| SKU | Size | Availability | Price | Qty |
|---|---|---|---|---|
| P485532-100mg | 100mg | Available within 8-12 weeks(?) Production requires sourcing of materials. We appreciate your patience and understanding. | $310.90 |
| Specifications & Purity | New Iridium, ≥97% |
|---|---|
| Legal Information | 专利申请PCT/US2016/058245。与New Iridium Inc.合作销售。对于大于25克的订单，请通过chern@newiridium.com联系New Iridium，或访问https://www.newiridium.com。PhenN O-PC is a trademark of New Iridium Inc.Phenox O-PC is a trademark of New Iridium LLC |
| Product Description | Description This dihydrophenazine-based organic photoredox catalyst (in addition to the dihydrophenazine catalyst901111) was designed to be a strong excited-state reductant and possesses advanced photophysical and electrochemical properties, enabling it to serve as a sustainable replacement for ruthenium- or iridium-based photoredox catalysts. For example, dihydrophenazine and phenoxazine derivatives were demonstrated to replace ruthenium or iridium complexes in the application of photoredox-catalyzed atom transfer radical polymerization (ATRP) for controlled polymer synthesis and small molecule transformations such as trifluoromethylation, atom transfer radical addition, and dual Nickel/photoredox catalyzed C-N and C-S cross-couplings. Dihydrophenazine- and phenoxazine-based organic photoredox catalysts were introduced in collaboration with theMiyakeResearch Group. |
| IUPAC Name | 5,10-dinaphthalen-2-ylphenazine |
|---|---|
| INCHI | InChI=1S/C32H22N2/c1-3-11-25-21-27(19-17-23(25)9-1)33-29-13-5-7-15-31(29)34(32-16-8-6-14-30(32)33)28-20-18-24-10-2-4-12-26(24)22-28/h1-22H |
| InChi Key | HPIOBCHPZVAATK-UHFFFAOYSA-N |
| Canonical SMILES | C1=CC=C2C=C(C=CC2=C1)N3C4=CC=CC=C4N(C5=CC=CC=C53)C6=CC7=CC=CC=C7C=C6 |
| Isomeric SMILES | C1=CC=C2C=C(C=CC2=C1)N3C4=CC=CC=C4N(C5=CC=CC=C53)C6=CC7=CC=CC=C7C=C6 |
| PubChem CID | 20767396 |
| Molecular Weight | 434.53 |
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| Flash Point(°F) | Not applicable |
|---|---|
| Flash Point(°C) | Not applicable |
| Pictogram(s) | GHS07 |
|---|---|
| Signal | Warning |
| Hazard Statements | H302:Harmful if swallowed |
| Precautionary Statements | P301+P312+P330:IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. Rinse mouth. |
| RIDADR | NONH for all modes of transport |
| 1. Jordan C Theriot,Chern-Hooi Lim,Haishen Yang,Matthew D Ryan,Charles B Musgrave,Garret M Miyake. (2016-04-02) Organocatalyzed atom transfer radical polymerization driven by visible light.. Science (New York, N.Y.), 352 ((6289)): (1082-1086). [PMID:27033549] |
