Click Here for 5% Off Your First Aladdin Purchase!

(R)-(+)-Glycidol - 98%, high purity , CAS No.57044-25-4

  • ≥98%
Item Number
R119621
Grouped product items
SKUSizeAvailabilityPrice Qty
R119621-1g
1g
In stock
$19.90
R119621-5g
5g
In stock
$74.90
R119621-25g
25g
In stock
$253.90
R119621-100g
100g
In stock
$913.90

Discover (R)-(+)-Glycidol by Aladdin Scientific in 98% for only $19.90. Available - in Ligands at Aladdin Scientific. Tags: asymmetric synthesis, Chiral non heterocyclic block.

Basic Description

Synonyms(R)-Glycidol|57044-25-4|(R)-(+)-Glycidol|(R)-Oxiran-2-ylmethanol|[(2R)-oxiran-2-yl]methanol|(R)-Oxiranemethanol|(+)-Glycidol|(R)-3-hydroxy-1,2-epoxypropane|(2R)-oxiran-2-ylmethanol|(R)-(+)-Oxirane-2-methanol|(R)-(+)-2,3-Epoxy-1-propanol|C3H6O2|Oxiranemeth
Specifications & Purity98%
Storage TempStore at -20°C,Argon charged
Shipped InIce chest + Ice pads
Product Description

Enantioselective esterification of (R)-(+)-glycidol with n-butyric acid in organic media using hybrid gel-entrapped lipase on Celite has been reported.
Chiral building block used to construct an epoxyvinyl iodide intermediate in a synthesis of a furanocembrane, a marine natural product.

Names and Identifiers

Pubchem Sid488195549
IUPAC Name [(2R)-oxiran-2-yl]methanol
INCHI InChI=1S/C3H6O2/c4-1-3-2-5-3/h3-4H,1-2H2/t3-/m1/s1
InChi Key CTKINSOISVBQLD-GSVOUGTGSA-N
Canonical SMILES C1C(O1)CO
Isomeric SMILES C1[C@H](O1)CO
WGK Germany 3
RTECS RR0508000
PubChem CID 5460455
Molecular Weight 74.08
Beilstein 79782
Reaxy-Rn 79782

Certificates

Certificate of Analysis(COA)

Enter Lot Number to search for COA:

To view the certificate results,please click on a Lot number.For Lot numbers from past orders,please use our order status section

11 results found

Lot NumberCertificate TypeDateItem
G2431505Certificate of AnalysisJul 04, 2024 R119621
G2431506Certificate of AnalysisJul 04, 2024 R119621
G2431507Certificate of AnalysisJul 04, 2024 R119621
G2324088Certificate of AnalysisJun 21, 2023 R119621
G2324089Certificate of AnalysisJun 21, 2023 R119621
G2324092Certificate of AnalysisJun 21, 2023 R119621
G2324094Certificate of AnalysisJun 21, 2023 R119621
G2324095Certificate of AnalysisJun 21, 2023 R119621
G2324098Certificate of AnalysisJun 21, 2023 R119621
G2324100Certificate of AnalysisJun 21, 2023 R119621
G2324103Certificate of AnalysisJun 21, 2023 R119621

more

Chemical and Physical Properties

SolubilitySolubility in water: Completely miscible
Sensitivityheat & Moisture sensitive
Refractive Index1.43
Specific Rotation[α]+13.0 to +17.0 deg(neat)
Flash Point(°F)150.8 °F
Flash Point(°C)72°C
Boil Point(°C)56-57°C

Safety and Hazards(GHS)

Pictogram(s) GHS06,   GHS08,   GHS07
Signal Danger
Hazard Statements

H331:Toxic if inhaled

H341:Suspected of causing genetic defects

H314:Causes severe skin burns and eye damage

H302:Harmful if swallowed

H312:Harmful in contact with skin

H360F:May damage fertility

H350:May cause cancer

H242:Heating may cause a fire

Precautionary Statements

P261:Avoid breathing dust/fume/gas/mist/vapors/spray.

P280:Wear protective gloves/protective clothing/eye protection/face protection.

P370+P378:In case of fire: Use ... to extinguish.

P210:Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking.

P302+P352:IF ON SKIN: wash with plenty of water.

P321:Specific treatment (see ... on this label).

P405:Store locked up.

P501:Dispose of contents/container to ...

P240:Ground/bond container and receiving equipment.

P264:Wash hands [and …] thoroughly after handling.

P260:Do not breathe dust/fume/gas/mist/vapors/spray.

P281:Use personal protective equipment as required.

P271:Use only outdoors or in a well-ventilated area.

P403:Store in a well-ventilated place.

P270:Do not eat, drink or smoke when using this product.

P301+P330+P331:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P363:Wash contaminated clothing before reuse.

P403+P233:Store in a well-ventilated place. Keep container tightly closed.

P362+P364:Take off contaminated clothing and wash it before reuse.

P410:Protect from sunlight.

P420:Store separately.

P330:Rinse mouth.

P234:Keep only in original container.

P235:Keep cool.

P411:Store at temperatures not exceeding ... °C/...°F.

P203:Obtain, read and follow all safety instructions before use.

P301+P317:IF SWALLOWED: Get medical help.

P305+P354+P338:IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing.

P318:if exposed or concerned, get medical advice.

P317:Get emergency medical help.

P302+P361+P354:IF ON SKIN: Take off Immediately all contaminated clothing. Immediately rinse with water for several minutes.

P316:Get emergency medical help immediately.

WGK Germany 3
RTECS RR0508000
Reaxy-Rn 79782

Related Documents

References

1. Lei Wang,Jian-Dong Tai,Ren Wang,Er-Na Xun,Xiao-Fei Wei,Lei Wang,Zhi Wang.  (2010-04-20)  Enantioselective transesterification of glycidol catalysed by a novel lipase expressed from Bacillus subtilis..  Biotechnology and applied biochemistry,  56  ((1)): (1-6).  [PMID:20397973]
2. Huofei Zhou,Weiting Yu,Xin Guo,Xiudong Liu,Nan Li,Ying Zhang,Xiaojun Ma.  (2010-10-30)  Synthesis and characterization of amphiphilic glycidol-chitosan-deoxycholic acid nanoparticles as a drug carrier for doxorubicin..  Biomacromolecules,  11  ((12)): (3480-3486).  [PMID:21028798]
3. Hui Lin,Yan Liu,Zhong-Liu Wu.  (2011-01-15)  Highly diastereo- and enantio-selective epoxidation of secondary allylic alcohols catalyzed by styrene monooxygenase..  Chemical communications (Cambridge, England),  47  ((9)): (2610-2612).  [PMID:21234475]
4. Javix Thomas,Fumie X Sunahori,Nicole Borho,Yunjie Xu.  (2011-03-25)  Chirality recognition in the glycidol···propylene oxide complex: a rotational spectroscopic study..  Chemistry (Weinheim an der Bergstrasse, Germany),  17  ((16)): (4582-4587).  [PMID:21433130]
5. Hiroshi Honda,Masayuki Onishi,Kenkichi Fujii,Naohiro Ikeda,Tohru Yamaguchi,Taketoshi Fujimori,Naohiro Nishiyama,Toshio Kasamatsu.  (2011-07-12)  Measurement of glycidol hemoglobin adducts in humans who ingest edible oil containing small amounts of glycidol fatty acid esters..  Food and chemical toxicology : an international journal published for the British Industrial Biological Research Association,  49  ((10)): (2536-2540).  [PMID:21740950]
6. Mathieu Dubois,Adrienne Tarres,Till Goldmann,Guenter Loeffelmann,Alfred Donaubauer,Walburga Seefelder.  (2011-10-25)  Determination of seven glycidyl esters in edible oils by gel permeation chromatography extraction and liquid chromatography coupled to mass spectrometry detection..  Journal of agricultural and food chemistry,  59  ((23)): (12291-12301).  [PMID:22017647]
7. Huofei Zhou,Xiudong Liu,Xin Guo,Nan Li,Weiting Yu,Ying Zhang,Xiaojun Ma.  (2011-12-27)  Synthesis and characterization of amphiphilic chitosan derivatives as a nano-carrier for paclitaxel delivery..  Journal of controlled release : official journal of the Controlled Release Society,  152 Suppl 1  (e124-e125).  [PMID:22195795]
8. Yoen Jung Lee,In-Kwon Choi,Yhun Yhong Sheen,Sue Nie Park,Ho Jeong Kwon.  (2012-02-24)  Moesin is a biomarker for the assessment of genotoxic carcinogens in mouse lymphoma..  Molecules and cells,  33  ((2)): (203-210).  [PMID:22358511]
9. Jing Xu,Tian-Duo Li,Xiao-Long Tang,Cong-De Qiao,Qing-Wei Jiang.  (2012-03-23)  Effect of aggregation behavior of gelatin in aqueous solution on the grafting density of gelatin modified with glycidol..  Colloids and surfaces. B, Biointerfaces,  95  (201-207).  [PMID:22436469]
10. A Becalski,S Y Feng,B P-Y Lau,T Zhao.  (2012-03-31)  Glycidyl fatty acid esters in food by LC-MS/MS: method development..  Analytical and bioanalytical chemistry,  403  ((10)): (2933-2942).  [PMID:22460076]
11. Koichi Sawada,Shinji Sakai,Masahito Taya.  (2012-05-19)  Enhanced productivity of electrospun polyvinyl alcohol nanofibrous mats using aqueous N,N-dimethylformamide solution and their application to lipase-immobilizing membrane-shaped catalysts..  Journal of bioscience and bioengineering,  114  ((2)): (204-208).  [PMID:22595342]
12. V Arjunan,T Rani,R Santhanam,S Mohan.  (2012-06-02)  Structural characteristics and harmonic vibrational analysis of the stable conformer of 2,3-epoxypropanol by quantum chemical methods..  Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy,  96  (24-34).  [PMID:22652541]
13. Rajesh A Shenoi,Benjamin F L Lai,Jayachandran N Kizhakkedathu.  (2012-08-28)  Synthesis, characterization, and biocompatibility of biodegradable hyperbranched polyglycerols from acid-cleavable ketal group functionalized initiators..  Biomacromolecules,  13  ((10)): (3018-3030).  [PMID:22920950]
14. Naohiro Ikeda,Kenkichi Fujii,Miko Sarada,Hitoshi Saito,Masayoshi Kawabata,Kiyoko Naruse,Katsuyuki Yuki,Hideaki Nakagiri,Hiroshi Honda,Yasushi Tamaki,Naohiro Nishiyama,Toshio Kasamatsu.  (2012-08-28)  Genotoxicity studies of glycidol fatty acid ester (glycidol linoleate) and glycidol..  Food and chemical toxicology : an international journal published for the British Industrial Biological Research Association,  50  ((11)): (3927-3933).  [PMID:22921352]
15. B D Craft,A Chiodini,J Garst,M Granvogl.  (2012-10-02)  Fatty acid esters of monochloropropanediol (MCPD) and glycidol in refined edible oils..  Food additives & contaminants. Part A, Chemistry, analysis, control, exposure & risk assessment,  30  ((1)): (46-51).  [PMID:23020600]
16. Theresa Weber,Yasmin Gies,Andreas Terfort.  (2012-10-18)  Bacteria-repulsive polyglycerol surfaces by grafting polymerization onto aminopropylated surfaces..  Langmuir : the ACS journal of surfaces and colloids,  28  ((45)): (15916-15921).  [PMID:23072589]
17. N Frank,M Dubois,G Scholz,W Seefelder,J-Y Chuat,B Schilter.  (2012-10-23)  Application of gastrointestinal modelling to the study of the digestion and transformation of dietary glycidyl esters..  Food additives & contaminants. Part A, Chemistry, analysis, control, exposure & risk assessment,  30  ((1)): (69-79).  [PMID:23083414]
18. Adriano A Mendes,Heizir F de Castro,Dasciana de S Rodrigues,Wellington S Adriano,Paulo W Tardioli,Enrique J Mammarella,Roberto de C Giordano,Raquel de L C Giordano.  (2010-10-06)  Multipoint covalent immobilization of lipase on chitosan hybrid hydrogels: influence of the polyelectrolyte complex type and chemical modification on the catalytic properties of the biocatalysts..  Journal of industrial microbiology & biotechnology,  38  ((8)): (1055-1066).  [PMID:20922457]
19. Ryo Tanaka,Masaru Kato,Takahiro Suzuki,Atsuo Nakazaki,Emi Nozaki,Mari Gotoh,Kimiko Murakami-Murofushi,Susumu Kobayashi.  (2011-06-17)  Efficient synthesis of 3-O-thia-cPA and preliminary analysis of its biological activity toward autotaxin..  Bioorganic & medicinal chemistry letters,  21  ((14)): (4180-4182).  [PMID:21676615]
20. .  (2011-08-20)  Glycidol..  Report on carcinogens : carcinogen profiles,  12  (215-216).  [PMID:21852841]
21. Ken-ichi Wakabayashi,Yoshimasa Kurata,Tomoo Harada,Yasushi Tamaki,Naohiro Nishiyama,Toshio Kasamatsu.  (2012-08-07)  Species differences in toxicokinetic parameters of glycidol after a single dose of glycidol or glycidol linoleate in rats and monkeys..  The Journal of toxicological sciences,  37  ((4)): (691-698).  [PMID:22863850]
22. Hiroshi Honda,Kenkichi Fujii,Tohru Yamaguchi,Naohiro Ikeda,Naohiro Nishiyama,Toshio Kasamatsu.  (2012-08-15)  Glycidol exposure evaluation of humans who have ingested diacylglycerol oil containing glycidol fatty acid esters using hemoglobin adducts..  Food and chemical toxicology : an international journal published for the British Industrial Biological Research Association,  50  ((11)): (4163-4168).  [PMID:22889899]

Solution Calculators