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Potassium tert-butoxide - 99.99% trace metals basis(May contain 0.5% Na), high purity , CAS No.865-47-4

13 Citations

≥99.99% metals basis
May contain 0.5% Na

CAS#: 865-47-4
Formula: C₄H₉KO
Molecular Weight: 112.21
Beilstein Registry Number: 3556712
PubChem CID: 23665647

Item Number

P434283

Grouped product items
SKU	Size	Availability	Price
P434283-5g	5g	Available within 8-12 weeks(?) Production requires sourcing of materials. We appreciate your patience and understanding.	$19.90
P434283-25g	25g	Available within 8-12 weeks(?) Production requires sourcing of materials. We appreciate your patience and understanding.	$69.90
P434283-100g	100g	Available within 8-12 weeks(?) Production requires sourcing of materials. We appreciate your patience and understanding.	$199.90

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Alcoholate K (Potassium) Compounds Organic base

Basic Description

Synonyms	Potassium tert-butylate \| Potassium T-butoxide
Specifications & Purity	≥99.99% metals basis, May contain 0.5% Na
Storage Temp	Argon charged
Shipped In	Normal
Product Description	Total impurities: may contain up to 5,000 ppm Sodium Potassium tert-butoxide is a strong alkoxide base, it can deprotonate carbon and other Brφnsted acids. It is a relatively poor nucleophile. Application Mizoroki-Heck-Type reactions are mediated by potassium tert-butoxide. potassium tert-butoxide can commence the anionic polymerization of carbazolyl-substituted oxiranes.

Names and Identifiers

IUPAC Name	potassium;2-methylpropan-2-olate
INCHI	InChI=1S/C4H9O.K/c1-4(2,3)5;/h1-3H3;/q-1;+1
InChi Key	LPNYRYFBWFDTMA-UHFFFAOYSA-N
Canonical SMILES	CC(C)(C)[O-].[K+]
Isomeric SMILES	CC(C)(C)[O-].[K+]
WGK Germany	1
PubChem CID	23665647
UN Number	3131
Packing Group	I
Molecular Weight	112.21
Beilstein	3556712
Reaxy-Rn	3556712

Certificates

Certificate of Analysis(COA)

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Chemical and Physical Properties

Sensitivity	Moisture sensitive
Flash Point(°F)	53.6 °F
Flash Point(°C)	12 °C
Boil Point(°C)	275°C
Melt Point(°C)	256-258°C

Safety and Hazards(GHS)

Pictogram(s)	GHS05, GHS07, GHS02
Signal	Danger
Hazard Statements	H314:Causes severe skin burns and eye damage H302:Harmful if swallowed H318:Causes serious eye damage H228:Flammable solid H252:Self-heating in large quantities; may catch fire
Precautionary Statements	P280:Wear protective gloves/protective clothing/eye protection/face protection. P370+P378:In case of fire: Use ... to extinguish. P210:Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking. P321:Specific treatment (see ... on this label). P405:Store locked up. P501:Dispose of contents/container to ... P240:Ground/bond container and receiving equipment. P264:Wash hands [and …] thoroughly after handling. P260:Do not breathe dust/fume/gas/mist/vapors/spray. P241:Use explosion-proof [electrical/ventilating/lighting/.../] equipment. P270:Do not eat, drink or smoke when using this product. P301+P330+P331:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing. P363:Wash contaminated clothing before reuse. P410:Protect from sunlight. P420:Store separately. P330:Rinse mouth. P235:Keep cool. P407:Maintain air gap between stacks or pallets. P413:Store bulk masses greater than ... kg/...lbs at temperatures not exceeding ... °C/...°F. P264+P265:Wash hands [and …] thoroughly after handling. Do not touch eyes. P301+P317:IF SWALLOWED: Get medical help. P305+P354+P338:IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. P317:Get emergency medical help. P302+P361+P354:IF ON SKIN: Take off Immediately all contaminated clothing. Immediately rinse with water for several minutes. P316:Get emergency medical help immediately.
WGK Germany	1
Reaxy-Rn	3556712
Class	8(4.3)
RIDADR	UN 3131 8(4.3) / PGI

Citations of This Product

How to Cite Aladdin Scientific Products?

1. Hui Yu, Wenbo Wu, Hongtu Zhao, Kui Chen, Shuyu Li, Mingzhe Tan, Ting Wang, Xin Huang, Na Wang, Hongxun Hao. (2023) Cyanostyrene derivative with multi-stimuli responsive properties: Multicolor- and high-color-contrast switching in response to force, heat and light. DYES AND PIGMENTS, 220 (111727). [PMID:17159994]
2. Zhang Yu, Zheng Jianzhi, Li Xijuan, Wu Ying, Zhang Ke. (2023) Stoichiometric Imbalance-promoted Step-growth Polymerization Based on Self-accelerating Three-component Reaction. CHEMICAL RESEARCH IN CHINESE UNIVERSITIES, 39 (5): (822-828). [PMID:15196461]
3. Shiying Wu, Huaqing Zhang, Zhu Mao, Yaohui Liang, Jian-An Li, Pengtao Hu, Qingqing Zhang, Cong Liu, Suilian Luo, Yuhai Wang, Guang Shi, Bingjia Xu. (2023) Achieving Stable and Switchable Ultralong Room-Temperature Phosphorescence from Polymer-Based Luminescent Materials with Three-Dimensional Covalent Networks for Light-Manipulated Anticounterfeiting. ACS Applied Materials & Interfaces, 15 (33): (39896–39904). [PMID:37555378]
4. Yixuan Xu, Changchang Teng, Huiping Dang, Dalong Yin, Lifeng Yan. (2024) Highly bright stable organic radicals encapsulated by amphiphilic polypeptide for efficient near-infrared phototheranostics. TALANTA, 266 (124948). [PMID:37459788]
5. Shaowen Pei, Xiuping Ju, Jinsheng Zhao, Hongmei Du. (2019) Synthesis and Electrochromic Properties of Two Random Copolymers Containing Benzotriazole, Benzothiadiazole as Electron Acceptors and Benzodithiophene or Indacenodithiophene as Electron Donors. International Journal of Electrochemical Science, 14 (6643). [PMID:]
6. Shuang Chen, Lingqian Kong, Chaolei Ban, Jinsheng Zhao, Hongmei Du. (2018) Synthesis and Characterization of Four Random copolymers Containing Fluorene as Electron Donors and Benzotriazole, Benzothiadiazole, Pyrido[3,4-b]pyrazine as Electron Acceptors. International Journal of Electrochemical Science, 13 (9964). [PMID:]
7. Chen Kai, Cai Zhongyuan, Cao Yingzi, Jiang Lingling, Jiang Yuting, Gu Haojie, Fu Shengxiang, Xia Chunchao, Lui Su, Gong Qiyong, Song Bin, Ai Hua. (2023) Kinetically inert manganese (II)-based hybrid micellar complexes for magnetic resonance imaging of lymph node metastasis. Regenerative Biomaterials, 10 [PMID:37293571]
8. Xiaojing Lv, Xuchen Zhu, Ling Zhang, Mi Ouyang, Minao Xia, Chunyan Liu, Cheng Zhang. (2023) Highly transparent to red/green/blue photo-crosslinkable polymer for patterned electrochromic device. Journal of Materials Chemistry C, 11 (16): (5490-5497). [PMID:]
9. Jintao Liang, Kaiteng Yan, Yutong Liu, Xiaoqing Yao, Fei Guo, Wen Xue, Guiyin Li, Jiejing Chen, Zhide Zhou. (2023) A rGO-PAM-Fc/AuNPs nanosensing membrane in a light-addressable potentiometric biosensor for 1,5-anhydroglucitol determination. MICROCHEMICAL JOURNAL, 184 (108185). [PMID:]
10. Zengwei Liu, Jing Lyu, Yi Ding, Yaqian Bao, Zhizhi Sheng, Nan Shi, Xuetong Zhang. (2022) Nanoscale Kevlar Liquid Crystal Aerogel Fibers. ACS Nano, 16 (9): (15237–15248). [PMID:36053080]
11. Xiao-San Li, Mao-Xun Yang, Yu-Hao Luo, He-Hui Zhan, Mei-Fang Chen, Yong-Mei Huang, Li Liu, Xue-Mei Yang. (2022) Design, Synthesis and Anticancer Activity of Novel Steroidal Derivatives with D-Ring Fused or Substituted N-Heterocyclic Systems. CHEMISTRY & BIODIVERSITY, 19 (10): (e202200648). [PMID:36043381]
12. Hang Yu, Dewang Li, Huayu Bao, Zhenhu Zhang, Hongli Liu, Fei Zhang, Shirong Wang. (2022) Multifunctional Cross-Linked Hole Transporting Interfacial Layer for Efficient and Stable Perovskite Solar Cells. ACS Applied Energy Materials, 5 (9): (10742–10750). [PMID:]
13. Henghui Huang, Qi Yao, Xiuping Zhang, Haijiang Wang. (2022) Microporous expanded polytetrafluoroethylene layer functionalized hydrophilic groups for excellent mechanical durability and superior performance in proton exchange membrane fuel cell. JOURNAL OF POWER SOURCES, 526 (231130). [PMID:]
14. Xinxin Mo, Yu Wang, Qiyou Xiao, Xitong Zhou, He Li. (2021) Conjugated polymer sensitized hyperbranched titanium dioxide based photoelectrochemical biosensor for detecting AFP in serum. Surfaces and Interfaces, 24 (101103). [PMID:]
15. Xuan Zhao, Yong Chen, XianYin Dai, WeiLei Zhou, JingJing Li, Yu Liu. (2020) An Efficient Aggregation-Induced Emission Supramolecular Probe for Detection of Nitroaromatic Explosives in Water. Advanced Photonics Research, 1 (1): (2000007). [PMID:]
16. Zifeng Yang, Lei Liu, Hongzhe An, Chenhao Li, Zhencai Zhang, Wenjuan Fang, Fei Xu, Suojiang Zhang. (2020) Cost-Effective Synthesis of High Molecular Weight Biobased Polycarbonate via Melt Polymerization of Isosorbide and Dimethyl Carbonate. ACS Sustainable Chemistry & Engineering, 8 (27): (9968–9979). [PMID:]
17. Lu Yan, Chang Zhaosen, Zhang Shizhen, Wang Shunli, Chen Qi, Feng Lijuan, Sui Zhuyin. (2020) Porous organic polymers containing zinc porphyrin and phosphonium bromide as bifunctional catalysts for conversion of carbon dioxide. JOURNAL OF MATERIALS SCIENCE, 55 (26): (11856-11869). [PMID:]
18. Lingchen Meng, Shan Jiang, Meiyu Song, Fei Yan, Wei Zhang, Bin Xu, Wenjing Tian. (2020) TICT-Based Near-Infrared Ratiometric Organic Fluorescent Thermometer for Intracellular Temperature Sensing. ACS Applied Materials & Interfaces, 12 (24): (26842–26851). [PMID:32436373]
19. Haibo Zhu, Yingying Zhang, Yishuai Liu, Liu Yang, Zongbo Xie, Guofang Jiang, Zhang-Gao Le. (2020) A general and practical sulfonylation of benzylic ammonium salts with sulfonyl hydrazides for the synthesis of sulfones. TETRAHEDRON LETTERS, 61 (151975). [PMID:]
20. Liming He, Jun Zhou, Yutao Wang, Zhongliang Ma, Chunlin Chen. (2020) Mechanical and Thermal Properties of Polyether Polytriazole Elastomers Formed by Click-Chemical Reaction Curing Glycidyl Azide Polymer. MOLECULES, 25 (8): (1988). [PMID:32340385]
21. Lei Miao, Tingting Jiang, Shudong Lin, Tao Jin, Jiwen Hu, Min Zhang, Yuanyuan Tu, Guojun Liu. (2020) Asymmetric forward osmosis membranes from p-aramid nanofibers. MATERIALS & DESIGN, 191 (108591). [PMID:]
22. Lei Ma, Xuyan Li, Xin Guo, Yongchao Jiang, XiaoMeng Li, Haiyang Guo, Bo Zhang, Yiyang Xu, Xiaofeng Wang, Qian Li. (2020) Promotion of Endothelial Cell Adhesion and Antithrombogenicity of Polytetrafluoroethylene by Chemical Grafting of Chondroitin Sulfate. ACS Applied Bio Materials, 3 (2): (891–901). [PMID:35019291]
23. Weimin Wan, Hui Ouyang, Wei Long, Wenfeng Yan, Mingzhen He, Hongye Huang, Shilin Yang, Xiaoyong Zhang, Yulin Feng, Yen Wei. (2019) Direct Surface Functionalization of Cellulose Nanocrystals with Hyperbranched Polymers through the Anionic Polymerization for pH-Responsive Intracellular Drug Delivery. ACS Sustainable Chemistry & Engineering, 7 (23): (19202–19212). [PMID:]
24. Yan Zhang, Hongmei Du, Yiming Yin, Yunyun Dong, Jinsheng Zhao, Zhen Xu. (2020) Synthesis and characterization of soluble donor-acceptor type copolymers based on benzotriazole, quinoxaline and benzene units with multicolor electrochromism. ORGANIC ELECTRONICS, 77 (105514). [PMID:]
25. Longfei Tang, Songjiang Chen, Dongjiao Gui, Xiangnan Zhu, Huan He, Xiuxiang Tao. (2020) Effect of removal organic sulfur from coal macromolecular on the properties of high organic sulfur coal. FUEL, 259 (116264). [PMID:]
26. Chun Qi, Gen Tang, Xiang Guo, Changhua Liu, Ai-min Pang, Lin Gan, Jin Huang. (2019) Network regulation and properties optimization of glycidyl azide polymer-based materials as a candidate of solid propellant binder via alternating the functionality of propargyl-terminated polyether. JOURNAL OF APPLIED POLYMER SCIENCE, 136 (40): (48016). [PMID:]

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30. Zhang Yu, Zheng Jianzhi, Li Xijuan, Wu Ying, Zhang Ke. (2023) Stoichiometric Imbalance-promoted Step-growth Polymerization Based on Self-accelerating Three-component Reaction. CHEMICAL RESEARCH IN CHINESE UNIVERSITIES, 39 (5): (822-828). [PMID:15196461]
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32. Yixuan Xu, Changchang Teng, Huiping Dang, Dalong Yin, Lifeng Yan. (2024) Highly bright stable organic radicals encapsulated by amphiphilic polypeptide for efficient near-infrared phototheranostics. TALANTA, 266 (124948). [PMID:37459788]
33. Shaowen Pei, Xiuping Ju, Jinsheng Zhao, Hongmei Du. (2019) Synthesis and Electrochromic Properties of Two Random Copolymers Containing Benzotriazole, Benzothiadiazole as Electron Acceptors and Benzodithiophene or Indacenodithiophene as Electron Donors. International Journal of Electrochemical Science, 14 (6643). [PMID:]
34. Shuang Chen, Lingqian Kong, Chaolei Ban, Jinsheng Zhao, Hongmei Du. (2018) Synthesis and Characterization of Four Random copolymers Containing Fluorene as Electron Donors and Benzotriazole, Benzothiadiazole, Pyrido[3,4-b]pyrazine as Electron Acceptors. International Journal of Electrochemical Science, 13 (9964). [PMID:]
35. Chen Kai, Cai Zhongyuan, Cao Yingzi, Jiang Lingling, Jiang Yuting, Gu Haojie, Fu Shengxiang, Xia Chunchao, Lui Su, Gong Qiyong, Song Bin, Ai Hua. (2023) Kinetically inert manganese (II)-based hybrid micellar complexes for magnetic resonance imaging of lymph node metastasis. Regenerative Biomaterials, 10 [PMID:37293571]
36. Xiaojing Lv, Xuchen Zhu, Ling Zhang, Mi Ouyang, Minao Xia, Chunyan Liu, Cheng Zhang. (2023) Highly transparent to red/green/blue photo-crosslinkable polymer for patterned electrochromic device. Journal of Materials Chemistry C, 11 (16): (5490-5497). [PMID:]
37. Jintao Liang, Kaiteng Yan, Yutong Liu, Xiaoqing Yao, Fei Guo, Wen Xue, Guiyin Li, Jiejing Chen, Zhide Zhou. (2023) A rGO-PAM-Fc/AuNPs nanosensing membrane in a light-addressable potentiometric biosensor for 1,5-anhydroglucitol determination. MICROCHEMICAL JOURNAL, 184 (108185). [PMID:]
38. Zengwei Liu, Jing Lyu, Yi Ding, Yaqian Bao, Zhizhi Sheng, Nan Shi, Xuetong Zhang. (2022) Nanoscale Kevlar Liquid Crystal Aerogel Fibers. ACS Nano, 16 (9): (15237–15248). [PMID:36053080]
39. Xiao-San Li, Mao-Xun Yang, Yu-Hao Luo, He-Hui Zhan, Mei-Fang Chen, Yong-Mei Huang, Li Liu, Xue-Mei Yang. (2022) Design, Synthesis and Anticancer Activity of Novel Steroidal Derivatives with D-Ring Fused or Substituted N-Heterocyclic Systems. CHEMISTRY & BIODIVERSITY, 19 (10): (e202200648). [PMID:36043381]
40. Hang Yu, Dewang Li, Huayu Bao, Zhenhu Zhang, Hongli Liu, Fei Zhang, Shirong Wang. (2022) Multifunctional Cross-Linked Hole Transporting Interfacial Layer for Efficient and Stable Perovskite Solar Cells. ACS Applied Energy Materials, 5 (9): (10742–10750). [PMID:]
41. Henghui Huang, Qi Yao, Xiuping Zhang, Haijiang Wang. (2022) Microporous expanded polytetrafluoroethylene layer functionalized hydrophilic groups for excellent mechanical durability and superior performance in proton exchange membrane fuel cell. JOURNAL OF POWER SOURCES, 526 (231130). [PMID:]
42. Xinxin Mo, Yu Wang, Qiyou Xiao, Xitong Zhou, He Li. (2021) Conjugated polymer sensitized hyperbranched titanium dioxide based photoelectrochemical biosensor for detecting AFP in serum. Surfaces and Interfaces, 24 (101103). [PMID:]
43. Xuan Zhao, Yong Chen, XianYin Dai, WeiLei Zhou, JingJing Li, Yu Liu. (2020) An Efficient Aggregation-Induced Emission Supramolecular Probe for Detection of Nitroaromatic Explosives in Water. Advanced Photonics Research, 1 (1): (2000007). [PMID:]
44. Zifeng Yang, Lei Liu, Hongzhe An, Chenhao Li, Zhencai Zhang, Wenjuan Fang, Fei Xu, Suojiang Zhang. (2020) Cost-Effective Synthesis of High Molecular Weight Biobased Polycarbonate via Melt Polymerization of Isosorbide and Dimethyl Carbonate. ACS Sustainable Chemistry & Engineering, 8 (27): (9968–9979). [PMID:]
45. Lu Yan, Chang Zhaosen, Zhang Shizhen, Wang Shunli, Chen Qi, Feng Lijuan, Sui Zhuyin. (2020) Porous organic polymers containing zinc porphyrin and phosphonium bromide as bifunctional catalysts for conversion of carbon dioxide. JOURNAL OF MATERIALS SCIENCE, 55 (26): (11856-11869). [PMID:]
46. Lingchen Meng, Shan Jiang, Meiyu Song, Fei Yan, Wei Zhang, Bin Xu, Wenjing Tian. (2020) TICT-Based Near-Infrared Ratiometric Organic Fluorescent Thermometer for Intracellular Temperature Sensing. ACS Applied Materials & Interfaces, 12 (24): (26842–26851). [PMID:32436373]
47. Haibo Zhu, Yingying Zhang, Yishuai Liu, Liu Yang, Zongbo Xie, Guofang Jiang, Zhang-Gao Le. (2020) A general and practical sulfonylation of benzylic ammonium salts with sulfonyl hydrazides for the synthesis of sulfones. TETRAHEDRON LETTERS, 61 (151975). [PMID:]
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