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Pentamethylcyclopentadienylrhodium(III) chloride dimer - 97%, high purity , CAS No.12354-85-7
Basic Description Specifications & Purity 97% Product Description Description
Pentamethylcyclopentadienylrhodium(III) chloride dimer can be used as a catalyst for:Oxidative olefination reactionsC-C bond cleavage of secondary alcoholsOrtho C-H olefination of phenol derivativesOxidative annulation of pyridinesOxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2C-H bondAmidation reactionsReductive alkylation reactionsUmicore Precatalysts for Asymmetric and Cross-Coupling CatalysisCatalyst for:Oxidative olefination reactionsC-C bond cleavage of secondary alcoholsOrtho C-H olefination of phenol derivativesOxidative annulation of pyridinesOxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2C-H bondAmidation reactionsReductive alkylation reactions
Names and Identifiers INCHI 1S/2C10H15.4ClH.2Rh/c2*1-6-7(2)9(4)10(5)8(6)3;;;;;;/h2*1-5H3;4*1H;;/q;;;;;;2*+2/p-4 InChi Key QNIVKTTWBMFSBR-UHFFFAOYSA-J Canonical SMILES Cl[Rh]Cl.Cl[Rh]Cl.C[C]1[C](C)[C](C)[C](C)[C]1C.C[C]2[C](C)[C](C)[C](C)[C]2C WGK Germany 3 Molecular Weight 618.08
Chemical and Physical Properties Safety and Hazards(GHS) Pictogram(s) GHS07 Signal Warning Hazard Statements H315: Causes skin irritation
H319: Causes serious eye irritation
H335: May cause respiratory irritation
H302+H312+H332: Harmful if swallowed, in contact with skin or if inhaled
Precautionary Statements P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P501: Dispose of contents/container to ...
P312: Call a POISON CENTER or doctor/... if you feel unwell.
P264: Wash hands [and …] thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P270: Do not eat, drink or smoke when using this product.
P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P337+P313: IF eye irritation persists: Get medical advice/attention.
P362+P364: Take off contaminated clothing and wash it before reuse.
P332+P313: IF SKIN irritation occurs: Get medical advice/attention.
P301+P312: IF SWALLOWED: call a POISON CENTER/doctor/... IF you feel unwell.
P301+P312+P330: IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. Rinse mouth.
P302+P352+P312: IF ON SKIN: Wash with plenty of water.Call a POISON CENTER/ doctor if you feel unwell.
P304+P340+P312: IF INHALED: Remove person to fresh air and keep comfortable for breathing.Call a POISON CENTER or doctor. if you feel unwell.
WGK Germany 3
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