Bin Wei, Hao Liang. (2023) Rhodium-Based MOF-on-MOF Difunctional Core–Shell Nanoreactor for NAD(P)H Regeneration and Enzyme Directed Immobilization. ACS Applied Materials & Interfaces, 15 (2): (3442–3454). [PMID:36609187 ] [10.1021/acsami.2c18440 ] 2. Jie Xiang, Junyi Zhang, Shunmei Li, Ruo Yuan, Yun Xiang. (2022) Aptamer-based and sensitive label-free colorimetric sensing of phenylalanine via cascaded signal amplifications. ANALYTICA CHIMICA ACTA, 1230 (340393). [PMID:36192064 ] [10.1016/j.aca.2022.340393 ] 3. Xiewen Wu, Song Wang, Jing Fang, Hui Chen, Hongbo Liu, Run Li. (2022) Enhanced Photocatalytic Efficiency in Visible-Light-Induced NADH Regeneration by Intramolecular Electron Transfer. ACS Applied Materials & Interfaces, 14 (34): (38895–38904). [PMID:35986690 ] [10.1021/acsami.2c11174 ] 4. Yuanyuan Zhang, Jian Liu. (2022) Bioinspired Photocatalytic NADH Regeneration by Covalently Metalated Carbon Nitride for Enhanced CO2 Reduction. CHEMISTRY-A EUROPEAN JOURNAL, 28 (55): (e202201430). [PMID:35758216 ] [10.1002/chem.202201430 ] 5. Fang Lan, Qin Wang, Hui Chen, Yi Chen, Yuanyuan Zhang, Bowen Huang, Hongbo Liu, Jian Liu, Run Li. (2020) Preparation of Hydrophilic Conjugated Microporous Polymers for Efficient Visible Light-Driven Nicotinamide Adenine Dinucleotide Regeneration and Photobiocatalytic Formaldehyde Reduction. ACS Catalysis, 10 (21): (12976–12986). [PMID: [10.1021/acscatal.0c03652 ] 6. Yizhou Wu, Jesse Ward-Bond, Donglin Li, Shaohua Zhang, Jiafu Shi, Zhongyi Jiang. (2018) g-C3N4@α-Fe2O3/C Photocatalysts: Synergistically Intensified Charge Generation and Charge Transfer for NADH Regeneration. ACS Catalysis, 8 (7): (5664–5674). [PMID: [10.1021/acscatal.8b00070 ]
References 1. Ying Zhang, Bin Wei, Hao Liang. (2023) Rhodium-Based MOF-on-MOF Difunctional Core–Shell Nanoreactor for NAD(P)H Regeneration and Enzyme Directed Immobilization. ACS Applied Materials & Interfaces, 15 (2): (3442–3454). [PMID:36609187 ] [10.1021/acsami.2c18440 ] 2. Jie Xiang, Junyi Zhang, Shunmei Li, Ruo Yuan, Yun Xiang. (2022) Aptamer-based and sensitive label-free colorimetric sensing of phenylalanine via cascaded signal amplifications. ANALYTICA CHIMICA ACTA, 1230 (340393). [PMID:36192064 ] [10.1016/j.aca.2022.340393 ] 3. Xiewen Wu, Song Wang, Jing Fang, Hui Chen, Hongbo Liu, Run Li. (2022) Enhanced Photocatalytic Efficiency in Visible-Light-Induced NADH Regeneration by Intramolecular Electron Transfer. ACS Applied Materials & Interfaces, 14 (34): (38895–38904). [PMID:35986690 ] [10.1021/acsami.2c11174 ] 4. Yuanyuan Zhang, Jian Liu. (2022) Bioinspired Photocatalytic NADH Regeneration by Covalently Metalated Carbon Nitride for Enhanced CO2 Reduction. CHEMISTRY-A EUROPEAN JOURNAL, 28 (55): (e202201430). [PMID:35758216 ] [10.1002/chem.202201430 ] 5. Fang Lan, Qin Wang, Hui Chen, Yi Chen, Yuanyuan Zhang, Bowen Huang, Hongbo Liu, Jian Liu, Run Li. (2020) Preparation of Hydrophilic Conjugated Microporous Polymers for Efficient Visible Light-Driven Nicotinamide Adenine Dinucleotide Regeneration and Photobiocatalytic Formaldehyde Reduction. ACS Catalysis, 10 (21): (12976–12986). [PMID: [10.1021/acscatal.0c03652 ] 6. Yizhou Wu, Jesse Ward-Bond, Donglin Li, Shaohua Zhang, Jiafu Shi, Zhongyi Jiang. (2018) g-C3N4@α-Fe2O3/C Photocatalysts: Synergistically Intensified Charge Generation and Charge Transfer for NADH Regeneration. ACS Catalysis, 8 (7): (5664–5674). [PMID: [10.1021/acscatal.8b00070 ]
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