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(R)-(+)-1,1′-Binaphthyl-2,2′-diamine - ≥99%, high purity , CAS No.18741-85-0
Basic Description Synonyms 4488-22-6|[1,1'-Binaphthalene]-2,2'-diamine|18531-95-8|18741-85-0|1,1'-Binaphthyl-2,2'-diamine|(R)-[1,1'-Binaphthalene]-2,2'-diamine|(S)-(-)-1,1'-Binaphthyl-2,2'-diamine|(R)-(+)-2,2'-Diamino-1,1'-binaphthalene|(S)-(-)-2,2'-Diamino-1,1'-binaphthalene|2,2'- Specifications & Purity ≥99% Shipped In Normal Product Description It is used for the preparation of N-alkylated derivatives and use as chiral auxiliaries. 1,1′-Binaphthyl-2,2′-diamine derivatives have been used for asymmetric hydrogenations,1 cyclopropanations,2,3 and formation of chiral lactones.3,4,5
Names and Identifiers Pubchem Sid 488182631 Pubchem Sid Url https://pubchem.ncbi.nlm.nih.gov/substance/488182631 IUPAC Name 1-(2-aminonaphthalen-1-yl)naphthalen-2-amine INCHI InChI=1S/C20H16N2/c21-17-11-9-13-5-1-3-7-15(13)19(17)20-16-8-4-2-6-14(16)10-12-18(20)22/h1-12H,21-22H2 InChi Key DDAPSNKEOHDLKB-UHFFFAOYSA-N Canonical SMILES C1=CC=C2C(=C1)C=CC(=C2C3=C(C=CC4=CC=CC=C43)N)N Isomeric SMILES C1=CC=C2C(=C1)C=CC(=C2C3=C(C=CC4=CC=CC=C43)N)N WGK Germany 3 PubChem CID 20571 Molecular Weight 284.35 Beilstein 5279621
Chemical and Physical Properties Solubility Slightly soluble in water. Specific Rotation[α] 155° (C=1,Pyridine) Melt Point(°C) 242-243°C
Safety and Hazards(GHS) Pictogram(s) GHS05 , GHS07 Signal Danger Hazard Statements H302: Harmful if swallowed
H318: Causes serious eye damage
Precautionary Statements P280: Wear protective gloves/protective clothing/eye protection/face protection.
P501: Dispose of contents/container to ...
P264: Wash hands [and …] thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P330: Rinse mouth.
P264+P265: Wash hands [and …] thoroughly after handling. Do not touch eyes.
P301+P317: IF SWALLOWED: Get medical help.
P305+P354+P338: IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing.
P317: Get emergency medical help.
WGK Germany 3
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