Discover (R)-RuCl[(p-cymene)(BINAP)]Cl by Aladdin Scientific in 99.95% metals basis for only $68.90. Available - in Ligands at Aladdin Scientific. Tags: .
Reaction type Hydrogenation, Asymmetric Reactions, Asymmetric Hydrogenation, Transfer Hydrogenation
Chemical properties
Chemical formula
C54H46Cl2P2Ru
Empirical formula
[RuCl(p-cymene)(R)-BINAP]Cl
Molecular weight
928.88
Metal
Ru
Theoretical metal content
11
Physical state
powder
Color Metal purity
red orange
99.95
Applications & references
Synthesis of chiral acid derivatives by asymmetrical hydrogenation of the corresponding (E)-allylic ethers in the preparation of spiro-substituted glutaramide derivatives.
Reference: EP644176
Asymmetric hydrogenation of halogenated acetophenones to enantiomerically pure halogenated phenyl ethanol derivatives.
Reference: Cat. Lett. 1996, 41, 111 (DOI: 10.1007/BF00811721)
Highly enantioselective catalytic hydrogenation of methyl-N-tertbutyl-3-oxoglutarate as a key step in the total synthesis of rovastatin.
Reference: Tetrah. Lett. 2008, 49, 4836 (DOI: 10.1016/j.tetlet.2008.06.018)
Enantioselective hydrogenation of 4-(hydroxymethyl)furan-2(5H)-one derivatives.