Basic Description

Synonyms	(E)-4-hydroxypent-3-en-2-one;rhodium \| Q48789857 \| Rhodium acetylacetonate \| Rhodium(III) acetylacetonate, 97% \| MFCD00083144 \| Rhodium(III) 2,4-pentanedionate, Premion(R) \| AKOS025311441 \| Rhodium(III) acetylacetonate
Specifications & Purity	≥97%
Shipped In	Normal
Product Description	Product class Homogeneous Catalysts, M-O Chemical properties Chemical formula C15H21O6Rh Empirical formula [Rh(acac)3] Molecular weight 400.23 Metal Rh Theoretical metal content 25 Physical state crystalline Color yellow orange

Names and Identifiers

Pubchem Sid	488202187
Pubchem Sid Url	https://pubchem.ncbi.nlm.nih.gov/substance/488202187
IUPAC Name	(E)-4-hydroxypent-3-en-2-one;rhodium
INCHI	InChI=1S/3C5H8O2.Rh/c31-4(6)3-5(2)7;/h33,6H,1-2H3;/b3*4-3+;
InChi Key	MBVAQOHBPXKYMF-MUCWUPSWSA-N
Canonical SMILES	CC(=CC(=O)C)O.CC(=CC(=O)C)O.CC(=CC(=O)C)O.[Rh]
Isomeric SMILES	C/C(=C\C(=O)C)/O.C/C(=C\C(=O)C)/O.C/C(=C\C(=O)C)/O.[Rh]
WGK Germany	3
PubChem CID	71306774
Molecular Weight	400.23

Certificates

Certificate of Analysis(COA)

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14 results found

Lot Number	Certificate Type	Date	Item
H2430192	Certificate of Analysis	Sep 10, 2024	R118539
H2430193	Certificate of Analysis	Sep 10, 2024	R118539
H2430194	Certificate of Analysis	Sep 10, 2024	R118539
H2430195	Certificate of Analysis	Sep 10, 2024	R118539
A2403375	Certificate of Analysis	Jan 09, 2024	R118539
A2403376	Certificate of Analysis	Jan 09, 2024	R118539
D2418054	Certificate of Analysis	Nov 08, 2023	R118539
J2331575	Certificate of Analysis	Nov 08, 2023	R118539
J2331576	Certificate of Analysis	Nov 08, 2023	R118539
J2331577	Certificate of Analysis	Nov 08, 2023	R118539
D23261183	Certificate of Analysis	May 12, 2023	R118539
G2209148	Certificate of Analysis	Jul 16, 2022	R118539
G2209149	Certificate of Analysis	Jul 16, 2022	R118539
G2209306	Certificate of Analysis	Jul 16, 2022	R118539

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Chemical and Physical Properties

Melt Point(°C)	263-264°C

Safety and Hazards(GHS)

Pictogram(s)	GHS08, GHS07
Signal	Warning
Hazard Statements	H315:Causes skin irritation H319:Causes serious eye irritation H335:May cause respiratory irritation H302+H312+H332:Harmful if swallowed, in contact with skin or if inhaled H361:Suspected of damaging fertility or the unborn child
Precautionary Statements	P261:Avoid breathing dust/fume/gas/mist/vapors/spray. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of water. P312:Call a POISON CENTER or doctor/... if you feel unwell. P308+P313:IF exposed or concerned: Get medical advice/attention. P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing. P301+P312:IF SWALLOWED: call a POISON CENTER/doctor/... IF you feel unwell.
WGK Germany	3

Citations of This Product

1. Ce Han, Bingbao Mei, Qinghua Zhang, Huimin Zhang, Pengfei Yao, Ping Song, Xue Gong, Peixin Cui, Zheng Jiang, Lin Gu, Weilin Xu. (2023) Atomic Ru coordinated by channel ammonia in V-doped tungsten bronze for highly efficient hydrogen-evolution reaction. CHINESE JOURNAL OF CATALYSIS, 51 (30): (80). [PMID:11536051]
2. Ziqiang Wang, Guanghui Yang, Pengjun Tian, Xinmiao Li, Kai Deng, Hongjie Yu, You Xu, Hongjing Wang, Liang Wang. (2023) Hydrophilic functionalization of rhodium metallene for saving-energy hydrogen production and sulfur recovery. CHEMICAL ENGINEERING JOURNAL, 473 (145147). [PMID:]
3. Xiaolan Li, Yangqi Huang, Zhenyu Chen, Shuqi Hu, Jinliang Zhu, Panagiotis Tsiakaras, Pei Kang Shen. (2023) Novel PtNi nanoflowers regulated by a third element (Rh, Ru, Pd) as efficient multifunctional electrocatalysts for ORR, MOR and HER. CHEMICAL ENGINEERING JOURNAL, 454 (140131). [PMID:]
4. Fan Yang, Hongbo Yu, Chunzheng Wu, Shiwei Wang, Tong Li, Hongfeng Yin. (2022) RhCu Bimetallic Nanoparticles in Hollow Carbon Spheres for Catalytic Halonitrobenzene Chemoselective Hydrogenation. ACS Applied Nano Materials, 5 (8): (11627–11635). [PMID:]
5. Qiqi Mao, Kai Deng, Hongjie Yu, You Xu, Ziqiang Wang, Xiaonian Li, Liang Wang, Hongjing Wang. (2022) In Situ Reconstruction of Partially Hydroxylated Porous Rh Metallene for Ethylene Glycol-Assisted Seawater Splitting. ADVANCED FUNCTIONAL MATERIALS, 32 (31): (2201081). [PMID:]
6. Yuting Chu, Bo Yan, Xia Yang, Shiwei Wang, Peng Cao, Tong Li, Hongbo Yu, Hongfeng Yin. (2021) Selective Oxidation of Methyl Lactate over Carbon-Supported Noble Metal Catalysts under Base-Free Conditions. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 60 (40): (14397–14409). [PMID:]

References

1. Ce Han, Bingbao Mei, Qinghua Zhang, Huimin Zhang, Pengfei Yao, Ping Song, Xue Gong, Peixin Cui, Zheng Jiang, Lin Gu, Weilin Xu. (2023) Atomic Ru coordinated by channel ammonia in V-doped tungsten bronze for highly efficient hydrogen-evolution reaction. CHINESE JOURNAL OF CATALYSIS, 51 (30): (80). [PMID:11536051]
2. Ziqiang Wang, Guanghui Yang, Pengjun Tian, Xinmiao Li, Kai Deng, Hongjie Yu, You Xu, Hongjing Wang, Liang Wang. (2023) Hydrophilic functionalization of rhodium metallene for saving-energy hydrogen production and sulfur recovery. CHEMICAL ENGINEERING JOURNAL, 473 (145147). [PMID:]
3. Xiaolan Li, Yangqi Huang, Zhenyu Chen, Shuqi Hu, Jinliang Zhu, Panagiotis Tsiakaras, Pei Kang Shen. (2023) Novel PtNi nanoflowers regulated by a third element (Rh, Ru, Pd) as efficient multifunctional electrocatalysts for ORR, MOR and HER. CHEMICAL ENGINEERING JOURNAL, 454 (140131). [PMID:]
4. Fan Yang, Hongbo Yu, Chunzheng Wu, Shiwei Wang, Tong Li, Hongfeng Yin. (2022) RhCu Bimetallic Nanoparticles in Hollow Carbon Spheres for Catalytic Halonitrobenzene Chemoselective Hydrogenation. ACS Applied Nano Materials, 5 (8): (11627–11635). [PMID:]
5. Qiqi Mao, Kai Deng, Hongjie Yu, You Xu, Ziqiang Wang, Xiaonian Li, Liang Wang, Hongjing Wang. (2022) In Situ Reconstruction of Partially Hydroxylated Porous Rh Metallene for Ethylene Glycol-Assisted Seawater Splitting. ADVANCED FUNCTIONAL MATERIALS, 32 (31): (2201081). [PMID:]
6. Yuting Chu, Bo Yan, Xia Yang, Shiwei Wang, Peng Cao, Tong Li, Hongbo Yu, Hongfeng Yin. (2021) Selective Oxidation of Methyl Lactate over Carbon-Supported Noble Metal Catalysts under Base-Free Conditions. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 60 (40): (14397–14409). [PMID:]

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SKU	Size	Availability	Price
R118539-250mg	250mg	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$179.90
R118539-1g	1g	In stock	$569.90
R118539-5g	5g	Available within 4-8 weeks(?) Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!	$2,299.90

Rhodium(III) acetylacetonate - 97%, high purity , CAS No.14284-92-5