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Pyridinium Dichromate - 98%, high purity , CAS No.20039-37-6

≥98%

CAS#: 20039-37-6
Formula: C₁₀H₁₀N₂·H₂Cr₂O₇
Molecular Weight: 376.2
EC Number: 243-478-8
MDL number: MFCD00013105
PubChem CID: 2724130

Item Number

P122663

Grouped product items
SKU	Size	Availability	Price
P122663-25g	25g	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$15.90
P122663-100g	100g	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$38.90
P122663-500g	500g	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$137.90

View related series

Pyridines Six-Membered Heterocyclic Compounds

Basic Description

Synonyms	20039-37-6\|Cornforth reagent\|dipyridinium dichromate\|Pyridinium Dichromate (PDC); bis(pyridium) chromate;\|pyridinium-dichromate\|Corey-Schmidt reagent\|SCHEMBL8634\|C10H12Cr2N2O7\|DTXSID60889393\|CHEBI:176796\|LMYWWPCAXXPJFF-UHFFFAOYSA-P\|AKOS015833213\|dipyridi
Specifications & Purity	98%
Storage Temp	Argon charged
Shipped In	Normal
Product Description	Oxidizing agent for conversion of primary alcohols to aldehydes and ketones acetals to esters and didehydroketones to enones in the presence of tert-butyl hydroperoxide.

Names and Identifiers

IUPAC Name	oxido-(oxido(dioxo)chromio)oxy-dioxochromium;pyridin-1-ium
INCHI	InChI=1S/2C5H5N.2Cr.7O/c21-2-4-6-5-3-1;;;;;;;;;/h21-5H;;;;;;;;;/q;;;;;;;;;2*-1/p+2
InChi Key	LMYWWPCAXXPJFF-UHFFFAOYSA-P
Canonical SMILES	C1=CC=[NH+]C=C1.C1=CC=[NH+]C=C1.[O-][Cr](=O)(=O)O[Cr](=O)(=O)[O-]
Isomeric SMILES	C1=CC=[NH+]C=C1.C1=CC=[NH+]C=C1.[O-][Cr](=O)(=O)O[Cr](=O)(=O)[O-]
WGK Germany	2
PubChem CID	2724130
UN Number	1479
Packing Group	II
Molecular Weight	376.2
Reaxy-Rn	11460878

Certificates

Certificate of Analysis(COA)

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3 results found

Lot Number	Certificate Type	Date	Item
H1512179	Certificate of Analysis	Apr 12, 2023	P122663
B2103066	Certificate of Analysis	Mar 05, 2021	P122663
D2321350	Certificate of Analysis	Mar 05, 2021	P122663

Chemical and Physical Properties

Solubility	Soluble in water, dimethyl formamide, dimethyl sulfoxide and acetonitrile. Slightly soluble in dichloromethane, chloroform and acetone. Insoluble in hexane, ether and ethyl acetate.
Sensitivity	Hygroscopic
Melt Point(°C)	145-147°C

Safety and Hazards(GHS)

Pictogram(s)	GHS08, GHS09, GHS05, GHS07, GHS02
Signal	Danger
Hazard Statements	H315:Causes skin irritation H319:Causes serious eye irritation H314:Causes severe skin burns and eye damage H317:May cause an allergic skin reaction H228:Flammable solid H400:Very toxic to aquatic life H272:May intensify fire; oxidizer H410:Very toxic to aquatic life with long lasting effects H350:May cause cancer
Precautionary Statements	P261:Avoid breathing dust/fume/gas/mist/vapors/spray. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing. P273:Avoid release to the environment. P280:Wear protective gloves/protective clothing/eye protection/face protection. P370+P378:In case of fire: Use ... to extinguish. P210:Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking. P302+P352:IF ON SKIN: wash with plenty of water. P321:Specific treatment (see ... on this label). P405:Store locked up. P501:Dispose of contents/container to ... P240:Ground/bond container and receiving equipment. P264:Wash hands [and …] thoroughly after handling. P220:Keep away from clothing and other combustible materials. P260:Do not breathe dust/fume/gas/mist/vapors/spray. P241:Use explosion-proof [electrical/ventilating/lighting/.../] equipment. P301+P330+P331:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing. P363:Wash contaminated clothing before reuse. P272:Contaminated work clothing should not be allowed out of the workplace. P333+P313:IF SKIN irritation or rash occurs: Get medical advice/attention. P362+P364:Take off contaminated clothing and wash it before reuse. P391:Collect spillage. P203:Obtain, read and follow all safety instructions before use. P264+P265:Wash hands [and …] thoroughly after handling. Do not touch eyes. P305+P354+P338:IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. P318:if exposed or concerned, get medical advice. P337+P317:If eye irritation persists: Get medical help. P332+P317:If skin irritation occurs: Get medical help. P302+P361+P354:IF ON SKIN: Take off Immediately all contaminated clothing. Immediately rinse with water for several minutes. P316:Get emergency medical help immediately.
WGK Germany	2
Reaxy-Rn	11460878
Class	5.1

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Chromium Compounds

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Chromium Trioxide (CrO3)

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