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(R)-(+)-3-Methoxy-2-methyl-3-oxopropylzinc bromide solution - 0.5M in THF, high purity , CAS No.343338-26-1
Basic Description Synonyms DTXSID60457319 | J-019559 | bromozinc(1+);methyl (2R)-2-methanidylpropanoate Specifications & Purity 0.5M in THF Legal Information Rieke® Metals, Inc. 产品 ®Rieke Metals, Inc. 的注册商标 Storage Temp Store at 2-8°C Shipped In Wet ice Product Description
Description
(R)-(+)-3-Methoxy-2-methyl-3-oxopropylzinc bromide can be used:As an intermediate in one of the key synthetic steps for the preparation of a natural product named (+)-discodermolide.As a starting material for the synthesis of (2R,4E)-methyl-2,4-dimethyl-hexanoate, a key intermediate for the preparation of C13-32 fragment of spirangien A.
Names and Identifiers IUPAC Name bromozinc(1+);methyl (2R)-2-methanidylpropanoate INCHI InChI=1S/C5H9O2.BrH.Zn/c1-4(2)5(6)7-3;;/h4H,1H2,2-3H3;1H;/q-1;;+2/p-1/t4-;;/m1../s1 InChi Key ZHZWKFSRZQRSJL-RZFWHQLPSA-M Canonical SMILES CC([CH2-])C(=O)OC.[Zn+]Br Isomeric SMILES C[C@@H]([CH2-])C(=O)OC.[Zn+]Br WGK Germany 3 PubChem CID 16667572 Molecular Weight 246.42
Certificates(CoA,COO,BSE/TSE and Analysis Chart) Chemical and Physical Properties Flash Point(°F) 1.4 °F Flash Point(°C) -17 °C
Safety and Hazards(GHS) Signal Danger Hazard Statements H319: Causes serious eye irritation
H335: May cause respiratory irritation
H351: Suspected of causing cancer
H302: Harmful if swallowed
H225: Highly Flammable liquid and vapor
Precautionary Statements P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P370+P378: In case of fire: Use ... to extinguish.
P210: Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking.
P403+P235: Store in a well-ventilated place. Keep cool.
WGK Germany 3 RIDADR UN29248(3)/PGII
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