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Pentamethylcyclopentadienylrhodium(III) chloride dimer - 97%, high purity , CAS No.12354-85-7

4 Citations

≥97%

CAS#: 12354-85-7
Formula: [Rh(C₅Me₅)Cl₂]₂
Molecular Weight: 618.08
MDL number: MFCD00061552

Item Number

P470206

Grouped product items
SKU	Size	Availability	Price
P470206-100mg	100mg	Available within 8-12 weeks(?) Production requires sourcing of materials. We appreciate your patience and understanding.	$282.90
P470206-250mg	250mg	In stock	$627.90
P470206-1g	1g	In stock	$1,527.90

Basic Description

Specifications & Purity	97%
Product Description	Description Pentamethylcyclopentadienylrhodium(III) chloride dimer can be used as a catalyst for:Oxidative olefination reactionsC-C bond cleavage of secondary alcoholsOrtho C-H olefination of phenol derivativesOxidative annulation of pyridinesOxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2C-H bondAmidation reactionsReductive alkylation reactionsUmicore Precatalysts for Asymmetric and Cross-Coupling CatalysisCatalyst for:Oxidative olefination reactionsC-C bond cleavage of secondary alcoholsOrtho C-H olefination of phenol derivativesOxidative annulation of pyridinesOxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2C-H bondAmidation reactionsReductive alkylation reactions

INCHI

1S/2C10H15.4ClH.2Rh/c2*1-6-7(2)9(4)10(5)8(6)3;;;;;;/h2*1-5H3;4*1H;;/q;;;;;;2*+2/p-4

InChi Key

QNIVKTTWBMFSBR-UHFFFAOYSA-J

Canonical SMILES

Cl[Rh]Cl.Cl[Rh]Cl.C[C]1[C](C)[C](C)[C](C)[C]1C.C[C]2[C](C)[C](C)[C](C)[C]2C

WGK Germany

Molecular Weight

618.08

Certificates

Certificate of Analysis(COA)

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5 results found

Lot Number	Certificate Type	Date	Item
G2426583	Certificate of Analysis	Apr 29, 2024	P470206
A2417637	Certificate of Analysis	Dec 15, 2023	P470206
A2417638	Certificate of Analysis	Dec 15, 2023	P470206
A2417639	Certificate of Analysis	Dec 15, 2023	P470206
A2417640	Certificate of Analysis	Dec 15, 2023	P470206

Safety and Hazards(GHS)

Pictogram(s)	GHS07
Signal	Warning
Hazard Statements	H315:Causes skin irritation H319:Causes serious eye irritation H335:May cause respiratory irritation H302+H312+H332:Harmful if swallowed, in contact with skin or if inhaled
Precautionary Statements	P261:Avoid breathing dust/fume/gas/mist/vapors/spray. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing. P280:Wear protective gloves/protective clothing/eye protection/face protection. P501:Dispose of contents/container to ... P312:Call a POISON CENTER or doctor/... if you feel unwell. P264:Wash hands [and …] thoroughly after handling. P271:Use only outdoors or in a well-ventilated area. P270:Do not eat, drink or smoke when using this product. P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing. P337+P313:IF eye irritation persists: Get medical advice/attention. P362+P364:Take off contaminated clothing and wash it before reuse. P332+P313:IF SKIN irritation occurs: Get medical advice/attention. P301+P312:IF SWALLOWED: call a POISON CENTER/doctor/... IF you feel unwell. P301+P312+P330:IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. Rinse mouth. P302+P352+P312:IF ON SKIN: Wash with plenty of water.Call a POISON CENTER/ doctor if you feel unwell. P304+P340+P312: IF INHALED: Remove person to fresh air and keep comfortable for breathing.Call a POISON CENTER or doctor. if you feel unwell.
WGK Germany	3

Citations of This Product

1. Ying Zhang, Bin Wei, Hao Liang. (2023) Rhodium-Based MOF-on-MOF Difunctional Core–Shell Nanoreactor for NAD(P)H Regeneration and Enzyme Directed Immobilization. ACS Applied Materials & Interfaces, 15 (2): (3442–3454). [PMID:36609187]
2. Jie Xiang, Junyi Zhang, Shunmei Li, Ruo Yuan, Yun Xiang. (2022) Aptamer-based and sensitive label-free colorimetric sensing of phenylalanine via cascaded signal amplifications. ANALYTICA CHIMICA ACTA, 1230 (340393). [PMID:36192064]
3. Xiewen Wu, Song Wang, Jing Fang, Hui Chen, Hongbo Liu, Run Li. (2022) Enhanced Photocatalytic Efficiency in Visible-Light-Induced NADH Regeneration by Intramolecular Electron Transfer. ACS Applied Materials & Interfaces, 14 (34): (38895–38904). [PMID:35986690]
4. Yuanyuan Zhang, Jian Liu. (2022) Bioinspired Photocatalytic NADH Regeneration by Covalently Metalated Carbon Nitride for Enhanced CO2 Reduction. CHEMISTRY-A EUROPEAN JOURNAL, 28 (55): (e202201430). [PMID:35758216]

References

1. Ying Zhang, Bin Wei, Hao Liang. (2023) Rhodium-Based MOF-on-MOF Difunctional Core–Shell Nanoreactor for NAD(P)H Regeneration and Enzyme Directed Immobilization. ACS Applied Materials & Interfaces, 15 (2): (3442–3454). [PMID:36609187]
2. Jie Xiang, Junyi Zhang, Shunmei Li, Ruo Yuan, Yun Xiang. (2022) Aptamer-based and sensitive label-free colorimetric sensing of phenylalanine via cascaded signal amplifications. ANALYTICA CHIMICA ACTA, 1230 (340393). [PMID:36192064]
3. Xiewen Wu, Song Wang, Jing Fang, Hui Chen, Hongbo Liu, Run Li. (2022) Enhanced Photocatalytic Efficiency in Visible-Light-Induced NADH Regeneration by Intramolecular Electron Transfer. ACS Applied Materials & Interfaces, 14 (34): (38895–38904). [PMID:35986690]
4. Yuanyuan Zhang, Jian Liu. (2022) Bioinspired Photocatalytic NADH Regeneration by Covalently Metalated Carbon Nitride for Enhanced CO2 Reduction. CHEMISTRY-A EUROPEAN JOURNAL, 28 (55): (e202201430). [PMID:35758216]

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