Rhodium Chloride Hydrate - Rh 38.5-42.5%, high purity , CAS No.20765-98-4

20 Citations
  • Rh 38.5-42.5%
Item Number
R109233
Grouped product items
SKUSizeAvailabilityPrice Qty
R109233-250mg
250mg
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$159.90
R109233-1g
1g
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$589.90
R109233-5g
5g
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$2,119.90
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Inorganic Catalysts

Basic Description

SynonymsRhCl3 x n H2O
Specifications & PurityRh 38.5-42.5%
Storage TempArgon charged
Shipped InNormal
Product Description

A catalyst for conjugate reduction of cinnamaldehydes followed by cross-coupling with arylboronic acids. Catalyst for the direct conversion of methane to acetic acid.
Catalyst for the isomerization of alkenes, the reduction of aromatic rings, the oxidation ofalkenes, the hydration of acetylene, the hydrosilylation of α,β-unsaturated esters to form dimethylketene trimethylsilyl acetals.


Application:

Catalyst for conjugate reduction of cinnamaldehydes followed by cross-coupling with arylboronic acids. Catalyst for the direct conversion of methane to acetic acid. Catalyst for the isomerization of alkenes, the reduction of aromatic rings, the oxidation ofalkenes, the hydration of acetylene, the hydrosilylation of α,β-unsaturated esters to form dimethylketene trimethylsilyl acetals.


Product class
PGM Solids, Chlorides, Hydrates

Reaction type
Hydroformylation, Isomerization, Oxidation, Reduction

Chemical properties

Chemical formula

Cl3Rh

Empirical formula

RhClx n H2O

Molecular weight

209.26 (anhydrous)

Metal

Rh

Theoretical metal content

38

Physical state

powder

Color

dark red

Names and Identifiers

INCHI 1S/3ClH.H2O.Rh/h3*1H;1H2;/q;;;;+3/p-3
InChi Key HSSMNYDDDSNUKH-UHFFFAOYSA-K
Canonical SMILES O.Cl[Rh](Cl)Cl
Isomeric SMILES O.Cl[Rh](Cl)Cl
WGK Germany 3
PubChem CID 16211510
UN Number 3260
Packing Group III
Molecular Weight 209.26(anhydrous basis)

Certificates

Certificate of Analysis(COA)

Enter Lot Number to search for COA:

Find and download the COA for your product by matching the lot number on the packaging.

6 results found

Lot NumberCertificate TypeDateItem
I2314006Certificate of AnalysisOct 08, 2023 R109233
I2314060Certificate of AnalysisOct 08, 2023 R109233
I2212310Certificate of AnalysisAug 09, 2022 R109233
I2212311Certificate of AnalysisAug 09, 2022 R109233
I2212323Certificate of AnalysisAug 09, 2022 R109233
G2218049Certificate of AnalysisJul 19, 2021 R109233

Chemical and Physical Properties

SolubilitySoluble in alcohol and water. Slightly soluble in acetone.
SensitivityHygroscopic
Melt Point(°C)100°C

Safety and Hazards(GHS)

Pictogram(s) GHS08,   GHS09,   GHS05,   GHS07
Signal Danger
Hazard Statements

H341:Suspected of causing genetic defects

H302:Harmful if swallowed

H318:Causes serious eye damage

H410:Very toxic to aquatic life with long lasting effects

H290:May be corrosive to metals

Precautionary Statements

P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.

P280:Wear protective gloves/protective clothing/eye protection/face protection.

P310:Immediately call a POISON CENTER or doctor/physician.

P405:Store locked up.

P501:Dispose of contents/container to ...

P264:Wash hands [and …] thoroughly after handling.

P201:Obtain special instructions before use.

P308+P313:IF exposed or concerned: Get medical advice/attention.

P391:Collect spillage.

P202:Do not handle until all safety precautions have been read and understood.

P330:Rinse mouth.

P234:Keep only in original container.

P390:Absorb spillage to prevent material damage.

P301+P312:IF SWALLOWED: call a POISON CENTER/doctor/... IF you feel unwell.

P406:Store in corrosive resistant/... container with a resistant inner liner.

WGK Germany 3
Class 8

Related Documents

Citations of This Product

1. Xia Kang, Zhendong Wang, Shijie Kang, Dazhong Ren.  (2024)  Rh0.7Ru0.3-MoOx supported on carbon nanotubes boosts hydrogen generation from hydrazine borane at room temperature.  INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,  54  (20): (1386).  [PMID:10411888]
2. Xuan Zhu, Yan Liu, Menglin Wang, Li Zhang, Qiaoli Li, Entao Zhang, Hongfen Mo, Yuan Gao, Chenyu Xu, Yanwei Zhang.  (2024)  Boosting solar photothermal synergy for efficient overall water splitting based on Mg, Al codoped and Rh/Cr2O3/CoOOH coloaded SrTiO3.  CHEMICAL ENGINEERING JOURNAL,  479  (18): (147636).  [PMID:16606821]
3. Huanhuan Zhang, Qunying Sun, Linyan Bian, Qiuming Peng, Shumin Han, Baozhong Liu, Yanping Fan.  (2024)  Alloy-exciting effect of palladium-rhodium on MXene for enhanced hydrogen generation.  INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,  49  (28): (1226).  [PMID:19369211]
4. Kai Deng, Wenxin Wang, Zilong Lian, Hongjie Yu, Ziqiang Wang, You Xu, Hongjing Wang, Liang Wang.  (2023)  A General Synthesis of Crystal Phase Controllable Aerogels for Efficient Hydrogen Evolution.  Small,  19  (49): (2304181).  [PMID:37563822]
5. Xiaofeng Ke, Feng Zhou, Yihuang Chen, Mei Zhao, Yun Yang, Huile Jin, Youqing Dong, Chao Zou, Xi'an Chen, Lijie Zhang, Shun Wang.  (2023)  Modifying charge transfer between rhodium and ceria for boosted hydrogen oxidation reaction in alkaline electrolyte.  JOURNAL OF COLLOID AND INTERFACE SCIENCE,  650  (1842).  [PMID:37515974]
6. Songliang Liu, Hugang Zhang, Hongjie Yu, Kai Deng, Ziqiang Wang, You Xu, Liang Wang, Hongjing Wang.  (2023)  Tailored design of PdRh bimetallene nanoribbons by solvent-induced strategy for efficient alkaline hydrogen evolution.  APPLIED CATALYSIS B-ENVIRONMENTAL,  336  (122948).  [PMID:]
7. Ziqiang Wang, Guanghui Yang, Pengjun Tian, Kai Deng, Hongjie Yu, You Xu, Xiaonian Li, Hongjing Wang, Liang Wang.  (2023)  Heterointerface engineering of Rh/Pd metallene for hydrazine oxidation-assisted energy-saving hydrogen production.  Journal of Materials Chemistry A,  11  (19): (10222-10227).  [PMID:]
8. Jie Shi, Qintao Sun, Wenxiang Zhu, Tao Cheng, Fan Liao, Mengjie Ma, Junjun Yang, Hao Yang, Zhenglong Fan, Mingwang Shao.  (2023)  Lattice stain dominated hydrazine oxidation reaction in single-metal-element nanosheet.  CHEMICAL ENGINEERING JOURNAL,  463  (142385).  [PMID:]
9. Wenjie Xue, Hongxia Liu, Binbin Zhao, Lixia Ge, Shuai Yang, Minghuang Qiu, Jiong Li, Wei Han, Xinqing Chen.  (2023)  Single Rh1Co catalyst enabling reversible hydrogenation and dehydrogenation of N-ethylcarbazole for hydrogen storage.  APPLIED CATALYSIS B-ENVIRONMENTAL,  327  (122453).  [PMID:]
10. Lei Zeng, Wei Li, Xueer Wei, Jiawei Cheng, Wei Zhou, Yanping Zheng, Fan Cai, Yuefeng Liu, Kang Cheng, Qinghong Zhang, Ye Wang.  (2023)  IrGa Bimetallic Catalyst with Atomical Metal Dispersion for Propane Dehydrogenation with High Stability.  ChemCatChem,  15  (4): (e202201405).  [PMID:]
11. Wenxiu Luo, Guo Li, Wei Cheng, Yi Wang.  (2023)  SiO2-mediated fabrication of hydrophilic biomass-carbon and its expediting effect on Rh nanoparticles catalyzed dehydrogenation of ammonia borane.  FUEL,  333  (126366).  [PMID:]
12. Jin Zhang, Mengting Gao, Ruiyi Wang, Xincheng Li, Pengqi Zhu, Yunwei Wang, Zhanfeng Zheng.  (2022)  Oxygen vacancy regulated selective hydrogenation of α,β-unsaturated aldehydes over LDH surface group coordinated transition metal photocatalysts.  Catalysis Science & Technology,  12  (20): (6163-6173).  [PMID:]
13. Fan Yang, Hongbo Yu, Chunzheng Wu, Shiwei Wang, Tong Li, Hongfeng Yin.  (2022)  RhCu Bimetallic Nanoparticles in Hollow Carbon Spheres for Catalytic Halonitrobenzene Chemoselective Hydrogenation.  ACS Applied Nano Materials,  (8): (11627–11635).  [PMID:]
14. Rongfei Wang, Xiaodeng Wang, Min Cheng, Yunpeng Wei, Jihong Xia, Hua Lin, Wei Sun, Weihua Hu.  (2022)  Phosphatizing engineering of heterostructured Rh2P/Rh nanoparticles on doped graphene for efficient hydrogen evolution in alkaline and acidic media.  INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,  47  (24669).  [PMID:]
15. Yan Guo, Yunwei Wang, Zhenfeng Huang, Xili Tong, Nianjun Yang.  (2022)  Size effect of Rhodium nanoparticles supported on carbon black on the performance of hydrogen evolution reaction.  CARBON,  194  (303).  [PMID:]
16. Y.F. Wang, X. Luo, W.J. Lu, L. Yang, B. Huang, P.T. Li, Y.Q. Yang.  (2022)  Carbon supported bifunctional Rh–Ni(OH)2/C nanocomposite catalysts with high electrocatalytic efficiency for alkaline hydrogen evolution reaction.  INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,  47  (13674).  [PMID:]
17. Dong-Xue Liu, Yi-Tong Zhou, Yong-Fu Zhu, Ze-Yu Chen, Jun-Min Yan, Qing Jiang.  (2022)  Tri-metallic AuPdIr nanoalloy towards efficient hydrogen generation from formic acid.  APPLIED CATALYSIS B-ENVIRONMENTAL,  309  (121228).  [PMID:]
18. Longfei Zhu, Sen Ye, Jing Wang, Jiazheng Zhu, Guangke He, Xiang Liu.  (2022)  Supported Iridium Catalyst for Clean Transfer Hydrogenation of Aldehydes and Ketones using Methanol as Hydrogen Source.  ChemCatChem,  14  (6): (e202101794).  [PMID:]
19. Huan Fu, Huan Zhang, Guichun Yang, Jun Liu, Junyuan Xu, Peihuan Wang, Ning Zhao, Lihua Zhu, Bing Hui Chen.  (2022)  Highly dispersed rhodium atoms supported on defect-rich Co(OH)2 for the chemoselective hydrogenation of nitroarenes.  NEW JOURNAL OF CHEMISTRY,  46  (3): (1158-1167).  [PMID:]
20. Fuyong Zhang, Wei Zhou, Xuewei Xiong, Yuhao Wang, Kang Cheng, Jincan Kang, Qinghong Zhang, Ye Wang.  (2021)  Selective Hydrogenation of CO2 to Ethanol over Sodium-Modified Rhodium Nanoparticles Embedded in Zeolite Silicalite-1.  Journal of Physical Chemistry C,  125  (44): (24429–24439).  [PMID:]

References

1. Xia Kang, Zhendong Wang, Shijie Kang, Dazhong Ren.  (2024)  Rh0.7Ru0.3-MoOx supported on carbon nanotubes boosts hydrogen generation from hydrazine borane at room temperature.  INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,  54  (20): (1386).  [PMID:10411888]
2. Xuan Zhu, Yan Liu, Menglin Wang, Li Zhang, Qiaoli Li, Entao Zhang, Hongfen Mo, Yuan Gao, Chenyu Xu, Yanwei Zhang.  (2024)  Boosting solar photothermal synergy for efficient overall water splitting based on Mg, Al codoped and Rh/Cr2O3/CoOOH coloaded SrTiO3.  CHEMICAL ENGINEERING JOURNAL,  479  (18): (147636).  [PMID:16606821]
3. Huanhuan Zhang, Qunying Sun, Linyan Bian, Qiuming Peng, Shumin Han, Baozhong Liu, Yanping Fan.  (2024)  Alloy-exciting effect of palladium-rhodium on MXene for enhanced hydrogen generation.  INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,  49  (28): (1226).  [PMID:19369211]
4. Kai Deng, Wenxin Wang, Zilong Lian, Hongjie Yu, Ziqiang Wang, You Xu, Hongjing Wang, Liang Wang.  (2023)  A General Synthesis of Crystal Phase Controllable Aerogels for Efficient Hydrogen Evolution.  Small,  19  (49): (2304181).  [PMID:37563822]
5. Xiaofeng Ke, Feng Zhou, Yihuang Chen, Mei Zhao, Yun Yang, Huile Jin, Youqing Dong, Chao Zou, Xi'an Chen, Lijie Zhang, Shun Wang.  (2023)  Modifying charge transfer between rhodium and ceria for boosted hydrogen oxidation reaction in alkaline electrolyte.  JOURNAL OF COLLOID AND INTERFACE SCIENCE,  650  (1842).  [PMID:37515974]
6. Songliang Liu, Hugang Zhang, Hongjie Yu, Kai Deng, Ziqiang Wang, You Xu, Liang Wang, Hongjing Wang.  (2023)  Tailored design of PdRh bimetallene nanoribbons by solvent-induced strategy for efficient alkaline hydrogen evolution.  APPLIED CATALYSIS B-ENVIRONMENTAL,  336  (122948).  [PMID:]
7. Ziqiang Wang, Guanghui Yang, Pengjun Tian, Kai Deng, Hongjie Yu, You Xu, Xiaonian Li, Hongjing Wang, Liang Wang.  (2023)  Heterointerface engineering of Rh/Pd metallene for hydrazine oxidation-assisted energy-saving hydrogen production.  Journal of Materials Chemistry A,  11  (19): (10222-10227).  [PMID:]
8. Jie Shi, Qintao Sun, Wenxiang Zhu, Tao Cheng, Fan Liao, Mengjie Ma, Junjun Yang, Hao Yang, Zhenglong Fan, Mingwang Shao.  (2023)  Lattice stain dominated hydrazine oxidation reaction in single-metal-element nanosheet.  CHEMICAL ENGINEERING JOURNAL,  463  (142385).  [PMID:]
9. Wenjie Xue, Hongxia Liu, Binbin Zhao, Lixia Ge, Shuai Yang, Minghuang Qiu, Jiong Li, Wei Han, Xinqing Chen.  (2023)  Single Rh1Co catalyst enabling reversible hydrogenation and dehydrogenation of N-ethylcarbazole for hydrogen storage.  APPLIED CATALYSIS B-ENVIRONMENTAL,  327  (122453).  [PMID:]
10. Lei Zeng, Wei Li, Xueer Wei, Jiawei Cheng, Wei Zhou, Yanping Zheng, Fan Cai, Yuefeng Liu, Kang Cheng, Qinghong Zhang, Ye Wang.  (2023)  IrGa Bimetallic Catalyst with Atomical Metal Dispersion for Propane Dehydrogenation with High Stability.  ChemCatChem,  15  (4): (e202201405).  [PMID:]
11. Wenxiu Luo, Guo Li, Wei Cheng, Yi Wang.  (2023)  SiO2-mediated fabrication of hydrophilic biomass-carbon and its expediting effect on Rh nanoparticles catalyzed dehydrogenation of ammonia borane.  FUEL,  333  (126366).  [PMID:]
12. Jin Zhang, Mengting Gao, Ruiyi Wang, Xincheng Li, Pengqi Zhu, Yunwei Wang, Zhanfeng Zheng.  (2022)  Oxygen vacancy regulated selective hydrogenation of α,β-unsaturated aldehydes over LDH surface group coordinated transition metal photocatalysts.  Catalysis Science & Technology,  12  (20): (6163-6173).  [PMID:]
13. Fan Yang, Hongbo Yu, Chunzheng Wu, Shiwei Wang, Tong Li, Hongfeng Yin.  (2022)  RhCu Bimetallic Nanoparticles in Hollow Carbon Spheres for Catalytic Halonitrobenzene Chemoselective Hydrogenation.  ACS Applied Nano Materials,  (8): (11627–11635).  [PMID:]
14. Rongfei Wang, Xiaodeng Wang, Min Cheng, Yunpeng Wei, Jihong Xia, Hua Lin, Wei Sun, Weihua Hu.  (2022)  Phosphatizing engineering of heterostructured Rh2P/Rh nanoparticles on doped graphene for efficient hydrogen evolution in alkaline and acidic media.  INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,  47  (24669).  [PMID:]
15. Yan Guo, Yunwei Wang, Zhenfeng Huang, Xili Tong, Nianjun Yang.  (2022)  Size effect of Rhodium nanoparticles supported on carbon black on the performance of hydrogen evolution reaction.  CARBON,  194  (303).  [PMID:]
16. Y.F. Wang, X. Luo, W.J. Lu, L. Yang, B. Huang, P.T. Li, Y.Q. Yang.  (2022)  Carbon supported bifunctional Rh–Ni(OH)2/C nanocomposite catalysts with high electrocatalytic efficiency for alkaline hydrogen evolution reaction.  INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,  47  (13674).  [PMID:]
17. Dong-Xue Liu, Yi-Tong Zhou, Yong-Fu Zhu, Ze-Yu Chen, Jun-Min Yan, Qing Jiang.  (2022)  Tri-metallic AuPdIr nanoalloy towards efficient hydrogen generation from formic acid.  APPLIED CATALYSIS B-ENVIRONMENTAL,  309  (121228).  [PMID:]
18. Longfei Zhu, Sen Ye, Jing Wang, Jiazheng Zhu, Guangke He, Xiang Liu.  (2022)  Supported Iridium Catalyst for Clean Transfer Hydrogenation of Aldehydes and Ketones using Methanol as Hydrogen Source.  ChemCatChem,  14  (6): (e202101794).  [PMID:]
19. Huan Fu, Huan Zhang, Guichun Yang, Jun Liu, Junyuan Xu, Peihuan Wang, Ning Zhao, Lihua Zhu, Bing Hui Chen.  (2022)  Highly dispersed rhodium atoms supported on defect-rich Co(OH)2 for the chemoselective hydrogenation of nitroarenes.  NEW JOURNAL OF CHEMISTRY,  46  (3): (1158-1167).  [PMID:]
20. Fuyong Zhang, Wei Zhou, Xuewei Xiong, Yuhao Wang, Kang Cheng, Jincan Kang, Qinghong Zhang, Ye Wang.  (2021)  Selective Hydrogenation of CO2 to Ethanol over Sodium-Modified Rhodium Nanoparticles Embedded in Zeolite Silicalite-1.  Journal of Physical Chemistry C,  125  (44): (24429–24439).  [PMID:]

Solution Calculators